Separation of 3,5-dichlorocumene from a mixture of 3,5-dichlorocumene and 2,4-dichlorocumene
    31.
    发明公开
    Separation of 3,5-dichlorocumene from a mixture of 3,5-dichlorocumene and 2,4-dichlorocumene 失效
    从3,5-二氯异丙基苯和2,4-二氯异丙基苯的混合物中分离3,5-二氯异丙苯

    公开(公告)号:EP0090875A1

    公开(公告)日:1983-10-12

    申请号:EP82103036.8

    申请日:1982-04-07

    IPC分类号: C07C25/02 C07C17/00

    CPC分类号: C07C17/395 C07C25/02

    摘要: 3,5-Dichlorocumene is separated from a mixture comprising 3,5-dichlorocumene and 2,4-dichlorocumene by a process comprising contacting the mixture with an isopropyl group acceptor, in the presence of a catalyst comprising:

    (1) at least one Lewis acid compound, and
    (2) a proton source whereby the isopropyl group of 2.4-dichlorocumene is transferred, to the acceptor forming a reaction product comprising the acceptor bearing the isopropyl group, 3,5-dichlorocumene and m-dichlorobenzene. 3,5-Dichlorocumene is readily separated from this reaction product by any conventional technique, typically distillation.

    摘要翻译: 通过包括使所述混合物与异丙基受体在包含以下物质的催化剂存在下接触的方法从含有3,5-二氯异丙基苯和2,4-二氯异丙基苯的混合物中分离3,5-二氯异丙苯:(1)至少一种路易斯 (2)将2.4-二氯异丙基的异丙基转移到质子源,形成包含带有异丙基的受体,3,5-二氯异丙基苯和间二氯苯的反应产物的受体。 通过任何常规技术,通常是蒸馏,3,5-二氯醌容易地从该反应产物中分离出来。