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公开(公告)号：EP1324824A1
公开(公告)日：2003-07-09
申请号：EP01972074.7
申请日：2001-09-20
IPC分类号： B01J23/887 , B01J37/00 , B01J35/00 , C07C51/25 , C07C57/04
CPC分类号： B01J37/00 , B01J23/002 , B01J23/887 , B01J35/0006 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69
摘要： The invention relates to a method for producing a multiple-phase multi-metal oxide material that contains Mo, V, Cu and, optionally, other elements. According to the invention, at least one phase is separately pre-formed and is dispersed in a plastically deformable precursor material of another phase. The mixture is then dried and calcined. The multi-metal oxide material is suited for use as an active material of catalysts for catalytically oxidizing organic compounds in the gas phase, in particular, for oxidizing acrolein into acrylic acid.
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公开(公告)号：EP1105365B1
公开(公告)日：2002-06-19
申请号：EP99940184.7
申请日：1999-08-10
发明人： MACHHAMMER, Otto , TENTEN, Andreas , JACHOW, Harald , HAUPT, Susanne , ARNOLD, Heiko , UNVERRICHT, Signe
CPC分类号： C07C51/215 , C07C45/33 , C07C45/35 , C07C51/252 , C07C47/22 , C07C57/04
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33.发明公开VERFAHREN DER KATALYTISCHEN GASPHASENOXIDATION VON PROPEN ZU ACRYLSÄURE 有权VERFAHREN DER KATALYTISCHEN GASPHASENOXIDATION VON PROPEN ZUACRYLSÄURE
公开(公告)号：EP1159248A1
公开(公告)日：2001-12-05
申请号：EP00918748.5
申请日：2000-02-28
发明人： UNVERRICHT, Signe , ARNOLD, Heiko , TENTEN, Andreas , HAMMON, Ulrich , NEUMANN, Hans-Peter , HARTH, Klaus
CPC分类号： C07C45/35 , B01J23/002 , B01J23/31 , B01J23/8872 , B01J23/8876 , B01J23/8885 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C51/252 , C07C47/22 , C07C57/04 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/842 , B01J2523/845
摘要： The invention relates to a method for the catalytic gas phase oxidation of propene into acrylic acid in which the initial mixture of reaction gas, with an increased propene charge, is oxidized on a first fixed-bed catalyst during a first reaction step, said fixed-bed catalyst being accommodated in two reaction zones A, B arranged in a spatially successive manner, whereby the temperature of reaction zone B is kept at a higher temperature than that of reaction zone A. In addition, the mixture of product gas which contains acrolein and which is of the first reaction step is, under an increase acrolein charge, subsequently oxidized on a second fixed-bed catalyst during a second reaction step. Said second fixed-bed catalyst is accommodated in two successively arranged reaction zones C, D, whereby the temperature of reaction zone D is kept at a higher temperature than that of reaction zone C.
摘要翻译： 本发明涉及一种将丙烯催化气相氧化成丙烯酸的方法，其中在第一反应步骤中在第一固定床催化剂上氧化具有增加的丙烯进料的反应气体的初始混合物， 床催化剂容纳在以空间连续方式布置的两个反应区A，B中，由此反应区B的温度保持在比反应区A的温度更高的温度。另外，含有丙烯醛的产物气体与 在第二反应步骤期间，在第一反应步骤中，随着丙烯醛进料量的增加，随后在第二固定床催化剂上被氧化。 所述第二固定床催化剂容纳在两个连续布置的反应区C，D中，由此反应区D的温度保持在比反应区C更高的温度。
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公开(公告)号：EP1159247A1
公开(公告)日：2001-12-05
申请号：EP00912516.2
申请日：2000-02-28
发明人： UNVERRICHT, Signe , ARNOLD, Heiko , TENTEN, Andreas , HAMMON, Ulrich , NEUMANN, Hans-Peter , HARTH, Klaus
CPC分类号： C07C51/252 , B01J23/002 , B01J23/31 , B01J23/8872 , B01J23/8876 , B01J23/8885 , B01J35/0006 , B01J37/0221 , B01J2523/00 , C07C45/35 , C07C47/22 , C07C57/04 , B01J2523/13 , B01J2523/17 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/845 , B01J2523/55
摘要： The invention relates to a method for the catalytic gas phase oxidation of propene into acrylic acid in which the initial mixture of reaction gas, with an increased propene charge, is oxidized on a first fixed-bed catalyst during a first reaction step, and the mixture of product gas which contains acrolein and which is of the first reaction step is, under an increased acrolein charge, subsequently oxidized on a second fixed-bed catalyst during a second reaction step, whereby the catalyst shaped bodies comprise an annular geometry in both reaction steps.
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