公开(公告)号：EP2804692B1

公开(公告)日：2016-01-13

申请号：EP13747536.4

申请日：2013-01-17

申请人： Intramicron, Inc.

发明人： YANG, Hongyun ,  DIMICK, Paul, S.

IPC分类号： B01D53/86 ,  B01J27/053 ,  B01J27/08 ,  C01B17/04

CPC分类号： B01J27/125 ,  B01D53/8612 ,  B01D2251/102 ,  B01D2251/104 ,  B01D2251/106 ,  B01D2251/11 ,  B01D2251/508 ,  B01D2253/1124 ,  B01D2255/908 ,  B01D2256/24 ,  B01D2258/05 ,  B01J27/053 ,  B01J27/10 ,  B01J27/128 ,  B01J27/138 ,  C01B17/0465 ,  C10G25/00 ,  C10G27/04 ,  C10G27/08 ,  C10G27/12 ,  C10G27/14 ,  C10K1/004 ,  C10K1/32 ,  C10K1/34

公开(公告)号：EP2652089A2

公开(公告)日：2013-10-23

申请号：EP11848506.9

申请日：2011-12-13

申请人： Saudi Arabian Oil Company

发明人： KOSEOGLU, Omer, Refa ,  BOURANE, Abdennour ,  AL-SHAHRANI, Farhan M. ,  AL-SHAFI, Emad

IPC分类号： C10G45/04

CPC分类号： C10G45/22 ,  B01J19/006 ,  B01J19/18 ,  B01J2219/00768 ,  B01J2219/00777 ,  C10G21/00 ,  C10G21/16 ,  C10G21/20 ,  C10G21/27 ,  C10G27/04 ,  C10G27/12 ,  C10G27/14 ,  C10G45/02 ,  C10G53/04 ,  C10G53/14 ,  C10G67/04 ,  C10G67/0418 ,  C10G67/12 ,  C10G67/14 ,  C10G2300/1096 ,  C10G2300/202 ,  C10G2300/44

摘要： Reduction of sulfur-containing and nitrogen-containing compounds from hydrocarbon feeds is achieved by first contacting the entire feed with a hydrotreating catalyst in a hydrotreating reaction zone operating under mild conditions to convert the labile organosulfur and organonitrogen compounds. An extraction zone downstream of the hydrotreating reaction zone separates an aromatic-rich fraction that contains a substantial amount of the remaining refractory organosulfur and organonitrogen compounds. The aromatic-lean fraction is substantially free of organosulfur and organonitrogen compounds, since the non-aromatic organosulfur and organonitrogen compounds were the labile organosulfur and organonitrogen compounds which were initially removed by mild hydrotreating. The aromatic-rich fraction is oxidized to convert the refractory organosulfur and organonitrogen compounds to oxidized sulfur-containing and nitrogen-containing hydrocarbon compounds. These oxidized organosulfur and organonitrogen compounds are subsequently removed.

公开(公告)号：EP2478075A2

公开(公告)日：2012-07-25

申请号：EP10816773.5

申请日：2010-09-10

申请人： Cetamax Ventures Ltd.

发明人： KIN, Meng Chan ,  KAMALUL, Arifin Yusof ,  SHAHRUL, Niza Bin Abdul Rahim ,  MD ASRAFF, Bin Abdul Karim ,  ROGER, Kai Lott

IPC分类号： C10L1/08 ,  B01J10/00 ,  B01J23/74 ,  B01J23/64

CPC分类号： C10G3/00 ,  C10G27/02 ,  C10G27/12 ,  C10G27/14 ,  C10G31/06 ,  C10G2300/1007 ,  C10G2300/1014 ,  C10G2300/1018 ,  C10G2300/1059 ,  C10G2300/301 ,  C10G2300/307 ,  C10G2300/4081 ,  C10L1/1805 ,  C10L10/12 ,  C10L2290/34 ,  C10L2290/544 ,  Y02E50/13 ,  Y02P30/20

摘要： High energy (e.g., ultrasonic) mixing of a liquid hydrocarbon feedstock and reactants comprised of an oxidation source, catalyst and acid yields a diesel fuel product or additive having substantially increased cetane number. Ultrasonic mixing creates cavitation, which involves the formation and violent collapse of micron-sized bubbles, which greatly increases the reactivity of the reactants. This, in turn, substantially increases the cetane number compared to reactions carried out using conventional mixing processes, such as simple mechanical stirring. Alternatively, an aqueous mixture comprising water and acid can be pretreated with an oxidation source such as ozone and subjected to ultrasonic cavitation prior to reacting the pretreated mixture with a liquid hydrocarbon feedstock.

摘要翻译： 液体烃原料和由氧化源，催化剂和酸组成的反应物的高能量（例如超声波）混合产生柴油燃料产物或具有大大增加的十六烷值的添加剂。 超声混合产生气蚀，其涉及微米级气泡的形成和剧烈的崩溃，这大大增加了反应物的反应性。 与使用常规混合过程如简单机械搅拌进行的反应相比，这反过来显着增加了十六烷值。 或者，包含水和酸的含水混合物可以用诸如臭氧的氧化源预处理，并在将预处理的混合物与液体烃原料反应之前进行超声空化。

公开(公告)号：EP2410038A3

公开(公告)日：2012-05-23

申请号：EP11161598.5

申请日：2011-04-08

申请人： Tung, Lin Hsin ,  Wei, Wan Meng ,  Chun, Lu Ming

发明人： Tung, Lin Hsin ,  Wei, Wan Meng ,  Chun, Lu Ming

IPC分类号： C10G27/04 ,  C10G27/12 ,  C10G27/14

CPC分类号： C10G27/04 ,  C10G21/00 ,  C10G21/28 ,  C10G27/12 ,  C10G27/14 ,  C10G2300/1055 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2300/44

摘要： Mixing-assisted oxidative desulfurization method of diesel fuel and the continuous desulfurization device thereof is disclosed herein. Because of the dangers of sulfur content in gasoline and other petroleum products, many governments have required the sulfur content of these petroleum products to be reduced so as to safeguard public safety and health. Desulfurization of fossil fuels is provided by the combination of fossil fuels with an aqueous mixture of ozone or hydrogen peroxide and a Tetraoctylphosphonium salt phase transfer catalyst, and the mixture is then reactive mixed to form oxidize sulfur compounds in the fuel. The polar oxidized sulfones species are removed via another mixing step. The desulfurization device (10) can be in the form of a portable device which provides for continuous mixing-assisted desulfurization for the selective removal of sulfur containing compounds from fossil fuels such as diesel fuel or other hydrocarbons.

公开(公告)号：EP1751259A2

公开(公告)日：2007-02-14

申请号：EP05742095.2

申请日：2005-04-26

申请人： M-I L.L.C.

发明人： BROWNE, Neale ,  IVAN, Catalin

IPC分类号： C10G27/14

CPC分类号： C10G27/04 ,  C10G27/14 ,  C10G31/06 ,  C10G32/02 ,  E21B21/066

摘要： A method of treating a hydrocarbon fluid (100) that includes contacting the hydrocarbon fluid with an effective amount of ozone. A method for separating contaminants from a contaminated material (100) includes supplying the contaminated material to a processing chamber (103), moving the contaminated material through the processing chamber, heating the contaminated material by externally heating the processing chamber (112) so as to volatilize the contaminants in the contaminated material, removing vapor resulting from the heating, wherein the vapor comprises the volatilized contaminants, collecting, condensing, and recovering the volatilized contaminants, and contacting the volatilized contaminants with an effective amount of ozone.

公开(公告)号：EP1342773A3

公开(公告)日：2003-11-19

申请号：EP03076459.1

申请日：1999-10-07

申请人： Carbon Resources Limited

发明人： Jorgensen, Pierre

IPC分类号： C10G27/14 ,  C10G9/36

CPC分类号： C10G21/02 ,  B01J4/001 ,  B01J2219/00006 ,  C10G1/02 ,  C10G9/00 ,  C10G9/36 ,  C10G27/14 ,  C10G33/06 ,  C10G55/04 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/201 ,  C10G2300/205 ,  C10G2300/807 ,  Y10S585/922 ,  Y10S585/923

摘要： A process for the conversion of hydrocarbons that are solid or have a high boiling temperature and may be laden with metals, sulfur or sediments, into liquids (gasolines, gas oil, fuels) with the help of a jet of gas properly superheated between 600 and 800°C. The process comprises preheating a feed (5) in a heater (8) to a temperature below the selected temperature of a reactor (10). This feed is injected by injectors (4) into the empty reactor (10) (i.e., without catalyst.) The feed is treated with a jet of gas or superheated steam from superheater (2) to activate the feed. The activated products in the feed are allowed to stabilize at the selected temperature and at a selected pressure in the reactor and are then run through a series of extractors (13) to separate heavy and light hydrocarbons and to demetallize the feed. Useful products appearing in the form of water/hydrocarbon emulsions are generally demulsified in emulsion breaker (16) to form water laden with different impurities. The light phase containing the final hydrocarbons is heated in heater (98) and is separated into cuts of conventional products, according to the demand for refining by an extractor (18) similar to (13).

公开(公告)号：EP1348013A1

公开(公告)日：2003-10-01

申请号：EP01925943.1

申请日：2001-04-26

申请人： Murakami, Seishiro ,  Fujita, Hideyuki

发明人： Murakami, Seishiro ,  Fujita, Hideyuki

IPC分类号： C10L1/08 ,  C10G27/14 ,  C10G25/00

CPC分类号： C10L1/026 ,  C10G27/04 ,  C10G27/14 ,  C10G33/06 ,  C10G2400/04 ,  Y02E50/13

摘要： A fuel for a diesel engine is produced by using a fish waste oil or a mixture of a vegetable waste oil and the fish waste oil which have conventionally been wasted as a staring material. Fish oil (virgin oil or fish waste oil) or a mixture of the fish oil and vegetable oil (virgin oil or vegetable waste oil) (hereinafter referred to as starting material) is subjected to stirring treatment while introducing ozone, and an oxidation-reduction agent and a polymerization inhibitor are added during the stirring treatment. Moreover, it comprises the respective steps of a first treatment step in which a stirring treatement is carried out while introducing ozone to the above-mentioned starting material, and an oxidation-reduction agent and a polymerization inhibitor are added during the stirring treatement, a second treatment step in which the material obtained in the above-mentioned first step is filtered and a stirring treatment is further carried out while introducing ozone again, and a step of introducing a vegetable additive to the resulting material by the second treatment step.

公开(公告)号：EP1342773A2

公开(公告)日：2003-09-10

申请号：EP03076459.1

申请日：1999-10-07

申请人： Carbon Resources Limited

发明人： Jorgensen, Pierre

IPC分类号： C10G27/14

CPC分类号： C10G21/02 ,  B01J4/001 ,  B01J2219/00006 ,  C10G1/02 ,  C10G9/00 ,  C10G9/36 ,  C10G27/14 ,  C10G33/06 ,  C10G55/04 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/201 ,  C10G2300/205 ,  C10G2300/807 ,  Y10S585/922 ,  Y10S585/923

摘要： A process for the conversion of hydrocarbons that are solid or have a high boiling temperature and may be laden with metals, sulfur or sediments, into liquids (gasolines, gas oil, fuels) with the help of a jet of gas properly superheated between 600 and 800°C. The process comprises preheating a feed (5) in a heater (8) to a temperature below the selected temperature of a reactor (10). This feed is injected by injectors (4) into the empty reactor (10) (i.e., without catalyst.) The feed is treated with a jet of gas or superheated steam from superheater (2) to activate the feed. The activated products in the feed are allowed to stabilize at the selected temperature and at a selected pressure in the reactor and are then run through a series of extractors (13) to separate heavy and light hydrocarbons and to demetallize the feed. Useful products appearing in the form of water/hydrocarbon emulsions are generally demulsified in emulsion breaker (16) to form water laden with different impurities. The light phase containing the final hydrocarbons is heated in heater (98) and is separated into cuts of conventional products, according to the demand for refining by an extractor (18) similar to (13).

摘要翻译： 一种用于烃类转化过程中确实是固体或具有高沸点温度，并且可以是负载金属，硫或沉积物，成液体（汽油，瓦斯油，燃料）与气体射流的帮助600之间适当的过热和 800℃，该方法包括在预热的加热器（8）的进料（5）到反应器（10）的选定的温度以下的温度。 该进料通过喷射器（4）到空反应器（10）注射（即，无催化剂）将进料气体的射流或从过热器过热蒸汽（2）以激活料治疗。 被激活的产品在饲料中被允许在选定的温度和在反应器中所选择的压力稳定，并且然后通过一系列提取的（13）以分离的重和轻的烃，并demetallize进料运行。 有用的产品在水/烃乳液的形式亮相的是破乳在破乳剂（16）的负载具有不同的杂质，以形成水基因集会。 轻相含有最终的烃是在加热器（98）加热，并被分离成类似于（13）常规产品，gemäß的削减通过在提取器（18），用于精炼的需求。 一种烃类转化过程中确实是固体或具有高沸点温度，并且可以是负载金属，硫或沉积物，成液体（汽油，瓦斯油，燃料）与气体射流的帮助下适当地过热 600和800℃之间，该方法包括在预热的进料（5）一个加热器（8）的反应器（10）的选定的温度以下的温度。 该进料通过喷射器（4）到空反应器（10）注射（即，无催化剂）将进料气体的射流或从过热器过热蒸汽（2）以激活料治疗。 被激活的产品在饲料中被允许在选定的温度和在反应器中所选择的压力稳定，并且然后通过一系列提取的（13）以分离的重和轻的烃，并demetallize进料运行。 有用的产品在水/烃乳液的形式亮相的是破乳在破乳剂（16）的负载具有不同的杂质，以形成水基因集会。 轻相含有最终的烃是在加热器（98）加热，并被分离成类似于（13）常规产品，gemäß的削减通过在提取器（18），用于精炼的需求。

公开(公告)号：EP1241243A1

公开(公告)日：2002-09-18

申请号：EP00964818.9

申请日：2000-09-25

申请人： Gandelman, Leonid Yakovlevich

发明人： GANDELMAN, Leonid Yakovlevich ,  LYAPIN, Andrei Grigorievich

IPC分类号： C10G27/14 ,  C10G32/02 ,  F02M25/10 ,  F02M27/04

CPC分类号： C10G27/14

摘要： The invention relates to chemistry and in particular to technology for processing hydrocarbon fuel, including engine fuel. The invention makes it possible to obtain a fuel with high cetane and octane numbers by means of the following: the initial fuel supply occurs simultaneously with ejection; an ozone containing gas is fed into the ejection area; turbulent flows are created by displacement of such a mixture; the transformed mixture is directed into a volume with a stable pressure level; and thermodynamic equalization of the mixture parameters is achieved. During thermodynamic equalization, sprayed water is injected into said mixture.

摘要翻译： 本发明涉及化学，特别涉及用于处理包括发动机燃料在内的烃类燃料的技术。 本发明可以通过以下方式获得具有高十六烷值和辛烷值的燃料：初始燃料供应与喷射同时发生; 将含臭氧气体送入喷射区域; 通过这种混合物的置换产生湍流; 将转化的混合物引入具有稳定压力水平的体积中; 并实现混合参数的热力学均衡。 在热力学均衡期间，将喷射水注入所述混合物中。

公开(公告)号：EP0029472A1

公开(公告)日：1981-06-03

申请号：EP79302615.4

申请日：1979-11-16

申请人： BIOLEX CORPORATION

发明人： Bouk, Ray S.

IPC分类号： C10G27/00 ,  C10G53/14

CPC分类号： C10G27/00 ,  C10G27/04 ,  C10G27/12 ,  C10G27/14 ,  C10G53/14

摘要： A process for eliminating and removing impurities including sulfur compounds and microorganisms as well as preventing further microbial contamination is accomplished by treating petroleum products or other hydrocarbon fluids with an aqueous solution of an oxidizing agent such as hydrogen peroxide or ozone together with a metallic ion catalyst, such as a mixture of ferric chloride and cupric chloride, where the metal ion is capable of forming activated oxygen complexes in the presence of such oxidizing agent, or by treatment with an aqueous solution of metallic ion catalyst and activated oxygen complexes formed from permanganate, peroxyborate or chromate ions. The products produced by such process are substantially free of viable forms of microbial contamination.

摘要翻译： 一种用于消除和除去杂质，包括硫化合物和微生物以及防止进一步的微生物污染是通过在氧化剂的wässrige溶液处理石油产品或其它烃流体与实现过程：例如过氧化氢或臭氧与金属离子催化剂一起 ：如氯化铁和氯化铜的混合物，其中所述金属离子是能够形成在搜索的存在下活化氧络合物氧化剂，或通过用金属离子催化剂的wässrige固溶处理，并从高锰酸盐FORMED活化氧配合物，过硼酸 或铬酸盐离子。 由这种方法生产的产品基本上没有微生物污染的可行形式。