公开(公告)号：EP3013795A1

公开(公告)日：2016-05-04

申请号：EP14737092.8

申请日：2014-06-06

申请人： ExxonMobil Chemical Patents Inc.

发明人： DAVIS, Jason, D. ,  BECKER, Christopher, L. ,  REINE, Travis, A. ,  PATEL, Bryan, A.

IPC分类号： C07C407/00 ,  C07C409/14

CPC分类号： C07C407/00 ,  C07C29/132 ,  C07C37/08 ,  C07C45/53 ,  C07C407/003 ,  C07C2601/14 ,  C07C409/14 ,  C07C39/04 ,  C07C49/403 ,  C07C409/02

摘要： Method for concentrating an organic hydroperoxide mixture comprising a hydrocarbon and a hydroperoxide corresponding thereto comprises evaporating a first liquid mixture in a thin-film evaporation device followed by separation in a separation zone. Both the evaporation device and the separation zone operate at a low absolute pressure at a temperature lower than the thermal degradation temperature of the hydroperoxide to prevent thermal decomposition thereof. The process is particularly useful for concentrating an oxidation product made from the oxidation of cyclohexylbenzene.

摘要翻译： 用于浓缩包含对应于其的烃和氢过氧化物的有机氢过氧化物混合物的方法包括在薄膜蒸发装置中蒸发第一液体混合物，然后在分离区中分离。 蒸发装置和分离区都在低于氢过氧化物的热降解温度的温度下在低绝对压力下操作，以防止其分解。 该方法对于浓缩由环己基苯氧化制得的氧化产物特别有用。

公开(公告)号：EP2044014B1

公开(公告)日：2010-08-18

申请号：EP07786751.3

申请日：2007-06-18

申请人： United Initiators GmbH & Co. KG

发明人： APPEL, Hans ,  MEICHELBÖCK, Wilfried ,  WEINMAIER, Josef, Helmut ,  ZELLNER, Helmut

IPC分类号： C07C407/00 ,  C07C409/38

CPC分类号： C07C407/00 ,  C07C407/003 ,  C07C409/38

公开(公告)号：EP1757581A1

公开(公告)日：2007-02-28

申请号：EP06254363.2

申请日：2006-08-18

申请人： Air Products and Chemicals, Inc.

发明人： Syvret, Robert George ,  Campion, Beth Ann ,  Cooper, Gregory Alan

IPC分类号： C07C409/16 ,  C07C407/00

CPC分类号： C07C409/16 ,  C07C407/00 ,  C07C407/003 ,  C07C409/22

摘要： High-purity fluorinated peroxides are prepared in a simplified process in which carbonyl fluoride is reacted with a hypofluorite to produce a gaseous reaction product which is essentially free of unreacted hypofluorite; unreacted carbonyl fluoride and by productsare removed from the gaseous reaction product under gas phase conditions; and then the fluorinated peroxideis collected in gas phase.

摘要翻译： 以简化的方法制备高纯度氟化过氧化物，其中使氟化碳与次氟酸盐反应以产生基本上不含未反应的次氟酸盐的气态反应产物; 未反应的碳酰氟和产物在气相条件下从气态反应产物中除去; 然后在气相中收集氟化过氧化物。

公开(公告)号：EP1648863A2

公开(公告)日：2006-04-26

申请号：EP04777728.9

申请日：2004-07-08

申请人： CHEMTURA CORPORATION

发明人： FRENKEL, Peter ,  NWOKO, Delphine ,  BOCK, Lawrence, A. ,  ANDREWS, Anthony

IPC分类号： C07C407/00 ,  C07C409/16

CPC分类号： C07C407/003 ,  C07C409/16

摘要： A process is disclosed for reducing the concentration of a dialkyl ether in a mixture comprising the dialkyl ether and a dialkyl peroxide wherein the process comprises treating said mixture with a strong acid.

公开(公告)号：EP1345894A1

公开(公告)日：2003-09-24

申请号：EP01991866.3

申请日：2001-12-17

申请人： SHELL INTERNATIONALE RESEARCHMAATSCHAPPIJ B.V.

发明人： MESTERS, Carolus, Matthias, Anna, Maria

IPC分类号： C07C407/00 ,  C07D301/19

CPC分类号： C07D301/19 ,  C07C407/00 ,  C07C407/003 ,  C07C407/006 ,  C07C409/08 ,  C07C409/10

摘要： Process for preparing organic hydroperoxide having a reduced content of contaminants, which process comprises: (a) oxidation of an organic compound to obtain reaction product containing an organic hydroperoxide, (b) contacting at least part of the organic hydroperoxide containing reaction product with a basic aqueous solution, (c) separating the hydrocarbonaceous phase containing organic hydroperoxide from the aqueous phase, (d) washing at least part of the separated hydrocarbonaceous phase containing organic hydroperoxide, and (e) contacting at least part of the hydrocarbonaceous phase containing organic hydroperoxide with a guard bed comprising solid adsorbent having a void content of from 50% to 98% by volume.

公开(公告)号：EP1247802A1

公开(公告)日：2002-10-09

申请号：EP02396042.0

申请日：2002-04-04

申请人： KEMIRA CHEMICALS OY

发明人： Pohjanvesi, Seppo ,  Pukkinen, Arto ,  Södervall, Teemu

IPC分类号： C07C409/26 ,  C07C407/00

CPC分类号： C07C407/006 ,  C07C407/00 ,  C07C407/003 ,  C07C409/26

摘要： The reaction medium and distillate of a conventional continuous peracetic acid process can be combined into a stable peracetic acid product if the acid catalyst present in the reaction medium is neutralized.

摘要翻译： 通过将馏出物，反应介质和部分中和酸催化剂的物质聚集在一起生产过乙酸产物。 过乙酸产物的制备包括将过氧化氢和乙酸连续加入到含有过氧化氢，乙酸，过乙酸和酸催化剂的水性反应介质中，其中过氧化氢和乙酸反应并形成过乙酸。 从反应介质中连续蒸馏过乙酸浓缩的含水馏分。 将馏出物，反应介质和部分中和酸催化剂的物质聚集在一起。 还包括一个独立的权利要求，用于使碱稳定含有比过乙酸更强的另一种酸的酸性过乙酸。

公开(公告)号：EP0974581A4

公开(公告)日：2002-01-02

申请号：EP98941863

申请日：1998-09-14

申请人： DAICEL CHEM

发明人： MATSUDA HIROKAZU ,  TAKEMOTO ETSUO

IPC分类号： C07C409/24 ,  C07C409/26 ,  C07C407/00 ,  C07C409/00 ,  C07D313/04 ,  C07D315/00

CPC分类号： C07D315/00 ,  C07C407/00 ,  C07C407/003 ,  C07C409/24 ,  C07C409/26 ,  Y02P20/127

摘要： A process for preparing an equilibrium peroxy acid by the reaction of hydrogen peroxide with a carboxylic acid while removing the formed water in a reactive distillation device, the contents of the water and hydrogen peroxide in the acid being each 1.5 % by weight or less; and a process for producing a lactone by the reaction between the peroxy acid thus obtained and a cyclic ketone, which permits the selectivity of the lactone to be improved without lowering the activity of the ketone at an early stage of conversion.

公开(公告)号：EP1107952A1

公开(公告)日：2001-06-20

申请号：EP99942457.5

申请日：1999-08-25

申请人： E.I. DUPONT DE NEMOURS AND COMPANY

发明人： DRULINER, Joe, Douglas ,  KOB, Nicholas, Edward, III ,  LANE, Samuel, Livingston ,  STOWE, Gerald, Thomas

IPC分类号： C07C407/00 ,  C07C409/14 ,  C07C45/53 ,  C07C49/403 ,  C07C29/132 ,  C07C35/08

CPC分类号： C07C407/003 ,  C07C29/132 ,  C07C45/53 ,  C07C2601/14 ,  C07C35/08 ,  C07C49/403 ,  C07C409/06

摘要： An improved process for decomposing alkyl or aromatic hydroperoxides to form a decomposition reaction mixture containing the corresponding alcohol and ketone is disclosed. The improvement relates to adding water to a starting hydroperoxide containing mixture, then removing the bulk of said water by a means such that water-soluble impurities are removed along with the water, then decomposing the hydroperoxide by contacting the hydroperoxide with a catalytic amount of a heterogeneous catalyst of Au, Ag, Cu or a sol-gel compound containing particular combinations of Cr, Co, Zr, Ta, Si, Mg, Nb, Al and Ti wherein certain of those metals have been combined with an oxide, such as an inorganic matrix of hydroxides or oxides, or combinations thereof. The catalysts may also optionally be supported on a suitable support member.

摘要翻译： 公开了一种改进的分解烷基或芳族氢过氧化物以形成含有相应的醇和酮的分解反应混合物的方法。 改进涉及将水加入含氢过氧化物的起始混合物中，然后通过使水溶性杂质与水一起除去的手段除去大部分所述水，然后通过使氢过氧化物与催化量的 含有Cr，Co，Zr，Ta，Si，Mg，Nb，Al和Ti的特定组合的Au，Ag，Cu或溶胶 - 凝胶化合物的非均相催化剂，其中某些金属已经与氧化物例如 氢氧化物或氧化物的无机基质，或其组合。 催化剂还可以任选地被支撑在合适的支撑构件上。

公开(公告)号：EP1066233A1

公开(公告)日：2001-01-10

申请号：EP99908164.9

申请日：1999-02-16

申请人： INDSPEC CHEMICAL CORPORATION

发明人： DURAIRAJ, Raj, B. ,  ROMELL, Vaughn, J. ,  TACKIE, Michael, N. ,  VOLEK, Thomas, K.

IPC分类号： C07C37/60

CPC分类号： C07C407/003 ,  C07C29/132 ,  C07C37/08 ,  C07C33/26 ,  C07C409/12 ,  C07C39/08

摘要： Improved methods for the simultaneous production of dihydroxybenzene and dicarbinol from diisopropylbenzene are provided. These methods provide for continuous and simultaneous production of DHP and HHP using Karr Column extractors operated in series. A very purity DHP-containing solution, the precursor to the dihydroxybenzene, can be produced according to the reported methods. A safe and efficient method for producing dicarbinol from HHP is also disclosed.

公开(公告)号：EP1064261A1

公开(公告)日：2001-01-03

申请号：EP99908636.6

申请日：1999-03-03

申请人： Huntsman Specialty Chemicals Corporation

发明人： CULBRETH, William, K., III ,  TAYLOR, Mark, E. ,  PRESTON, Kyle, L. ,  MUELLER, Mark, A.

IPC分类号： C07C409/04 ,  C07C407/00 ,  C07C29/50 ,  C07C31/12 ,  C07C409/14 ,  C07C409/08

CPC分类号： C07C409/14 ,  B01J10/002 ,  B01J2219/00006 ,  C07C29/50 ,  C07C407/00 ,  C07C407/003 ,  C07C409/04 ,  C07C409/08 ,  C07C2601/14 ,  C07C31/12

摘要： Peroxides are prepared from organic compounds and oxygen in a reaction vessel by introducing organic compound and oxygen to the reaction vessel and by simultaneously withdrawing a first liquid product stream from adjacent the top of the reactor and a second liquid product stream from adjacent the bottom of the reaction vessel. Suitable organic compounds include, but are not limited to, alkanes and alkyl aryl compounds.

摘要翻译： 过氧化物由有机化合物和氧气在反应容器中通过将有机化合物和氧气引入反应容器中并同时从邻近反应器的顶部排出第一液体产物流，并且从邻近反应器的底部的第二液体产物流 反应容器 合适的有机化合物包括但不限于烷烃和所有芳基化合物。