摘要:
The present invention relates to a graft polymer PG including a polymer backbone P and at least one side graft G linked to the polymer backbone, the graft G having the general formula (1): in which R 1 and R 2 represent, separately from one another, straight or branched, unsaturated or saturated hydrocarbon groups, such that the total number of carbon atoms in groups R 1 and R 2 is between 2 and 110; X represents an amide, amino-acid, urea or urethane function, said graft G being linked to said polymer backbone P via the sulphur atom. The graft polymer PG is a polymer that allows thermoreversible cross-linking. The graft polymer PG can be used in many fields such as coatings, paints, thermoplastics, adhesives, lubricants, fuels, inks, cements, construction materials, rubbers and bitumens. The graft polymer PG can be used in particular for thermoreversibly cross-linking bitumen/polymer compositions and thus for reducing coating, spreading and/or compaction temperatures during the production of bituminous coated materials.
摘要:
The present invention relates to a method for preparing grafted polymers from a polymer made of conjugated diene units and a graft which is a thiol derivative. The method is characterised by the lack of a solvent and of a radical initiator. The grafted polymer can be used advantageously as an additive for a bitumen/polymer composition and enables, in particular, thermoreversible cross-linking.
摘要:
The invention relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The invention also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The invention further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
摘要:
The invention relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The invention also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The invention further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
摘要:
Polymer network composition comprising a semi-crystalline covalently crosslinked polymer network including exchangeable covalent bonds and crosslinking bonds and at least an exchange reaction catalyst, wherein the number of crosslinking bonds is sufficient for the polymer network to be beyond the gel point and the number of exchangeable bonds is sufficient for the network to relax stresses and/or flow when conditioned at an appropriate temperature. Such compositions are characterized by the fact that the network is able to reorganize by exchange reactions that allow it to relax stresses and/or flow while maintaining network connectivity.
摘要:
The invention relates to a thermoreversibly cross-linked graft polymer, to the method for preparing same, and to the use of such a graft polymer in preparing a thermoreversibly cross-linked bitumen/polymer composition. The present invention also relates to a thermoreversibly cross-linked bitumen/polymer composition comprising such a graft polymer, to the method for preparing same, and to bituminous asphalt including such a composition. The polymer comprises: a main polymer chain P consisting of conjugated diene units; at least one side graft G having the following general formula (1): R-(OCH 2 CH 2 ) m -S---, where R is a straight or branched saturated hydrocarbon chain having at least 18 carbon atoms, and m is an integer varying from 0 to 20, said graft G being connected to the main polymer chain P via the sulfur atom of formula (1); and at least one graft G' having the following general formula (4): ---S-R'-S---, where R' is a straight or branched, saturated or unsaturated hydrocarbon grouping having 2 to 40 carbon atoms, optionally including one or more heteroatoms, said graft G' being connected to the main polymer chain P via each sulfur atom of formula (4).
摘要:
The invention relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The invention also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The invention further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.