SUBSTITUTED TERRYLENE AND QUATERRYLENE DERIVATIVES AND THE USE AS SEMICONDUCTORS THEREOF
    58.
    发明公开
    SUBSTITUTED TERRYLENE AND QUATERRYLENE DERIVATIVES AND THE USE AS SEMICONDUCTORS THEREOF 审中-公开
    取代terrylene-和quaterrylene及其用途随着半导体

    公开(公告)号:EP2867234A2

    公开(公告)日:2015-05-06

    申请号:EP13810563.0

    申请日:2013-06-28

    IPC分类号: C07D471/06 C09B5/62 H01L51/50

    摘要: The present invention relates to terrylene and quaterrylene derivates of the general formula I (formula I) (I) wherein n is 0 or 1, R
    a and R
    b are independently of one another selected from hydrogen and in each case unsubstituted or substituted alkyl, alkenyl, alkadienyl, alkynyl, cycloalkyl, bicyclo- alkyl, cycloalkenyl, heterocycloalkyl, aryl or heteroaryl, X
    1 , X
    2 , X
    3 and X
    4 are independently of one another selected from F, CI, Br, I, CN and B(OR
    c )
    2 , wherein R
    c is selected from in each case unsubstituted or substituted alkyl, cycloalkyl or aryl, or wherein two radicals R
    c may together form a divalent bridging group selected from in each case unsubstituted or substituted C
    2 - C
    10 -alkylene, C
    3 -C
    6 -cycloalkylene and C
    6 -C
    14 -arylene, wherein C
    2 -C
    10 - alkylene, C
    3 -C
    6 -cycloalkylene and C
    6 -C
    14 -arylene may carry one or more identical or different C
    2 -C
    12 -alkyl radicals, R
    1 , R
    2 , R
    3 , R
    4 , R
    5 , R
    6 , R
    11 and R
    12 and, if present, R
    7 , R
    8 , R
    9 and R
    10 are independently of one another selected from hydrogen, F, CI, Br, I, CN, hydroxy, mercapto, nitro, cyanato, thiocyanato, formyl, acyl, carboxy, carboxylate, alkylcarbonyloxy, car¬ bamoyl, alkylaminocarbonyl, dialkylaminocarbonyl, sulfo, sulfonate, sulfoamino, sulfamoyl, alkylsulfonyl, arylsulfonyl, amidino, NE
    1 E
    2 , where E
    1 and E
    2 are each independently selected from hydrogen, alkyl, cycloalkyi, heterocycloalkyl, aryl or hetaryl, in each case unsubstituted or substituted alkyl, alkoxy, alkylthio, (monoal- kyl)amino, (dialkyl)amino, cycloalkyi, cycloalkoxy, cycloalkylthio, (monocycloal- kyl)amino, (dicycloalkyl)amino, heterocycloalkyi, heterocycloalkoxy, heterocyclo- alkylthio, (monoheterocycloalkyl)amino, (diheterocycloalkyl)amino, aryl, aryloxy, arylthio, (monoaryl)amino, (diaryl)amino, hetaryl, hetaryloxy, hetarylthio, (mono- hetaryl)amino, (dihetaryl)amino, and the use thereof as organic semiconductor materials.