摘要:
A reduced methyl bromide process for making tetrabromobisphenol-A in methanol, including: dissolving bisphenol-A in a methanol solvent to form a bisphenol-A methanol solution, adding bromide to the bisphenol-A methanol solution to brominate bisphenol-A and form tetrabromobisphenol-A and hydrogen bromide, exposing the bisphenol-A methanol solution to an amount of a hydrogen peroxide agent to reduce the amount of methyl bromide co-product resulting from the bromination of bisphenol-A in methanol by reducing the amount of hydrogen bromide co-product available to react with the methanol, and collecting the resulting tetrabromobisphenol-A product thus formed after the bromination is substantially complete.
摘要:
Flame retardant latex coatings are disclosed which include natural or synthetic latex grafted with ring-halogenated, ethylenically unsaturated aromatic monomers. The grafted latex is used alone or in combination with non-grafted natural or synthetic latex. The coatings are useful for a wide variety of applications, including fabric backcoatings, carpetings, paints, adhesives, sealants, caulks, non-woven binders and so on.
摘要:
A method for providing aqueous solutions of HOBr or HOCl which includes adding bleach (NaOCl) to a solution of HBr or HCl until an identified absorbance or color change in the resulting solution is detected. Dialkylhydantoins are optionally added to the resulting solution to suppress the formation of halate ions. The method provides a simple and reliable method for producing accurately defined solutions of hypohalous acids, which are useful in a variety of ways, including for disinfecting, cleaning, and odor control purposes.
摘要:
Disclosed are high-solids processes for producing N,N'-bis(tetrabromophthalimide) and/or N,N'-alkylene-bis(tetrabromophthalimide) products useful as flame retardants. The processes are performed in high-mass transfer reactors similar to apparatuses conventionally used as mixers/dryers for particulate solid materials.
摘要:
A process for leaching platinum and palladium wherein an aqueous leaching solution containing bromine and bromide ion contacts a precious metal source to produce an aqueous leachate. A precursor composition for producing an aqueous leaching solution for leaching platinum and palladium. A process for electrogenerating bromine and a process for leaching platinum and palladium wherein bromine is electrogenerated and contacts a precious metal source to produce an aqueous leachate. A process for leaching gold, silver, platinum and palladium wherein bromine is electrogenerated from a solution containing chloride ions and bromide ions.
摘要:
A method of completely decomposing gasesous halocarbons at temperatures of between about 500 C and about 700 C, preferably about 600 C. The gaseous halocarbons may initially pass through a vaporizer tube (14), before entering the reaction tube (13). The reaction and vaporizer tubes are heated by ceramic fiber heaters (15 and 16). Temperatures were monitored and controlled by a thermocouple inserted into the heaters. Gas flows are monitored with two flowmeters. This sytem for decomposing gaseous halocarbons has the advantage of mixing the halocarbon gas with oxygen and maintaining the temperature at 600 C for a length of time sufficient to eliminate all halocarbons from the gas.
摘要:
A flame retarding additive composition, useful in thermoplastic polyolefins, is disclosed comprising a mixture of a halogenated bisphenol derivative and the copolymer of a halogenated vinyl aromatic grafted onto polyolefin. The preferred bisphenol derivative is tetrabromobisphenol A bis(dibromopropyl ether), and the preferred graft copolymer comprises bromostyrene grafted onto isotactic or syndiotactic polypropylene. Also disclosed are the flame retarded, thermoplastic polyolefins prepared using the foregoing additive compositions.
摘要:
Product stream processing methods, systems, and mixtures are provided. A reaction product stream can have a first amount of a halogen exchange by product and an azeotropic composition of a halogen exchange reaction product and a halogen donating reactant. A majority of the halogen exchange by-product from the reaction product stream can be removed to produce a mixture. The mixture can include the halogen exchange reaction product, the halogen donating reactant, and a second amount of the halogen exchange by-product that is less than the first amount of the halogen donating reactant. A majority of the halogen exchange reaction product containing less than the azeotropic amount of the halogen donating reactant can be removed from the mixture. Exemplary halogen exchange reaction product, halogen donating reactant and halogen exchange by-product are CH2F2, HF, and HCI respectively.
摘要:
This invention provides a stabilized alkyl bromide based solvent system that is useful for cleaning and degreasing a wide variety of metal objects. The solvent is stabilized with a stabilizer system that includes a dialkyl carbonate such as dimethyl carbonate and optionally other stabilizers and/or acid scavengers to inhibit the metal induced decomposition of the alkyl bromide based solvent. The stabilized solvent is applied to metal articles by any known or conventional means to solvate and entrain greases, oils and other undesirable matter from the article's surface.
摘要:
A method of inhibiting the autooxidation of fatty acids in a paper product made from pulp fiber is accomplished by adding to the pulp fiber between about 2 moles/metric ton and about 10 moles/metric ton of an oxidizing halogen.