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    PROCEDE DE PREPARATION DE PEROXYDES ORGANIQUES
    12.
    发明公开
    PROCEDE DE PREPARATION DE PEROXYDES ORGANIQUES 有权
    VERFAHREN ZUR HERSTELLUNG有机硅过氧化物

    公开(公告)号：EP3030546A1

    公开(公告)日：2016-06-15

    申请号：EP14747087.6

    申请日：2014-07-09

    申请人： Arkema France

    发明人： MAJ, Philippe ,  HUB, Serge

    IPC分类号： C07C407/00 ,  C07C409/16

    CPC分类号： C07C409/16 ,  B01J27/053 ,  B01J31/0225 ,  C07C407/00 ,  C07C407/003

    摘要： The invention relates to a method for preparing peroxide, including a step of treating, in a reaction medium, a component having at least one tertiary alcohol grouping with a compound having at least one tertiary hydroperoxide function in the presence of a catalyst, said method being characterised in that the catalyst includes a sulphonic acid and a inorganic acid, the molar ratio between the sulphonic acid and the aforementioned component including at least one tertiary alcohol grouping ranges from 0.05 to 0.8, and the molar ratio between the inorganic acid and the aforementioned component including at least one tertiary alcohol grouping ranges from 0.05 to 0.8. The invention also relates to the peroxide resulting directly from said preparation method.

    摘要翻译： 一种制备过氧化物的方法，包括在催化剂存在下，在反应介质中处理具有至少一个叔醇基团的组分与具有至少一个叔氢过氧化物功能的化合物的步骤的方法，其特征在于， 催化剂包括磺酸和无机酸，所述磺酸与包含至少一种叔醇基团的上述组分的摩尔比在0.05至0.8范围内，并且所述无机酸与上述组分的摩尔比包括至少一种 叔醇分数范围为0.05至0.8。 而且，直接由所述制备方法得到的过氧化物。

    Dialkyl peroxide, cross-linking composition containing the same, method for cross-linking, and electric power cable
    18.
    发明公开
    Dialkyl peroxide, cross-linking composition containing the same, method for cross-linking, and electric power cable 失效
    二烷基过氧化物，交联剂含有它们的剂的组合物，用于交联和电缆的方法。

    公开(公告)号：EP0579434A1

    公开(公告)日：1994-01-19

    申请号：EP93305277.1

    申请日：1993-07-06

    申请人： NOF CORPORATION

    发明人： Suyama, Shuji ,  Ishigaki, Hideyo ,  Matsushima, Masaru ,  Naito, Satoshi ,  Ooto, Noriyoshi ,  Okada, Hiroshi

    IPC分类号： C07C409/16

    CPC分类号： H01B3/441 ,  C07C409/16 ,  C08K5/14 ,  C08L23/04

    摘要： A novel dialkyl peroxide is disclosed which is represented by the formula:

    wherein R₁ and R₂ independently stand for a hydrogen atom or a methyl group, R₃ stands for an alkyl group of 1 to 5 carbon atoms, X stands for an alkylene group of 1 to 3 carbon atoms, -C(O)-, -CH₂-(O-CH₂-CHR₄) m -OC(O)- [wherein R₄ stands for a hydrogen atom or a methyl group and m stands for an integer in the range of 0 to 10], or -C(O)-(O-CH₂-CHR₅) n -OC(O)- (wherein R₅ stands for a hydrogen atom or a methyl group and n stands for an integer in the range of 1 to 10). A composition for the production of a cross-linked ethylene type polymer comprises the dialkyl peroxide and an ethylene type polymer. An electric power cable excelling in electrical characteristics (AC breakdown strength) comprises a conductor and a resin layer deposited on the periphery of the conductor and formed of a cross-linked ethylene type polymer obtained by using the dialkyl peroxide as a cross-linking agent.

    摘要翻译： 一种新颖的二烷基过氧化物是圆盘游离缺失所有其由下式表示： worin R1和R2unabhängig代表氢原子或甲基，R 3代表在烷基的1至5个碳原子，X代表在亚烷基组 1至3个碳原子的，-C（O） - ， - CH 2 - （O-CH 2 CHR 4）M-OC（O） - [worin R 4代表氢原子或甲基，m表示在整数 的0至10]，或（O）-C的范围 - （O-CH 2 CHR 5）N-OC（O） - （R5 worin表示氢原子或甲基，n的范围内代表整数 的1〜10）。 一种用于生产交联的乙烯类聚合物的组合物包括二烷基过氧化物和以乙烯类聚合物。 一种电力电缆的电学特性（AC击穿强度）优异包括导体和沉积在导体的外周形成，通过使用二烷基过氧化物作为交联剂获得的交联的乙烯类聚合物的树脂层。