摘要:
3,5-Dichlorocumene is separated from a mixture comprising 3,5-dichlorocumene and 2,4-dichlorocumene by a process comprising contacting the mixture with an isopropyl group acceptor, in the presence of a catalyst comprising:
(1) at least one Lewis acid compound, and (2) a proton source whereby the isopropyl group of 2.4-dichlorocumene is transferred, to the acceptor forming a reaction product comprising the acceptor bearing the isopropyl group, 3,5-dichlorocumene and m-dichlorobenzene. 3,5-Dichlorocumene is readily separated from this reaction product by any conventional technique, typically distillation.
摘要:
To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition containing HFO-1234yf and R40. A method for separating HFO-1234yf containing substantially no R40, which comprises bringing an azeotropic composition or azeotrope-like composition of HFO-1234yf and R40 into contact with a specific extraction solvent.
摘要:
The present invention is the process comprising forming a stable mixture comprising I(CF2)nI, wherein n is at least 3 and at least one of I(CF2)nI, wherein n is 1 or 2, as a contaminant in said mixture and heating said mixture to a temperature of at least 220° C. to reduce the amount of said contaminant to be no greater than 1% when said contaminant is ICF2I (n=1) and no greater than 0.1% when said contaminant is ICF2CF2I (n=2).
摘要:
A method is described for producing vinyl chloride by thermally cracking 1,2-dichloroethane in a vinyl chloride structure, wherein a 1,2-dichloroethane pyrolysis unit is provided, wherein feed 1,2-dichloroethane is thermally cracked, the cracked gas produced therein is cooled in a downstream quench column, and the chlorohydrocarbon contained in the cracked gas is separated off in a downstream HCl column, wherein a 1,2-dichloroethane structure is connected upstream of the vinyl chloride structure, said 1,2-dichloroethane structure having a distillative purification of 1,2-dichloroethane structure, wherein at least one high-boiling column is provided for separating off the substances boiling higher than 1,2-dichloroethane, and wherein the high-boiling column is operated under excess pressure. The method is characterised in that at least one part of the vapours from the quench column is used for obtaining thermal energy which is used for heating the HCl column.
摘要:
To provide a method for efficiently separating 2,3,3,3-tetrafluoropropene (HFO-1234yf) and chloromethane (R40) from a composition containing HFO-1234yf and R40. A method for separating HFO-1234yf containing substantially no R40, which comprises bringing an azeotropic composition or azeotrope-like composition of HFO-1234yf and R40 into contact with a specific extraction solvent.
摘要:
The invention concerns a process for purifying α,ω-diiodoρerfluorinatcd compounds of formula 1-(CF2CF2Y)m-I comprising contacting an impure α,ω-diiodopcrfluorinated compound with a suitable sequestering agent, with formation of a reversible adduct and separating the α,ω- diiodoperfluorinated compound from the adduct itself. Diammonium dihalogenids of the general formula [R1,2,3N-(CH2)n-NR4,5,6]2*2X (R1-6=alkyl C1-C6n=8-26, X=I,Br, Cl) also called 'methonium compounds' are the preferred sequestering agents.
摘要:
2,3-dichlorobutadiene-1,3 of high purity is produced from 1,2,3,4-tetrachlorobutane by a process comprising the steps of dehydrochlorination, chlorination of the reaction product obtained in the dehydrochlorination step and subsequent separation of a 2,3-dichlorobutadiene-1,3 composition from the reaction product of the chlorination step.