Ester derivatives of N-trifluoro-acetyl-N-phosphonomethylglycine and the herbicidal use thereof
    2.
    发明公开
    Ester derivatives of N-trifluoro-acetyl-N-phosphonomethylglycine and the herbicidal use thereof 失效
    Esterderivate von N-Trifluoracetyl-N-Phosphonmethylglyzin und deren Verwendung als Herbizide。

    公开(公告)号:EP0007210A2

    公开(公告)日:1980-01-23

    申请号:EP79301306.1

    申请日:1979-07-06

    申请人: MONSANTO COMPANY

    IPC分类号: C07F9/38 A01N57/18

    摘要: This disclosure relates to ester derivatives of N-trifluoroacetyl- N-phosphonomethylglycine, to herbicidal compositions containing same and to the herbicidal use thereof. The ester derivatives of N-trifluoroacetyl -N-phosphonomethylglycine are useful as herbicides.
    The novel N-trifluoroacetyl- N-phosphonomethylglycine esters of this invention are those mixed ester derivatives having the formula
    wherein R is an alkyl group containing 1 to 10 carbon atoms or a phenyl group and R'is a member of the group consisting of allyl, naphthyl, benzyl and ring-substituted benzyl wherein the substituent is halo, cyano, nitro and trifluoromethyl, phenyl and phenyl substituted with one or two groups selected from the class consisting of halo, cyano, nitro and trifluoromethyl.

    摘要翻译: 本公开涉及N-三氟乙酰基-N-膦酰基甲基甘氨酸的酯衍生物,含有其的除草组合物及其除草用途。 N-三氟乙酰基-N-膦酰基甲基甘氨酸的酯衍生物可用作除草剂。

    Amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters and herbicidal compositions containing them
    7.
    发明公开
    Amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters and herbicidal compositions containing them 失效
    酰胺 - 和肼基转移酶N-磷酸硫代甲基甘氨酸和其他药物。

    公开(公告)号:EP0031714A1

    公开(公告)日:1981-07-08

    申请号:EP80304693.7

    申请日:1980-12-23

    申请人: MONSANTO COMPANY

    IPC分类号: C07F9/44 C07F9/65 A01N57/26

    摘要: This invention relates to a new class of organic chemical compounds. More particularly, this invention is concerned with amido and hydrazido derivatives of N-phosphinothioylmethylglycine esters. This class of compounds has been found to be useful as herbicides.
    The compounds of the present invention are compounds of the formula.
    wherein R is a member of the group consisting of alkyl of from 1 to 8 carbon atoms, chloroalkyl of from 1 to 4 carbon atoms and from 1 to 3 chlorine atoms and alkoxyalkyl containing from 3 to 7 carbon atoms and wherein Z is a member of the class consisting of
    wherein each R' is individually selected from the class consisting of hydrogen, C 1 -C 4 alkyl, C 2 -C 4 alkenyl, C 3 -C 7 cycloalkyl, benzyl or phenyl; a heterocyclic group selected from the class consisting of morpholine, pyrrolidine or piperidine: or a
    group wherein Z 1 is a
    group wherein R" is hydrogen, C 1 -C 4 alkyl or phenyl; a heterocyclic group selected from the class consisting of piperidine. pyrrolidine and morpholine.

    摘要翻译: 本发明涉及一类新的有机化合物。 更具体地说,本发明涉及N-膦酰硫基甲基甘氨酸酯的酰氨基和酰肼衍生物。 已经发现这类化合物可用作除草剂。 本发明的化合物是下式的化合物。 其中R为1〜8个碳原子的烷基,1〜4个碳原子的氯烷基和1〜3个氯原子的烷基和含3〜7个碳原子的烷氧基烷基,Z为 由CHEM组成的类的成员,其中每个R min分别选自氢,C 1 -C 4烷基,C 2 -C 4烯基,C 3 -C 7环烷基,苄基或苯基; 选自吗啉,吡咯烷或哌啶的杂环基; 或其中Z 1为CHEM基团的R 1基团,其中R sec为氢,C 1 -C 4烷基或苯基; 选自哌啶,吡咯烷和吗啉的杂环基。

    Amide and hydrazide derivatives of N-trifluoracetyl-N-phosphonomethylglycine, herbicidal compositions and their use
    8.
    发明公开
    Amide and hydrazide derivatives of N-trifluoracetyl-N-phosphonomethylglycine, herbicidal compositions and their use 失效
    N-三氟乙酰基-N-膦酰甲基甘氨酸的酰胺和酰肼衍生物,涉及除草组合物和它们的用途。

    公开(公告)号:EP0008852A1

    公开(公告)日:1980-03-19

    申请号:EP79301307.9

    申请日:1979-07-06

    申请人: MONSANTO COMPANY

    IPC分类号: C07F9/44 A01N57/26 C07F9/65

    摘要: This disclosure relates to alkyl N-trifluoroacetyl-N-phosphonomethylglycine amide and hydrazide derivatives, to herbicidal compositions containing same and to the herbicidal use thereof. These amide and hydrazide derivatives are useful as pre-emergent and/or post-emergent herbicides.
    The novel N-trifluoroacetyl-N-phosphonomethyl- glycinate amide and hydrazide derivatives of this invention are those havina the formula

    wherein R is an alkyl group of from 1 to 10 carbon atoms, a chloro lower alkyl group, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or a lower alkoxy lower alkoxy lower alkyl group containing from 5 to 9 carbon atoms, R' is hydrogen, lower alkyl, lower alkenyl or lower alkynyl, Z is a member of the class consisting of alkyl of from 1 to 6 carbon atoms, alkenyl of from 2 to 6 carbon atoms, alkynyl of from 3 to 6 carbon atoms, cycloalkyl containing from 3 to 7 carbon atoms or a R2 N - R 3 group wherein R 2 is lower alkyl, phenyl or substituted phenyl and R 3 is hydrogen or lower alkyl and together with the nitrogen atom R 2 and R 3 can form a heterocyclic ring.

    Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine and their herbicidal use
    9.
    发明公开
    Thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine and their herbicidal use 失效
    N-三氟乙酰基-N-膦酰甲基甘氨酸的硫代衍生物和它们作为除草剂的用途。

    公开(公告)号:EP0008158A1

    公开(公告)日:1980-02-20

    申请号:EP79301305.3

    申请日:1979-07-06

    申请人: MONSANTO COMPANY

    IPC分类号: C07F9/40 A01N57/18

    摘要: This disclosure relates to thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters, to herbicidal compositions containing same and to the herbicidal use thereof. The thio derivatives of N-trifluoroacetyl-N-phosphonomethylglycine esters are useful as herbicides.
    The novel N-trifluoroacetyl-N-phosphonomethyl-glycinate thio derivatives of this invention are those having the formula
    wherein R is an alkyl group containing from 1 to 10 carbon atoms, a chloro lower alkyl group containing from 1 to 4 carbon atoms and 1 to 3 chlorine groups, a lower alkoxy lower alkyl group containing from 3 to 6 carbon atoms or an alkoxyalkoxyalkyl group containing from 5 to 9 carbon atoms and R' is a member of the group consisting of lower alkylthio. lower alkenylthio, benzylthio, phenylthio, or substituted phenylthio wherein the phenyl group contains 1 to 2 substituents selected from the group consisting of halo, lower alkyl and lower alkoxy.

    Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof
    10.
    发明公开
    Derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates and the herbicidal use thereof 失效
    N-三氟乙酰基-N- phosphonomethylglycinat衍生物和它们作为除草剂的用途。

    公开(公告)号:EP0007211A1

    公开(公告)日:1980-01-23

    申请号:EP79301308.7

    申请日:1979-07-06

    申请人: MONSANTO COMPANY

    摘要: This disclosure relates to derivatives of N-trifluoroacetyl-N-phosphonomethylglycinates wherein different moieties are attached to the phosphorus atom, to herbicidal compositions containing same and to the herbicidal use thereof.
    The novel N-trifluoroacetyl-N- phosphonomethylglycinates of this invention are those having the formula
    wherein R is an alkyl group of from 1 to 10 carbon atoms or chlorinated lower alkyl group, R, is a member of the group consisting of lower alkoxy, lower alkylthio, phenoxy, phenylthio, substituted phenoxy, substituted phenylthio, lower alkylamino, lower dialkylamino, morpholino and N-piperidinoamino and R 2 is a member of the group consisting of lower alkylthio, phenoxy, phenylthio, substituted phenoxy, substituted phenylthio, lower alkylamino, lower dialkylamino, lower alkenylamino, lower dialkenylamino, lower alkynylamino, lower dialkynylamino, morpholino and N-piperidinoamino with the proviso that R, and R 2 cannot represent the same group.