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    STYRYL SULFIDE DYES
    16.
    发明授权
    STYRYL SULFIDE DYES 有权
    STYRYL SULFIDE染料

    公开(公告)号：EP1893695B1

    公开(公告)日：2009-07-22

    申请号：EP06763543.3

    申请日：2006-06-07

    申请人： Ciba Holding Inc.

    发明人： ELIU, Victor, Paul ,  FRÖHLING, Beate ,  KAUFFMANN, Dominique

    IPC分类号： C09B23/14 ,  C09B49/00 ,  A61Q5/10

    CPC分类号： C09B23/14 ,  A61K8/4926 ,  A61Q5/10 ,  C09B23/145 ,  C09B49/00

    摘要： Disclosed are styryl sulfide dyes of formula (1), wherein R1, R'1, R2, R'2, R3 and R'3, independently from each other are hydrogen; C1-C20alkyl or C1- C20alkoxy, which may be substituted by one or more C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, -NO2 or hydroxy; C3-C6cycloalkyl; -C(O)H; -C(O)-C1-C5alkyl; halogen; NO2; OH; phenyl, which may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, -NO2 or hydroxy; or a radical of formula -NR4R5, wherein R4 and R5 independently from each other are hydrogen; C1-C12alkyl, which may be substituted by one or more C1-C5alkyl, C1-C5-alkoxy, hydroxy or -(CO)-H; -(CO)-C1-C5alkyl; phenyl or phenyl-C1-C4alkyl, wherein the phenyl moiety may be substituted by one or more C1-C5alkyl, C1-C5alkoxy, halogen, -NH2, mono-C1-C5alkylamino, di-C1-C5alkylamino, -NO2, carboxy or hydroxy; W1, W'1, W2, W'2, W3, W'3, W4 or W'4, independently from each other are -CH- or -N+-; wherein only one of W1/W'1, W2/W'2, W3/W'3, W4/W4' is -N+; and the bivalent radical -Q-Z-Y-S-S-Y'-Z'-Q'- is bonded to W1 or W2 and W'1 or W'2 respectively; Y1 and Y2 independently from each other are C1-C10alkylene; C5-C10cycloalkylene; C5-C12arylene; or C5-C12arylene-(C1-C10alkylene); Q and Q' independently from each other are the direct bond; or -C(O)-; -C(O)O-; -OCO-; -N(R6)-; formula (AA); -C(O)N(R6)-; -(R6)NC(O)-; -O-; -S-; -S(O)-; or -S(O)2-; and R6 and R7 independently from each other are hydrogen; C1-C14alkyl; C2-C14alkenyl; C6- C12aryl; C6-C12aryl-C1-C10alkyl; or C1-C10alkyl(C5-C12aryl). Further, the present invention relates to novel styryl sulfide compounds, compositions thereof, especially comprising other dyes, and to processes for their preparation.

    摘要翻译： 公开了式（1）的苯乙烯基硫醚染料，其中R 1，R'1，R 2，R'2，R 3和R'3彼此独立地为氢; C1-C20烷基或C1-C20烷氧基，其可以被一个或多个C1-C5烷氧基，卤素，-NH2，单-C1-C5烷基氨基，二-C1-C5烷基氨基，-NO2或羟基取代; C3-C6环烷基; -C（O）H; -C（O）-C 1 -C 5烷基; 卤素; NO2; 哦; 可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，单-C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2或羟基取代的苯基; 或式-NR4R5的基团，其中R4和R5彼此独立地为氢; 可以被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，羟基或 - （CO）-H取代的C 1 -C 12烷基; - （CO）-C 1 -C 5烷基; 苯基或苯基-C 1 -C 4烷基，其中苯基部分可被一个或多个C 1 -C 5烷基，C 1 -C 5烷氧基，卤素，-NH 2，单-C 1 -C 5烷基氨基，二-C 1 -C 5烷基氨基，-NO 2，羧基或羟基 ; W1，W'1，W2，W'2，W3，W'3，W4或W'4彼此独立地为-CH-或-N + - ; 其中W1 / W'1，W2 / W'2，W3 / W'3，W4 / W4'中只有一个是-N + 并且二价基团-Q-Z-Y-S-S-Y'-Z'-Q'-分别与W1或W2和W'1或W'2键合; Y1和Y2彼此独立地为C1-C10亚烷基; C5-C10cycloalkylene; C5-C12arylene; 或C 5 -C 12亚芳基 - （C 1 -C 10亚烷基）; Q和Q'彼此独立的是直接债券; 或-C（O） - ; -C（O）O-; -OCO-; -N（R 6） - ; 公式（AA）; -C（O）N（R 6） - ; - （R 6）NC（O） - ; -O-; -S-; -所以）-; 或-S（O）2 - ; 且R6和R7彼此独立地为氢; C1-C 1-4烷基; C2-C14alkenyl; C 6 -C 12芳基; C6-12芳基-C 1 -C 10烷基; 或C 1 -C 10烷基（C 5 -C 12芳基）。 此外，本发明涉及新颖的苯乙烯基硫醚化合物，其组合物，特别是包含其它染料，及其制备方法。

    FLUORESCENT DYES
    20.
    发明公开
    FLUORESCENT DYES 审中-公开
    FLUORESZENZFARBSTOFFE

    公开(公告)号：EP1973973A2

    公开(公告)日：2008-10-01

    申请号：EP06845749.8

    申请日：2006-12-19

    申请人： Corning Incorporated

    发明人： GASPER, Susan, M. ,  HE, Mingqian ,  LAI,Fang ,  LESLIE, Thomas, M. ,  SAMSON, Helen

    IPC分类号： C09B23/10 ,  C09B23/14 ,  G01N33/52

    CPC分类号： C07D277/64 ,  C09B23/105 ,  C09B23/145 ,  G01N33/582

    摘要： Fluorescent dyes useful for detecting a target material in biological assays an electron donating moiety which is linked by a conjugated π-electron bridge to an electron accepting moiety. The π-electron bridge includes at least one carbocyclic ring structure or heterocyclic ring structure. The electron accepting moiety is a carboxylic acid, a salt of a carboxylic acid, or has the formula (I) wherein X8 is selected from the group consisting of H, CH3, and (CH2)n6-Z2-, where Z2- is a monovalent anion; and n6 is an integer from 1 through 10; and Q3 is O or S.