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公开(公告)号：EP0595381B1
公开(公告)日：1996-12-04
申请号：EP93202710.5
申请日：1993-09-18
申请人： ENICHEM S.p.A.
IPC分类号： C08F18/24
CPC分类号： C08F18/24
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32.发明授权
公开(公告)号：EP0614469B1
公开(公告)日：1996-02-28
申请号：EP92923091.0
申请日：1992-10-28
申请人： PPG INDUSTRIES, INC.
IPC分类号： C08F18/24 , C08F20/26 , C08F26/02 , C08F283/02 , C08F220/36 , C08F218/00
CPC分类号： C08F218/00 , G02B1/041 , C08L31/00
摘要： Organic resin compositions of from about 30 to 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), and from about 10 to 70, e.g., 10 to 30, weight percent of a mixture of aliphatic urethanes, the terminal portions of which contain allyl or acrylyl functional groups. Polymerizable compositions prepared from such compositions produce castings which have low yellowness (b*) values and which do not pre-release from the molds in which they are formed. Polymerizates prepared from such compositions may be used to prepare photochromic articles, e.g., lenses, by incorporating a photochromic substance, e.g., by thermal transfer, into the polymerizate.
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33.发明授权Liquid composition which can polymerize into almost colourless and easily dyeable organic glass 失效液体组合物，其能够聚合的几乎无色的和易染色有机玻璃。
公开(公告)号：EP0473163B1
公开(公告)日：1995-11-02
申请号：EP91114564.7
申请日：1991-08-29
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34.发明公开Procédé et dispositif pour l'obtention d'un polymère à gradient d'indice 失效Verfahren und Vorrichtung zur Herstellung eines Brechungsindexgradienten-Polymers。
公开(公告)号：EP0407294A1
公开(公告)日：1991-01-09
申请号：EP90401922.1
申请日：1990-07-03
IPC分类号： C08F263/00 , C08F18/24 , G02C7/04 , B29D11/00
CPC分类号： C08F2/00 , C08F263/00 , C08F218/00
摘要： Le procédé suivant l'invention est du genre suivant lequel on fait diffuser, de manière contrôlée, au sein d'une matière de base (10), qui, formée d'au moins un monomère partiellement polymérisé et susceptible de conduire à un homopolymère d'indice de réfraction N1, se présente à l'état de gel, une matière d'addition (11), qui est elle-même formée d'au moins un monomère susceptible de conduire à un homopolymère d'indice de réfraction N2 différent de N1.
Suivant l'invention, on choisit pour matière d'addition (11) un mélange d'au moins deux monomères (A, B), et on fait varier dans le temps la composition de ce mélange.
Application à l'obtention d'éléments en matière synthétique de qualité optique convenant notamment à la réalisation de lentilles ophtalmiques.摘要翻译： 根据本发明的方法是根据该方法，添加剂物质（11）以受控的方式扩散到基质（10）内，所述基础物质（10）由至少一种部分聚合的单体组成，所述部分聚合的单体能够得到 折射率N1处于凝胶状态，添加剂本身由能够产生与N1不同的折射率N2的均聚物的至少一种单体构成。 根据本发明，所选择的添加剂物质（11）是至少两种单体（A，B）的混合物，并且该混合物的组成随时间而变化。 ... 应用于生产由特别适用于眼科镜片生产的光学质量的合成物质制成的部件。
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公开(公告)号：EP0346996A2
公开(公告)日：1989-12-20
申请号：EP89201532.2
申请日：1989-06-14
IPC分类号： C08F18/24 , G02B1/04 , C09D131/00
CPC分类号： C08F290/061 , C08F18/24 , G02B1/04 , C08L31/00
摘要： Organic glasses and surface coatings are prepared, with short hardening cycles, by submitting to the action of U.V. light a liquid polymerizable composition containing at least one di-(allyl carbonate) or poly-(allyl carbonate) of a diol or polyol, a photoinitiator and a vinyl ester monomer and/or an organic peroxide.
The composition can additionally contain small amounts of an organic compound selected from among those compounds which are used in the art in order to stabilize the organic polymers to the degrading action of U.V. light.
The composition is preferably heated before being treated with U.V. iight.摘要翻译： 制备有机玻璃和表面涂层，具有短的硬化周期，通过提交紫外线的作用。 点燃含有二醇或多元醇的至少一种碳酸二（碳酸烯丙酯）或聚（碳酸烯丙酯），光引发剂和乙烯基酯单体和/或有机过氧化物的液体可聚合组合物。 该组合物可另外含有少量选自本领域中使用的那些化合物中的有机化合物，以将有机聚合物稳定至紫外线的降解作用。 光。 组合物优选在用紫外线处理之前加热。 光。
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36.发明公开Compositions for producing polymers of high refractive index and low yellowness 失效组合物用于具有高折射率和低变黄聚合物的制备。
公开(公告)号：EP0224123A2
公开(公告)日：1987-06-03
申请号：EP86115687.5
申请日：1986-11-12
申请人： PPG INDUSTRIES, INC.
摘要： The yellowness of polymerizates formed from polymerizable compositions containing bisphenol bis(allylic carbonate)-functional material is reduced by inclusion of one or more cyclohexenic compounds in the polymerizable compositions.
摘要翻译： 从含有双酚双聚合组合物形成聚合产物的黄度（烯丙基碳酸酯官能材料是通过包含在cyclohexenic聚合组合物的一种或多种化合物的减少。
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37.发明公开Method of reduction of discoloration of aromatic peroxide initiated polyol (allyl carbonate) polymers and polymers produced thereby 失效一种用于减少过氧化物的变色与芳族引发的多元醇（烯丙基碳酸酯）聚合物等制成的聚合物的方法。
公开(公告)号：EP0081984A1
公开(公告)日：1983-06-22
申请号：EP82306591.7
申请日：1982-12-10
申请人： PPG INDUSTRIES, INC.
IPC分类号： C08F18/24
CPC分类号： C08F18/24
摘要： A solid polymeric composition comprising a polymerizate of a polyol (allyl carbonate), fragments of aromatic peroxide initiator, and an effective amount of a 2-hydroxy-4-alkoxy benzophenone.
A method of polymerizing a polyol (allyl carbonate) monomer comprising:
a) forming a composition comprising polyol (allyl carbonate) monomer and aromatic peroxide initiator; and
b) initiating polymerization; characterized in that the composition initially contains up to 0.01 mole of original aromatic peroxide initiator per equivalent of polyol (allyl carbonate) monomer and an effective amount of a 2-hydroxy-4-alkoxy benzophenone.
A method of reducing ultraviolet induced yellowing of aromatic peroxide initiated poly [polyol (allyl carbonate)] comprising:
a) maintaining the level of original aromatic peroxide initiator up to about 0.01 mole per equivalent of polyol (allyl carbonate) monomer; and
b) providing an effective amount of a 2-hydroxy-4-alkoxy benzophenone in the polyol (allyl carbonate) monomer.
A method of reducing yellowing of aromatic peroxide initiated poly [polyol (allyl carbonate) comprising:
a) maintaining the level of original aromatic peroxide initiator up to 0.01 mole per equivalent of polyol (allyl carbonate) monomer and providing an effective amount of a 2-hydroxy-4-alkoxy benzophenone;
b) polymerizing the polyol (allyl carbonate) to form a solid polymerizate; and
c) continuing the polymerization above 100 degrees Centigrade and low enough to avoid thermal degradation induced yellowness.摘要翻译： 的固体聚合物组合物含有多元醇（烯丙基碳酸酯）的聚合产物，芳族过氧化物引发剂的片段，以及在有效量的2-羟基-4-烷氧基二苯甲酮。 聚合的多元醇（烯丙基碳酸酯）单体的方法，包括：a）形成组合物，包含多元醇（烯丙基碳酸酯）单体和芳族过氧化物引发剂; 和b）引发聚合; 在组合物中的二苯甲酮表征确实最初包含高达12点01每摩尔多元醇（烯丙基碳酸酯）单体的等效原始芳族过氧化物引发剂，并在有效量的2-羟基-4-烷氧基。 减少的芳族过氧化物的紫外线引起的变黄的方法引发的聚[多元醇（烯丙基碳酸酯）]，包括：a）维持原芳族过氧化物引发剂的高达每多元醇（烯丙基碳酸酯）单体的当量大约12时01摩尔的水平; 和b）有效量的多元醇（烯丙基碳酸酯）单体2-羟基-4-烷氧基二苯甲酮的提供。 减少的芳族过氧化物的变黄的方法引发的聚[多元醇（烯丙基碳酸酯），其包括：a）维持原芳族过氧化物引发剂的水平提高到每个多元醇（烯丙基碳酸酯的当量）单体00:01摩尔和2-的有效量的提供 羟基-4-烷氧基二苯甲酮; b）该多元醇的聚合（烯丙基碳酸酯），以形成固体聚合产物; 和c）继续高于100摄氏度和足够低的聚合以避免热降解引起的泛黄。
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公开(公告)号：EP1276780B1
公开(公告)日：2006-11-02
申请号：EP01926472.0
申请日：2001-03-29
IPC分类号： C08F18/24 , C08F218/18 , C08F290/06 , G02B1/04
CPC分类号： C08F18/24 , C08F2218/245
摘要： Describes a polymerizable composition of (a) a first allyl functional monomer, which is selected such that a substantially completely cured polymerizate of the first allyl functional monomer has a 15 second Barcol 934 hardness of at least 40, and (b) a second allyl functional monomer selected from polyether diol bis(allyl carbonate), polylactone diol bis(allyl carbonate) and mixtures thereof. The second allyl functional monomer is present in the composition in an amount to provide a substantially completely cured polymerizate having: (i) improved organic photochromic substance incorporation relative to a substantially completely cured polymerizate of the composition free of monomer (b); and (ii) heat distortion temperature of at least 40 DEG C.
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公开(公告)号：EP0787749B1
公开(公告)日：2003-04-02
申请号：EP96927885.2
申请日：1996-08-23
发明人： YOKOYAMA, Keiichi Mitsui Petrochemical Industries , SASANO, Takako Mitsui Petrochemical Industries, , HIWARA, Akio Mitsui Petrochemical Industries, , TORIIDA, Masahiro Mitsui Petrochemical Industries , MITA, Satoko Mitsui Petrochemical Industries,
IPC分类号： C08F16/26 , C08F18/24 , C08F20/28 , C08F299/00 , C08G65/32 , C07C69/96 , H01B1/12 , H01M10/40
CPC分类号： H01M10/052 , C07C69/54 , C07C69/96 , C08F16/26 , C08F18/24 , C08F20/28 , C08F22/105 , C08F290/062 , C08G65/332 , H01B1/122 , H01M10/0565 , H01M2300/0085
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公开(公告)号：EP1276780A2
公开(公告)日：2003-01-22
申请号：EP01926472.0
申请日：2001-03-29
IPC分类号： C08F18/24 , C08F218/18 , C08F290/06 , G02B1/04
CPC分类号： C08F18/24 , C08F2218/245
摘要： Describes a polymerizable composition of (a) a first allyl functional monomer, which is selected such that a substantially completely cured polymerizate of the first allyl functional monomer has a 15 second Barcol 934 hardness of at least 40, and (b) a second allyl functional monomer selected from polyether diol bis(allyl carbonate), polylactone diol bis(allyl carbonate) and mixtures thereof. The second allyl functional monomer is present in the composition in an amount to provide a substantially completely cured polymerizate having: (i) improved organic photochromic substance incorporation relative to a substantially completely cured polymerizate of the composition free of monomer (b); and (ii) heat distortion temperature of at least 40 °C.
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