摘要:
The Invention relates to a nitrogen oxide storage catalyst composed of at least two catalytically active washcoat layers on a support body, wherein a lower washcoat layer A comprises cerium oxide, an alkaline earth metal compound and/or an alkali compound, platinum and palladium, and manganese oxide, and an upper washcoat layer B disposed on the washcoat layer A comprises cerium oxide, platinum and palladium and does not contain any alkali and alkaline-earth compounds, and to a method for converting NOx in exhaust gases from motor vehicles which are operated with lean-burn engines.
摘要:
An oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from a diesel engine, wherein the oxidation catalyst comprises: a first layer comprising a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component and a combination of a platinum (Pt) component and palladium (Pd) component; an alkaline earth metal component; and a support material comprising alumina doped with silica, wherein the alkaline earth metal component is supported on the support material; a second layer comprising a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; and a substrate, which is a flow-through monolith; wherein: the first layer is disposed on the substrate, the second layer is disposed on the first layer, and the first layer is different in composition to the second layer; and the total amount of the alkaline earth metal component is 0.35 to 17.66 gL- (10 to 500 gft- ).
摘要:
To provide a catalyst having hydrotreatment (hydrogenation, desulfurization and denitrification) performance that is equal to or superior to the prior art, as a hydrotreating catalyst for hydrocarbon oils, and a hydrotreating process for hydrocarbon oils using the catalyst. The catalyst comprises 10 to 40 mass % of at least one element of Group 6 of the Periodic Table, 0.5 to 15 mass % of at least one element of Groups 8 to 10 of the Periodic Table based on the oxide catalysts, and a 0.05- to 3-fold amount of an organic additive with respect to the total number of moles of the elements of Group 6 and Groups 8 to 10 of the Periodic Table, added to an inorganic porous support composed mainly of silica-alumina that comprises an oxide of a metal of Group 2 of the Periodic Table.
摘要:
A catalyst precursor composition and methods for making such a catalyst precursor are disclosed. The catalyst precursor comprises at least a promoter metal selected from Group VIII, Group IIB, Group IIA, Group IVA and combinations thereof having an oxidation state of +2 or +4, at least one Group VIB metal having an oxidation state of +6, and at least one organic oxygen-containing ligand. Catalysts prepared from the sulfidation of such catalyst precursors are used in the hydroprocessing of hydrocarbon feeds.
摘要:
The present invention relates to a hydrocarbon conversion process comprising contacting a hydrocarbon feed stream with a hydrocarbon conversion catalyst, wherein the hydrocarbon conversion catalyst comprises a first composition comprising a dehydrogenation active metal on a solid support; and a second composition comprising a transition metal and a doping agent on an inorganic support, wherein the doping agent is selected from zinc, gallium, indium, lanthanum, and mixtures thereof.
摘要:
The present invention relates to a method for preparing acrylic acid, more specifically to a method for preparing acrylic acid under the neutral condition at high yield in a short time without using a base, which can be performed under the neutral condition without using the base, unlike the prior art in which base is essentially used, by producing acrylic acid using the supported catalyst having a specific composition when preparing acrylic acid by oxidation of allyl alcohol. Particularly, the preparation method of the present invention can recover acrylic acid rather than acrylic acid salt as a final product, and thus has an advantage that the overall process cost can be reduced by eliminating essential processes in the prior art, such as ion exchange after the acidification process required for the conversion of acrylic acid salt to acrylic acid.
摘要:
An oxidation catalyst for treating carbon monoxide (CO) and hydrocarbons (HCs) in exhaust gas from a diesel engine, wherein the oxidation catalyst comprises: a first layer comprising a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component and a combination of a platinum (Pt) component and palladium (Pd) component; an alkaline earth metal component; and a support material comprising alumina doped with silica, wherein the alkaline earth metal component is supported on the support material; a second layer comprising a platinum group metal (PGM) component selected from the group consisting of a platinum (Pt) component, a palladium (Pd) component and a combination thereof; and a substrate, which is a flow-through monolith; wherein: the first layer is disposed on the substrate, the second layer is disposed on the first layer, and the first layer is different in composition to the second layer; and the total amount of the alkaline earth metal component is 0.35 to 17.66 gL- (10 to 500 gft- ).
摘要:
A method of producing an oxide of manganese including reacting, in a first aqueous solution, a manganese salt and an alkali agent to form manganese hydroxide; separating the manganese hydroxide from the first solution; mixing the manganese hydroxide into an aqueous medium to form a manganese hydroxide suspension; mixing the manganese hydroxide suspension with alkali metal hydroxide to form a second aqueous solution; and oxidizing the manganese hydroxide in the second aqueous solution to form an oxide of manganese. The dried oxide of manganese includes birnessite, a maximum of 20% hausmannite, and a maximum of 10% feitknechtite, may further include a maximum of 400 ppm of anions, may have a specific surface area of at least 25 m2/g, and may have an average oxidation state of greater than 3.5.
摘要:
The present invention is directed to a method for producing a regeneration catalyst for a working solution usable for producing hydrogen peroxide by an anthraquinone method, wherein active alumina is treated with a 20% by weight to saturated aqueous solution of a magnesium salt, treated with ammonia and then burned; and is also directed to a regeneration catalyst produced by the method.
摘要:
The present invention relates to a process for conversion of a hydrocarbon feed comprising saturated hydrocarbon compounds to olefin products comprising contacting a hydrocarbon feed stream with a catalyst in an oxidic form of the formula M1M2M3M4O comprising metals M1, M2, M3 and M4, wherein: M1 is selected from Si, Al, Zr, and mixtures thereof; M2 is selected from Pt, Cr, and mixtures thereof; M3 is selected from W, Mo, Re, and mixtures thereof; and M4 is selected from Sn, K, Y, Yb and mixtures thereof; wherein: mass fraction of M1 is in the range of 0.1 to 0.8; mass fraction of M2 is in the range of 0.001 to 0.2; mass fraction of M3 is in the range of 0.001 to 0.2; mass fraction of M4 is in the range of 0.0001 to 0.2; and mass fraction of oxygen is in the range of 0.1 to 0.8.