摘要:
Provided is a active material for positive electrode for an alkaline secondary cell, which advantageously exhibits improved overdischarge characteristics, improved utilization of the active material and an improved effect of suppressing the rise in cell internal pressure, a method for producing the same, and an alkaline secondary cell using the above active material for positive electrode, especially a nickel-hydrogen secondary cell. The above active material comprises nickel hydroxide particles each having a surface to which a cobalt oxide sticks, wherein the cobalt oxide contains 20 to 40 % by mole of cobalt (II) oxide, wherein the nickel hydroxide particles form an eutectic together with Co and Zn or/and Y, and the Co content of the eutectic is 2 % by mass or less, and the nickel hydroxide particles have a value of a half width of the peak ascribed to the (101) crystal face diffraction of 0.8°/2θ(Cu-K α ) or more as measured by powder X-ray diffractometry.
摘要:
In a flat non-aqueous electrolyte secondary cell comprising an electricity-generating element including at least a cathode, a separator and an anode and a non-aqueous electrolyte in the inside of a cathode case, a plurality of electrode units each consisting of the cathode and the anode opposite to each another via the separator are laminated to form an electrode group, or an electrode unit in a sheet form consisting of the cathode and the anode opposite to each another via the separator is wound to form an electrode group, or a sheet-shape cathode is wrapped with the separator except for a part contacting at inner face of cathode case and a sheet-shaped anode is set on the sheet-shaped cathode in a right angled position each other and then these cathode and anode are bent alternately to form an electrode group, and the total sum of the areas of the opposing cathode and anode in this electrode group is larger than the area of the opening of an insulating gasket in a sealed portion in the cathode case or than the area of an opening in a sealed plate in a sealed portion in the cathode case, whereby the discharge capacity upon heavy-loading discharge is significantly increased as compared with the conventional cells. Accordingly, while the size of the cell is small, the discharge capacity is increased as described above, and thus it is possible to provide a highly utilizable flat non-aqueous electrolyte secondary cell. Further, in said flat non-aqueous electrolyte secondary cell, problems which may be caused by the increased discharge capacity in the cell can be solved by improving the solvent and supporting electrolyte for the electrolyte or by various improvements in the cathode and anode cases.
摘要:
Provided is a hydrogen absorbing alloy superior to the MmNi 5 system hydrogen absorbing alloy and the TiFe system hydrogen absorbing alloy that are widely put to practical use in both the capacity density per unit volume and the capacity density per unit weight. The hydrogen absorbing alloy of the present invention is also superior to the conventional TiMn 2 system hydrogen absorbing alloy in the initial activation. The hydrogen absorbing alloy of the present invention is represented by a general formula AM x , where A is at least one element selected from IA group, IIA group, IIIB group, and IVB group of the periodic table, and M is at least one element selected from VB group, VIB group, VIIB group, VIIIB group, IB group, IIB group, IIIA group, IVA group and VA group of the periodic table, x meets the relationship of 2.7
摘要:
An alkaline secondary battery which is characterized in that it comprises, a positive electrode (2) containing nickel hydroxide having a value of 0.8° or more in the half-width of a peak in the (101) plane thereof as measured by X-ray powder diffraction (2θ) using Cu-Kα ray, and 4.0 to 15% by weight of at least one material selected from the group consisting of zinc and zinc compounds, and an alkali electrolyte, the ratio of which to theoretical capacity of the positive electrode being 0.7 to 2.0 cm 3 /Ah, the weight of the at least one material being one calculated as zinc element and based on the weight of the nickel hydroxide. The positive electrode may also comprise an alkali metal compound selected from the group of cesium, rubidium and potassium compounds.
摘要:
A nickel-metal hydride secondary cell comprising an enclosure (4), a non-sinter type nickel positive electrode (1) accommodated in the enclosure (4) and formed of a conductive core and a layer formed on the core and made mainly of a binding medium, nickel hydroxide powder, and cobalt monoxide powder, a hydrogen absorbing alloy negative electrode (2) accommodated in the enclosure (4) and formed of a punched metal and a layer formed on the punched metal by applying a paste thereto, the punched metal having a plurality of apertures having a diameter of 1 to 5 mm at an aperture rate of 45 to 70% and having a thickness equal to 10 to 35% of the overall thickness of the negative electrode, and the paste made of 100 parts by weight of hydrogen absorbing alloy powder, 0.005 to 1 part by weight of polyacrylate, 0.01 to 1 part by weight of carboxymethylcellulose 0.5 to 7 parts by weight of fluororesin, and 0.1 to 4 parts by weight of conductive material powder a separator (3) made of synthetic resin unwoven fabric and located between the positive and negative electrodes(1, 2), and an alkali electrolyte contained in the enclosure (4).
摘要:
Disclosed is a thin type electronic instrument having a structure comprising a circuit base plate for mounting an integrated circuit chip thereon and a power source battery for supplying power to the circuit base plate sandwiched between a pair of synthetic resin sheets opposed to each other, with the pair of synthetic resin sheets being plastered at the peripheral portions thereof, characterized in that a substrate made of a metal is interposed between the pair of synthetic resin sheets. The thin type electronic instrument of the present invention is improved in mechanical durability against mechanical shock such as warping or torsion by a stress during carrying or usage, whereby erroneous actuation or breaking can be inhibited.
摘要:
Disclosed is a thin type electronic instrument having a structure comprising a circuit base plate for mounting an integrated circuit chip thereon and a power source battery for supplying power to the circuit base plate sandwiched between a pair of synthetic resin sheets opposed to each other, with the pair of synthetic resin sheets being plastered at the peripheral portions thereof, characterized in that a substrate made of a metal is interposed between the pair of synthetic resin sheets. The thin type electronic instrument of the present invention is improved in mechanical durability against mechanical shock such as warping or torsion by a stress during carrying or usage, whereby erroneous actuation or breaking can be inhibited.
摘要:
A liquid action substance battery having its external terminal welded after assembling the battery in which safety of the battery is enhanced by protecting an explosion-proof valve against being torn apart in the subsequent welding work of the external terminal even if the position of a negative pole action substance being press-bonded to the inner surface of the battery can is shifted and that substance is extruded to the bottom face of the battery can. The liquid action substance battery employing an alkaline metal such as lithium, sodium or potassium or its alloy as the negative pole action substance, and an oxyhalide such as thionyl chloride, sulfuryl chloride or phosphoryl chloride in a liquid state at normal temperature as the positive pole action substance, and storing and sealig the negative pole action substance and the positive pole action substance in the bottomed battery, wherein a metal plate is welded to the inner surface at the bottom part of the battery can to form a partial space between them so that welding heat is not transmitted directly to the negative pole action substance when the external terminal is welded.
摘要:
This invention presents an anode zinc can for battery with excellent process-ability and corrosion resistance without adding lead to zinc, and a manganese dry battery made by using such a can. Disclosed is a manufacturing method of the proposed can along with technical clues including material composition, optimum hardness, process temperature, and crystal grains with regard to metallographic aspect.