摘要:
N-formyl-N-phosphonomethylglycine and esters thereof having the formula wherein R is hydrogen or C 1-5 alkyl; Z, is XR 1 or NR 3 R 4 ; Z 2 is YR 2 or NR 3 R 4 ; X and Y are independently oxygen or sulfur; R, is hydrogen, C 1-5 alkyl or phenyl;
R 2 is hydrogen, C 1-5 alkyl or phenyl; R 3 and R 4 are independently hydrogen or C 1-5 alkyl; provided that R, may not be phenyl when R 2 is methyl and X and Y are oxygen and provided that R 1 may not be methyl when Z 2 is N-(C 2 H 5 ) 2 , have been found to be effective herbicides, especially when applied to emerged plants.
摘要:
This disclosure relates to ester derivatives of N-trifluoroacetyl- N-phosphonomethylglycine, to herbicidal compositions containing same and to the herbicidal use thereof. The ester derivatives of N-trifluoroacetyl -N-phosphonomethylglycine are useful as herbicides. The novel N-trifluoroacetyl- N-phosphonomethylglycine esters of this invention are those mixed ester derivatives having the formula wherein R is an alkyl group containing 1 to 10 carbon atoms or a phenyl group and R'is a member of the group consisting of allyl, naphthyl, benzyl and ring-substituted benzyl wherein the substituent is halo, cyano, nitro and trifluoromethyl, phenyl and phenyl substituted with one or two groups selected from the class consisting of halo, cyano, nitro and trifluoromethyl.