摘要:
Method for performing a Fischer-Tropsch process using as a catalyst (precursor) an iron-containing layered material selected from the group consisting of layered materials in which iron is present in the layered structure as divalent and/or trivalent metal (group 1), iron-doped layered materials (group 2), calcined iron-doped layered materials (group 3), and calcined layered materials in which iron is present in the layered structure as divalent metal (group 4). The term "layered material" includes anionic clays, layered hydroxy salts, cationic clays, and cationic layered materials.
摘要:
Method for performing a Fischer-Tropsch process using as a catalyst (precursor) an iron-containing layered material selected from the group consisting of layered materials in which iron is present in the layered structure as divalent and/or trivalent metal (group 1), iron-doped layered materials (group 2), calcined iron-doped layered materials (group 3), and calcined layered materials in which iron is present in the layered structure as divalent metal (group 4). The term 'layered material' includes anionic clays, layered hydroxy salts, cationic clays, and cationic layered materials.
摘要:
The present invention provides a method for testing the accessibility of porous materials with regard to large, often high-molecular weight compounds and correlating said accessibility to the porous material's accessibility under conditions of use, i.e. the application conditions.
摘要:
A process for preparing a catalyst is disclosed. The process generally comprises the steps of: (a) preparing a slurry comprising clay, zeolite, a sodium-free silica source, quasi-crystalline boehmite, and micro-crystalline boehmite, provided that the slurry does not comprise peptized quasi-crystalline boehmite; (b) adding a monovalent acid to the slurry; (c) adjusting the pH of the slurry to a value above about 3, and (d) shaping the slurry to form particles. This process results in attrition resistant catalysts with a good accessibility.
摘要:
Fluid catalytic cracking process comprising the steps of (a) preparing a physical 5 mixture comprising (i) aluminium trihydrate and/or flash-calcined aluminium trihydrate and (ii) a divalent metal oxide, hydroxide, carbonate, or hydroxycarbonate, (b) shaping the physical mixture of step a) to form fluidisable particles, and (c) adding the fluidisable particles obtained from step b) or step c) to a fluid catalytic cracking unit. In this FCC process, active sites of the catalyst composition are formed in-situ, i.e. in the FCC unit, without requiring peptisation, aging, or calcination steps prior to the addition of the composition to the hydrocarbon conversion unit.
摘要:
Process for the preparation of an additive-containing anionic clay comprising the steps of (a) milling a physical mixture of a divalent metal compound and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800°C, and (c) hydrating the calcined mixture in aqueous suspension, wherein an additive is present in the physical mixture and/or the aqueous suspension of step (c). With this process additive-containing anionic clays with a homogeneous additive distribution can be prepared.
摘要:
Metal-containing composition and use thereof in catalytic reactions, which metal-containing composition is obtainable by contacting a metal hydroxy salt with a solution comprising one or more pH-dependent anions selected from the group consisting of pH-dependent boron-containing anions, vanadium-containing anions, tungsten-containing anions, molybdenum-containing anions, iron-containing anions, niobium-containing anions, tantalum-containing anions, aluminium-containing anions, and gallium-containing anions.