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    Polymerization catalyst and process
    44.
    发明公开
    Polymerization catalyst and process 失效
    聚合物和Verfahren。

    公开(公告)号：EP0501672A1

    公开(公告)日：1992-09-02

    申请号：EP92301382.5

    申请日：1992-02-19

    申请人： BP Chemicals Limited

    发明人： Dawkins, Gordon Michael

    IPC分类号： C08F4/78 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/78

    摘要： Olefin polymerization catalysts capable of polymerizing olefins such as ethylene to polyolefins with broad molecular weight distributions are made by depositing on an oxide suport (or especially phosphate derivative thereof) (i) a chromium complex of formula RCr-L, where R is optionally substituted pentadienyl or cyclopentadienyl and L is a reactive ligand, or a bis arene chromium and (ii) a metal complex of formula MR³ R⁴ R⁵ R⁶ wherein M is Ti, Zr or Hf, and R³-R⁶ can be allyl (when M is Zr or Hf) or of 4-20 carbons of formula (a) CH₂ X (R⁷ R⁸ R⁹) where X = C, Si or Ge and R⁷-R⁹ are hydrocarbyl, or (b) CH₂ Ar where Ar is optionally substituted aromatic, or said metal complex is of formula Ti R¹¹ R¹², where R¹¹ and R¹² are acyclic dienyl.

    摘要翻译： 能够将烯烃如乙烯聚合成具有宽分子量分布的聚烯烃的烯烃聚合催化剂通过在氧化物（或其特别是磷酸酯衍生物）上沉积（i）式RCr-L的铬络合物来制备，其中R是任选取代的戊二烯基 或环戊二烯基，L为反应性配体或双芳烃铬，和（ii）式为MR 3 R 4 R 5 R 6的金属络合物，其中M为Ti，Zr或Hf，R为 R 3可以是烯丙基（当M是Zr或Hf时）或4-20个碳原子的式（a）CH 2 X（R 7 R 8 R 9），其中X = C ，Si或Ge和R 7 -R 9是烃基，或（b）CH 2 Ar，其中Ar是任选取代的芳族，或所述金属络合物具有式Ti R 1 R 1， 2>，其中R 1和R 2均为非环状二烯基。

    Chromium-containing complex polymerisation catalyst
    45.
    发明公开
    Chromium-containing complex polymerisation catalyst 失效
    含铬复合聚合催化剂

    公开(公告)号：EP0416784A3

    公开(公告)日：1991-10-02

    申请号：EP90309280.7

    申请日：1990-08-23

    申请人： BP Chemicals Limited

    发明人： Dawkins, Gordon Michael

    IPC分类号： C08F10/00 ,  C08F4/78

    CPC分类号： C08F10/00 ,  C08F4/78

    摘要： The present invention relates to an olefin polymerization catalyst obtainable by depositing on a dry inorganic oxide support a monocuclear chromium complex to produce a catalyst precursor and thereafter by thermally activating the said catalyst precursor. The catalyst is characterised in that the mononuclear chromium complex is representable by the general formula:
    wherein:
    - the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbon groups containing 1 to 3 carbon atoms,
    - x is an integer from 1 to 4, and
    - L is either a four-or five-substituted cyclopentadienyl ligand, or (CO)₃R in which R is H, methyl or ethyl. The catalyst is used for polymerizing olefins, particularly ethylene optionally with C₃-C₈ alpha-olefins. It produces polyolefins having a relatively high molecular weight and a broad molecular weight distribution.

    摘要翻译： 烯烃聚合催化剂本发明涉及通过在干燥的无机氧化物载体上沉积单环铬配合物以制备催化剂前体并随后通过热活化所述催化剂前体而获得的烯烃聚合催化剂。 该催化剂的特征在于，单核铬配合物可用下列通式表示：其中： - 环戊二烯基配体被4或5个含1至3个碳原子的烃基取代， - x为1至4的整数， L是四取代或五取代的环戊二烯基配位体，或（R）H，甲基或乙基的（CO）3 R。 该催化剂用于聚合烯烃，特别是乙烯任选与C 3 -C 8α-烯烃聚合。 它生产具有较高分子量和宽分子量分布的聚烯烃。

    Chronium-containing complex polymerisation catalyst
    46.
    发明公开
    Chronium-containing complex polymerisation catalyst 失效
    含氯化氢复合聚合催化剂

    公开(公告)号：EP0416785A3

    公开(公告)日：1991-09-25

    申请号：EP90309281.5

    申请日：1990-08-23

    申请人： BP Chemicals Limited

    发明人： Dawkins, Gordon Michael

    IPC分类号： C08F4/78 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F4/78

    摘要： The present invention relates to an olefin polymerization obtainable by depositing on a dry inorganic oxide support at least one mononuclear chromium complex, which is representable by the general formula:
    wherein
    - the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbyl groups (R1-R5) containing 1 to 3 carbon atoms, and
    - L is one or more hydrocarbyl ligands which are sufficiently reactive to enable the complex to react with the inorganic oxide without thermal activation. The catalyst can be used without thermal activation for polymerizing olefins, particularly ethylene optionally with C₃₋₈ alpha-olefins. It produces polyolefins having broad molecular weight distribution.

    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME
    49.
    发明授权
    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME 有权
    过渡金属/羰基配合物及其生产方法

    公开(公告)号：EP3023430B1

    公开(公告)日：2018-01-31

    申请号：EP14827072.1

    申请日：2014-07-17

    申请人： Zeon Corporation

    发明人： HAYANO, Shigetaka

    IPC分类号： C07F11/00 ,  C07F19/00 ,  C08F4/78

    CPC分类号： C07F11/00 ,  C08F4/78

    摘要： Provided are a transition metal carbene complex represented by the following general formula (1) and a method of producing the same. (In general formula (1), M represents for example a molybdenum atom, R 1 represents for example a C 1 -C 20 alkyl group optionally having a substituent, L to L 3 each represent a ligand selected for example from a halogen group, R 2 and R 3 each represent for example a hydrogen atom or a C 1 -C 20 alkyl group optionally having a substituent, A represents for example a nitrogen atom, and R 4 to R 7 each represent for example a C 1 -C 20 alkyl group optionally having a substituent.)

    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME
    50.
    发明公开
    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME 有权
    过渡金属/碳烯和方法及其制造

    公开(公告)号：EP3023430A4

    公开(公告)日：2017-02-15

    申请号：EP14827072

    申请日：2014-07-17

    申请人： ZEON CORP

    发明人： HAYANO SHIGETAKA

    IPC分类号： C07F11/00 ,  C07F19/00 ,  C08F4/78

    CPC分类号： C07F11/00 ,  C08F4/78

    摘要： Provided are a transition metal carbene complex represented by the following general formula (1) and a method of producing the same. (In general formula (1), M represents for example a molybdenum atom, R 1 represents for example a C 1 -C 20 alkyl group optionally having a substituent, L to L 3 each represent a ligand selected for example from a halogen group, R 2 and R 3 each represent for example a hydrogen atom or a C 1 -C 20 alkyl group optionally having a substituent, A represents for example a nitrogen atom, and R 4 to R 7 each represent for example a C 1 -C 20 alkyl group optionally having a substituent.)