摘要:
The invention relates to a luminescent material, particularly for use in security documents, comprised of a host lattice made of rare-earth oxysulfide, which is doped with at least two types of ions. The luminescent material exhibits anti-Stokes luminescence according to Stokes' law when it is irradiated with an excitation radiation. According to the invention, the luminescent material contains two luminescent material constituents, which are co-doped with ytterbium/holmium on the one hand and with ytterbium/erbium on the other. The luminescent material can preferably be used for forming security features.
摘要:
This invention is related to efficient inorganic borophosphate phosphors which can applied in various technical applications such as fluorescent lamps, colored light or white light emitting diodes, and other devices where phosphors are used to convert especially near UV radiation into the visible light. Further, this invention is related to light sources comprising the efficient borophosphate phosphor. The inventive phosphor absorbs radiation in a first wavelength range of the electromagnetic spectrum and emits radiation in a second wavelength range of the electromagnetic spectrum. This phosphor is a borophosphate activated with divalent rare earth metal ions and is represented by the general formula: AM 1-x RE x BP 2 O 8 . Symbol A stand for at least one univalent alkaline metal ion. Symbol M represents at least one divalent metal ion. Symbol RE stands for at least one divalent ion selected from the group comprising rare earth metals as well as Pb, Sn, Cu, and Mn, wherein RE contains at least one divalent rare earth metal ion that is acting as an activator, preferably Eu. Variable x is limited by 0
摘要翻译:本发明涉及可用于诸如荧光灯,彩色光或白色发光二极管等各种技术应用的有效的无机磷光体磷光体,以及使用荧光体将UV辐射特别接近可见光的其它装置。 此外,本发明涉及包含有效硼磷酸盐荧光体的光源。 本发明的荧光体吸收电磁光谱的第一波长范围内的辐射并且在电磁光谱的第二波长范围内发射辐射。 该磷光体是用二价稀土金属离子活化的硼磷酸盐,由通式AM 1-x RE x BP 2 O 8表示。 符号A代表至少一种一价碱金属离子。 符号M表示至少一种二价金属离子。 符号RE表示选自稀土金属以及Pb,Sn,Cu和Mn中的至少一种二价离子,其中RE含有至少一种作为活化剂的二价稀土金属离子,优选为Eu。 变量x受限于0
摘要:
This invention is related to ABOS:M-based phosphors, e.g. phosphors that are based on modified CaZnOS. Furthermore, this invention is related to the use of these phosphors for converting radiation. This invention is also related to light sources that contain the inventive phosphor. An inventive phosphor shows the general formula ABOS:M, where A is at least one element selected from the group consisting of Ca, Mg, Sr, and Ba; B is at least one element selected from the group consisting of Zn and Mg; and M is at least one element selected from the group consisting of Mn 2+ , Cu 2+ , and Eu 2+ . Optionally, M can additionally contain one ore more elements selected from the group consisting of Mn 2+ , Cu 2+ , Cu + , Ag + , Pb 2+ , Sb 3+ , Sn 2+ , Bi 3- , Eu 2+ , Ce 3+ , Tb 3+ , and Pr 3+ as well as Li + , Na + , K + , and Rb + .
摘要:
The invention relates to a method of manufacturing a rare-earth doped alkaline-earth silicon nitride phosphor of a stoichiometric composition. Said method comprising the step of selecting one or more compounds each comprising at least one element of the group comprising the rare-earth elements (RE), the alkaline-earth elements (AE), silicon (Si) and nitrogen (N) and together comprising the necessary elements to form the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). The method further comprises the step of bringing the compounds at an elevated temperature in reaction for forming the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). In such a method normally a small amount of oxygen, whether intentionally or not-intentionally added, will be incorporated in the rare-earth doped alkaline-earth silicon nitride phosphor (AE2Si5N8:RE). According to the invention the creation of defects by formation of a non-stoichiometric oxygen containing phosphor is at least partly prevented by partly substituting for the ions (AE, Si, N) of the alkaline-earth silicon nitride phosphor (AE2Si5N8:RE) suitable further elements of the periodic system by which vacancies are created, filled or annihilated resulting in the formation of a modified alkaline-earth silicon nitride phosphor (AE2Si5N8:RE) having a stoichiometric composition. In this way a modified phosphor is obtained having excellent and stable optical properties. The invention further relates to a modified phosphor obtainable by the above-mentioned method and a radiation converting device comprising such a phosphor.
摘要:
The invention relates to a method of manufacturing a rare-earth (RE) doped alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 ) of a stoichiometric composition, said method comprising the step of selecting one or more compounds each comprising at least one element of the group comprising the rare-earth elements (RE), the alkaline-earth elements (AE), silicon (Si) and nitrogen (N) and together comprising the necessary elements to form the rare-earth doped alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 :IRE) bringing the compounds at an elevated temperature in reaction for forming the rare-earth doped alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 :RE), a small amount of oxygen, whether intentionally or not-intentionally added, being incorporated in the rare-earth doped alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 :RE) thus formed. According to the invention the creation of defects by formation of a non stoichiometric oxygen containing phosphor is at least partly prevented by partly substituting for the ions (AE, Si, N) of the alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 ) suitable further elements of the periodic system by which vacancies are created, filled or annihilated resulting in the formation of a modified alkaline-earth silicon nitride phosphor (AE 2 Si 5 N 8 ) having a stoichiometric composition. In this way a modified phosphor is obtained having excellent and stable optical properties. The invention further comprises a modified phosphor obtainable by a method according to the invention and a radiation-emitting device comprising such a phosphor.
摘要翻译:本发明涉及制造稀土类的方法(RE)掺杂的碱土硅氮化物荧光体的化学计量组合物的(AE 2的Si 5 N 8),所述方法包括:选择至少各自包含一种或多种化合物的步骤 包括以下的组的稀土类元素(RE),碱土元素(AE),硅(Si)和氮(N)和一起包括必要的元素,以形成掺杂稀土的碱土硅的一种元素 氮化物荧光体(AE 2的Si 5 N 8:IRE)使所述化合物在高温下在反应用于形成掺杂稀土的碱土硅氮化物磷光体(AE 2的Si 5 N 8:RE),氧的少量 ,无论故意或不有意加入,在掺杂稀土的碱土硅氮化物荧光体被结合(AE 2的Si 5 N 8:RE)由此形成。 通过形成非化学计量的氧的含磷的。根据本发明的缺陷创建是至少部分地由部分地代入碱土硅氮化物荧光体的离子(AE,硅,N)(AE 2的Si 5 N 8防治 ),通过该空位被创建,填充或消灭在形成的改性的碱土硅氮化物荧光体的具有化学计量组成(AE 2的Si 5 N 8)产生的周期性的系统的其它合适的元件。 以这种方式修饰的磷可获得具有优异的和稳定的光学特性。 本发明通过一种方法雅丁本发明的和发射辐射的装置,包括寻求磷还包括经修饰的磷可获得的。