BIODEGRADABLE POLYESTER AND USE THEREOF
    21.
    发明公开

    公开(公告)号:EP3660071A1

    公开(公告)日:2020-06-03

    申请号:EP18870723.6

    申请日:2018-06-26

    IPC分类号: C08G63/183 C08G63/78 C08J5/18

    摘要: Disclosed are a biodegradable polyester and the use thereof, said biodegradable polyester comprising: A) an acid component comprising the following repeating units: 40-48 mol% of terephthalic acid A1; 38.5-50 mol% of sebacic acid A2; and 2-20 mol% of aliphatic dibasic acid A3 having a carbon chain length with less than or equal to 6 carbons; and B) a butanediol. With a low content of terephthalic acid, the introduction of the aliphatic dibasic acid monomer having a carbon chain length with less than or equal to 6 carbons sensibly improves the mechanical property of the material, specifically, when storing the material in a humid environment so as to maintain the good mechanical property retention rate.

    POLYTEREPHTHALATE-CO-SEBACATE RESIN COMPOSITION

    公开(公告)号:EP3553130A1

    公开(公告)日:2019-10-16

    申请号:EP17881804.3

    申请日:2017-11-30

    IPC分类号: C08L67/02 C08K5/01

    摘要: The present invention discloses a poly(terephthalate-co-sebacate) resin composition, comprising the following components: a. poly(terephthalate-co-sebacate); and b. an alkane, which is at least one selected from the group consisting of hexadecane, heptadecane, octadecane, nonadecane and eicosane; wherein a weight content of the alkane is 5ppm-1000ppm based on a total weight of the poly(terephthalate-co-sebacate) resin composition. The present invention controls the content of alkane in the composition within a range of 5ppm-1000ppm by adding an alkane, which not only enables the poly(terephthalate-co-sebacate) resin to have obviously improved blow molding properties, a film thickness range of less than 0.3 µm, and a relative deviation of film thickness of less than 2.0%, thereby guaranteeing a bubble stability and a continuity of blow molding, but also enables the film material to prevent the ink from stripping off the film material, and to prevent excessive ink from adhering to the film material in the printing process, so that the film shows excellent printing performance.

    POLYLACTIC ACID 3D PRINTING MATERIAL AND PREPARATION METHOD THEREFOR

    公开(公告)号:EP3808813A1

    公开(公告)日:2021-04-21

    申请号:EP19820285.5

    申请日:2019-05-28

    IPC分类号: C08L67/04 C08K5/20 C08K5/098

    摘要: The present invention relates to a polylactic acid 3D printing material and a preparation method thereof, which belong to the technical field of polymer materials. The polylactic acid 3D printing material of the present invention comprises the following preparation raw materials in parts by weight: (a) 40-95 parts of crystalline or semi-crystalline polylactic acid, (b) 5-60 parts of noncrystalline polylactic acid, and (c) 0-1.0 parts of a processing aid. In the polylactic acid 3D printing material, a weight of dextral polylactic acid represents 0.5%-8% of a total weight of the polylactic acid. According to the present invention, a polylactic acid 3D printing material with a good aging resistance property can be obtained, by selecting and using two kinds of polylactic acids with different optical purities as raw materials, rationally distributing the proportional relationship between the two, and defining the content of dextral polylactic acid. Studies show that the viscosity retention rate of the polylactic acid 3D printing material of the present invention reaches 70% or more after storage in a constant-temperature and -humidity chamber (at a temperature at 60°C and a humidity of 60%) for 12 days.

    BIO-DEGRADABLE POLYESTER COMPOSITION
    27.
    发明公开
    BIO-DEGRADABLE POLYESTER COMPOSITION 审中-公开
    生物可降解聚酯组合物

    公开(公告)号:EP3296360A1

    公开(公告)日:2018-03-21

    申请号:EP17764498.6

    申请日:2017-03-01

    IPC分类号: C08L67/02

    摘要: The present invention discloses a biodegradable polyester composition, wherein based on a total weight of the biodegradable polyester composition, a weight content of glycidyl methacrylate is 0.05ppm-10ppm. In the present invention, by adding a trace amount of glycidyl methacrylate into a chosen formula of the biodegradable polyester composition and controlling the weight content of glycidyl methacrylate which finally remains in the biodegradable polyester composition as 0.05ppm-10ppm, a compatibility between aliphatic-aromatic polyester and polylactic acid in the biodegradable polyester composition can be greatly enhanced, which enables the biodegradable polyester composition to have excellent surface property of film material, and no fisheye occurs on the film material because of a fluctuation of processing technique.

    摘要翻译: 本发明公开了一种生物可降解聚酯组合物,其中基于生物可降解聚酯组合物的总重量,甲基丙烯酸缩水甘油酯的重量含量为0.05ppm-10ppm。 在本发明中,通过在选择的生物降解性聚酯组合物中添加微量的甲基丙烯酸缩水甘油酯,将最终残留于生物降解性聚酯组合物中的甲基丙烯酸缩水甘油酯的重量含量控制在0.05ppm〜10ppm,脂肪族 - 芳香族 可生物降解的聚酯组合物中的聚酯和聚乳酸可以大大增强,这使得可生物降解的聚酯组合物具有优异的膜材料表面性能,并且由于加工技术的波动,在膜材料上不会发生鱼眼。

    METHOD FOR PREPARING POLY (DIPHENYL ETHER SULFONE) AND POLY (DIPHENYL ETHER DIPHENYL SULFONE) TERNARY POLYMER
    28.
    发明公开
    METHOD FOR PREPARING POLY (DIPHENYL ETHER SULFONE) AND POLY (DIPHENYL ETHER DIPHENYL SULFONE) TERNARY POLYMER 有权
    制备聚(二苯基醚砜)和聚(二苯基醚二苯基砜)三元共聚物的方法

    公开(公告)号:EP2444446A1

    公开(公告)日:2012-04-25

    申请号:EP10838508.9

    申请日:2010-12-10

    IPC分类号: C08G75/23

    CPC分类号: C08G75/23

    摘要: A method for preparing series of terpolymer of poly (diphenyl ether sulfone) and poly (diphenyl ether diphenyl sulfone) comprises: adding high temperature organic solvent, stirring and heating; sequentially adding 4,4'-dihydroxydiphenyl, 4,4'-dichlorodiphenyl sulfone and 4,4'-Bis(4-chloropl-ienyl)sulfonyl-1,1'-biphenyl; after all the monomers are completely dissolved, heating to 100°C and adding alkali metal carbonate salt-forming agent which is 5-10 mol % more than the amount of 4,4'-dihydroxydiphenyl added, and subsequently adding xylene; continuously heating and salt-forming reaction begins in the system, and controlling the temperature at 190∼210°C; then heating to 230∼236°C, and maintaining for 3-4 hours to obtain polymer viscous liquid; and refining the polymer viscous liquid to obtain a terpolymer containing different structural units in the molecular chain, wherein the Tg or the terpolymer can be regulated by changing the ratio of the two dichloro-containing monomers.

    摘要翻译: 一种聚(二苯醚砜)和聚(二苯醚二苯砜)三元共聚物的制备方法,包括:加入高温有机溶剂,搅拌加热; 依次加入4,4'-二羟基联苯,4,4'-二氯二苯基砜和4,4'-双(4-氯苯基)磺酰基-1,1'-联苯; 待所有单体完全溶解后,加热至100℃,加入比加入4,4'-二羟基联苯量多5-10mol%的碱金属碳酸盐成盐剂,随后加入二甲苯; 系统开始连续加热和成盐反应,控制温度在190〜210℃; 然后加热至230〜236℃,保持3-4小时,得到聚合物粘稠液体; 并精制聚合物粘稠液体以获得分子链中含有不同结构单元的三元共聚物,其中可通过改变两种含二氯单体的比例来调节Tg或三元共聚物。