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    Solid catalyst component for use in polymerization of alpha-olefins
    11.
    发明公开
    Solid catalyst component for use in polymerization of alpha-olefins 失效
    用于ALPHA-OLEFINS聚合的固体催化剂组分

    公开(公告)号：EP0446801A3

    公开(公告)日：1992-04-22

    申请号：EP91103566.5

    申请日：1991-03-08

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Sasaki, Toshio ,  Ebara, Takeshi ,  Kawai, Kiyoshi

    IPC分类号： C08F4/656 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6492

    摘要： A solid-catalyst component for use in the polymerization of α-olefins obtained by
       reducing a titanium compound represented by the following general formula:
            Ti(OR¹) n x 4-n
    wherein R¹ represents a hydrocarbon group having 1 to 20 carbon atoms, X represents a halogen atom and n represents a number satisfying 0
       treating the solid product with an ester compound,
       treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or with a mixture of an ether compound, titanium tetrachloride and an ester compound to obtain a trivalent titanium compound-containing solid catalyst precursor, and
       treating the solid catalyst precursor with a small quantity of an olefin in the presence of an organoaluminum compound to obtain a solid catalyst component for use in the polymerization of α-olefins.

    Solid catalyst component for use in polymerization of alpha-olefins
    12.
    发明公开
    Solid catalyst component for use in polymerization of alpha-olefins 失效
    Fester Katalysatorbestandteil zur Anwendung在α-烯烃聚合中。

    公开(公告)号：EP0446801A2

    公开(公告)日：1991-09-18

    申请号：EP91103566.5

    申请日：1991-03-08

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Sasaki, Toshio ,  Ebara, Takeshi ,  Kawai, Kiyoshi

    IPC分类号： C08F4/656 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6492

    摘要： A solid-catalyst component for use in the polymerization of α-olefins obtained by
       reducing a titanium compound represented by the following general formula:



            Ti(OR¹) n x 4-n



    wherein R¹ represents a hydrocarbon group having 1 to 20 carbon atoms, X represents a halogen atom and n represents a number satisfying 0
       treating the solid product with an ester compound,
       treating the ester-treated solid product with a mixture of an ether compound and titanium tetrachloride or with a mixture of an ether compound, titanium tetrachloride and an ester compound to obtain a trivalent titanium compound-containing solid catalyst precursor, and
       treating the solid catalyst precursor with a small quantity of an olefin in the presence of an organoaluminum compound to obtain a solid catalyst component for use in the polymerization of α-olefins.

    摘要翻译： 用于通过还原由以下通式表示的钛化合物获得的α-烯烃的固体催化剂组分：Ti（OR 1）n x4-n其中R 1表示具有1至20个的烃基 碳原子，X表示卤原子，n表示满足0

    Process for producing highly stereospecific alpha-olefin polymers
    14.
    发明公开
    Process for producing highly stereospecific alpha-olefin polymers 失效
    Verfahren zum Herstellen von alpha-Olefinpolymeren mit hoherStereospezifizität。

    公开(公告)号：EP0376084A2

    公开(公告)日：1990-07-04

    申请号：EP89123186.2

    申请日：1989-12-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Ebara, Takeshi ,  Sasaki, Toshio ,  Kawai, Kiyoshi

    IPC分类号： C08F4/646 ,  C08F4/656 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6465 ,  C08F4/6565

    摘要： A process for producing a highly stereospecific α-olefin polymer which comprises homopolymerizing or copolymerizing an α-olefin or copolymerizing an α-olefin with ethylene by the use of a catalyst system comprising:

    (A) a solid catalyst component containing a trivalent titanium compound obtained by reducing a titanium compound represented by the following general formula:
    Ti(OR¹) n x 4-n
    (R¹ represents a hydrocarbon group having 1 to 20 carbon atoms, X represents a halogen atom and n represents a number satisfying 0
    (B) an organoaluminum compound, and
    (C) a silicon compound represented by the following general formula:
    R²R³Si(OR⁴)₂
    (R² represents an alicyclic hydrocarbon group having 5 to 20 carbon atoms, R³ represents an acyclic hydrocarbon group having 2 to 12 carbon atoms, and R⁴ represents a hydrocarbon group having 1 to 20 carbon atoms).

    摘要翻译： 一种制备高立体定向α-烯烃聚合物的方法，其包括使α-烯烃均聚或共聚合或使α-烯烃与乙烯共聚的催化剂体系包括：（A）含有三价钛化合物的固体催化剂组分 通过还原由以下通式表示的钛化合物：Ti（OR 1）nx4-n（R 1表示具有1至20个碳原子的烃基，X表示卤素原子，n表示满足0的数） 在具有Si-O键的有机硅化合物的存在下与有机镁化合物反应，得到固体产物，然后用酯化合物处理固体产物，然后用 醚化合物和四氯化钛的混合物或醚化合物，四氯化钛和酯化合物的混合物，（B）有机铝化合物和（C）硅化合物代用品 由以下通式表示：R 2 R 3 Si（OR 4）2（R 2表示具有5至20个碳原子的脂环族烃基，R 3表示无环烃基，其具有 2〜12个碳原子，R 4表示碳原子数1〜20的烃基）。 Ø

    Catalyst system and process for producing alpha-olefin polymer
    17.
    发明公开
    Catalyst system and process for producing alpha-olefin polymer 失效
    Katalysatorsystem und Verfahren zur Herstellung von Alpha-Olefinpolymeren。

    公开(公告)号：EP0314169A1

    公开(公告)日：1989-05-03

    申请号：EP88118008.7

    申请日：1988-10-28

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Sasaki, Toshio ,  Jyohouji, Hirofumi ,  Ebara, Takeshi ,  Kawai, Kiyoshi

    IPC分类号： C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6425

    摘要： A process for producing an α-olefin polymer which comprises polymerizing an α-olefin in the presence of a catalyst system comprising

    (A) a solid catalyst component containing at least titanium, magnesium, halogen, and an electron donor and
    (B) a sterically hindered aluminum amide compound represented by the general formula
    wherein, R¹ through R⁵ denote each a hydrocarbon group of to 20 carbon atoms, L denotes an alkoxy group of 1 to 20 carbon atoms and/or halogen, ℓ is 2 or 3, x is defined by 0

    摘要翻译： 一种制备α-烯烃聚合物的方法，其包括在催化剂体系存在下聚合α-烯烃，所述催化剂体系包含（A）至少含有钛，镁，卤素和电子给体的固体催化剂组分和（B）空间位阻 由通式表示的受阻铝酰胺化合物，其中R 1至R 5各自表示20个碳原子的烃基，L表示1至20个碳原子的烷氧基和/或卤素， l是2或3，x由0

    Process for producing olefin polymer
    19.
    发明公开
    Process for producing olefin polymer 失效
    Verfahren zur Herstellung von Olefinpolymeren。

    公开(公告)号：EP0245854A1

    公开(公告)日：1987-11-19

    申请号：EP87106959.7

    申请日：1987-05-14

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Sasaki, Toshio ,  Ebara, Takeshi ,  Kawai, Kiyoshi ,  Shiga, Akinobu

    IPC分类号： C08F4/64 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/6465 ,  C08F4/6546

    摘要： A solid catalyst component containing a trivalent titanium compound, obtained by reducing a titanium com­pound represented by the general formula Ti(OR¹) n X 4-n (wherein R¹ is a hydrocarbon group of 1 to 20 carbon atoms, X is a halogen atom, and n is a number satisfying 0
    (A) said solid catalyst component, and
    (B) an organoaluminum compound; and
    a process for producing an olefin polymer, which comprises homopolymerizing an olefin or copolymerizing olefins using said catalyst system.

    摘要翻译： 一种含有三价钛化合物的固体催化剂组分，其通过还原由通式Ti（OR 1）n X 4-n表示的钛化合物（其中R 1是1至20个碳原子的烃基，X是 卤素原子，n为满足0

    Process for producing alpha-olefin polymers using novel catalyst system
    20.
    发明公开
    Process for producing alpha-olefin polymers using novel catalyst system 失效
    一种用于使用新的催化体系生产α-烯烃聚合物的方法。

    公开(公告)号：EP0132848A2

    公开(公告)日：1985-02-13

    申请号：EP84108885.9

    申请日：1984-07-26

    申请人： SUMITOMO CHEMICAL COMPANY, LIMITED

    发明人： Shiga, Akinobu ,  Sasaki, Toshio ,  Kojima, Junpei ,  Nunose, Akira

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F4/6492

    摘要： A process for producing an a-olefin polymer which comprises polymerizing an α-olefin in the presence of a catalyst system comprising

    (A) a solid catalyst component obtained by steps of

    i) reducing titanium tetrachloride with an organoaluminum compound represented by the general formula R 1 nAlY 3-n , wherein R' represents a C 1 -C 18 hydrocarbon group, Y represents a halogen, and n represents a number satisfying 1
    ii) heating the reduction product at a temperature of up to 150°C,
    iii) treating the thus obtained solid product containing y-titanium trichloride by preliminary polymerization of an α-olefin in the presence thereof, and
    iv) reacting the resulting solid product with a halogen represented by the general formula X 2 , wherein X represents Cl, Br, or I, and/or an interhalogen compound represented by the general formula X'X"a, wherein X' and X" represent each Cl, Br, or I and a represents 1 or 3, and with an ether compound represented by the general formula R 2 -O-R 3 , wherein R 2 and R' are the same or different and represent each a C 1 -C 10 alkyl group, in a hydrocarbon solvent at a temperature of 50° to 100°C, and

    (B) an organoaluminum compound.