PROCESS FOR CONTROLLING THE POLYMER COMPOSITION OF AN ETHYLENE COPOLYMER OBTAINED BY A CATALYST SYSTEM COMPRISING A TRANSITION METAL CATALYST COMPONENT AND A ZIEGLER CATALYST COMPONENT
    52.
    发明公开
    PROCESS FOR CONTROLLING THE POLYMER COMPOSITION OF AN ETHYLENE COPOLYMER OBTAINED BY A CATALYST SYSTEM COMPRISING A TRANSITION METAL CATALYST COMPONENT AND A ZIEGLER CATALYST COMPONENT 有权
    用于控制乙烯共聚物的聚合物组合由催化剂体系,包含过渡金属催化剂成分和齐格勒催化剂组分获得WILL

    公开(公告)号:EP2794691A1

    公开(公告)日:2014-10-29

    申请号:EP12806022.5

    申请日:2012-12-17

    IPC分类号: C08F210/16

    摘要: A method of controlling the polymer composition of an ethylene copolymer in a process for preparing ethylene copolymers by copolymerizing ethylene and at least one other olefin in the presence of a polymerization catalyst system comprising at least one late transition metal catalyst component (A), at least one Ziegler catalyst component (B), and at least one activating compound (C) by adding an alkyl alkoxy silane or a dialkyi ether for increasing the relative portion of the ethylene copolymer component obtained from polymerization by late transition metal catalyst component (A), or by adding a saturated halogenated hydrocarbon for increasing the relative portion of the ethylene copolymer component obtained from polymerization by Ziegler catalyst component (B), processes for copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system comprising utilizing the controlling method, a method for altering the polymer composition of an ethylene copolymer obtained by copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system and a method for transitioning from one ethylene copolymer grade to another by using the method for altering the polymer composition.

    Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a Ziegler catalyst component
    53.
    发明公开
    Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a Ziegler catalyst component 审中-公开
    一种用于控制乙烯共聚物的聚合物组合物,其完全从催化剂体系,一过渡金属催化剂成分和齐格勒类催化剂成分得到的方法

    公开(公告)号:EP2607391A1

    公开(公告)日:2013-06-26

    申请号:EP11194812.1

    申请日:2011-12-21

    IPC分类号: C08F210/16

    摘要: A method of controlling the polymer composition of an ethylene copolymer in a process for preparing ethylene copolymers by copolymerizing ethylene and at least one other olefin in the presence of a polymerization catalyst system comprising
    - at least one late transition metal catalyst component (A),
    - at least one Ziegler catalyst component (B), and
    - at least one activating compound (C)

    by adding an alkyl alkoxy silane or a dialkyl ether for increasing the relative portion of the ethylene copolymer component obtained from polymerization by late transition metal catalyst component (A), or
    by adding a saturated halogenated hydrocarbon for increasing the relative portion of the ethylene copolymer component obtained from polymerization by Ziegler catalyst component (B),
    processes for copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system comprising utilizing the controlling method, a method for altering the polymer composition of an ethylene copolymer obtained by copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system and a method for transitioning from one ethylene copolymer grade to another by using the method for altering the polymer composition.

    摘要翻译: 至少一个后过渡金属催化剂成分(A), - 控制的乙烯共聚物的聚合物组合物在用于通过在聚合催化剂系统,其包括的存在下共聚合乙烯和至少一种其它烯烃制备乙烯共聚物的方法的方法 - 至少一种齐格勒催化剂组分(B),和 - 至少一个通过向烷基烷氧基硅烷或用于通过后过渡金属催化剂成分增加从聚合得到的乙烯共聚物组分的相对部分的二烷基醚(活化化合物(C) A),或通过添加饱和卤代烃用于增加由齐格勒催化剂组分(B从聚合得到的乙烯共聚物组分的相对部分)处理用于在寻求聚合催化剂系统的存在下共聚合乙烯和至少一种其它烯烃 包括利用该控制方法,用于改变的所述聚合物组合物的方法 乙烯共聚物通过在聚合催化剂搜索体系的存在下和通过使用该方法用于改变聚合物组合物从一个乙烯共聚物级转换到另一种方法共聚合乙烯和至少一种其它烯烃得到。

    Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom
    58.
    发明公开
    Process for the polymerization of olefins; polyethylenes, and films and articles produced therefrom 有权
    一种用于烯烃聚合的过程; 制造的聚乙烯,和膜,和对象,以便

    公开(公告)号:EP2277924A1

    公开(公告)日:2011-01-26

    申请号:EP10010552.7

    申请日:1999-10-14

    IPC分类号: C08F10/00

    摘要: A novel process for the polymerization of olefins is provided. The process involves contacting at least one olefin with a Ziegler-Natta type catalyst in the presence of a specified compound that results in the production of polymeric products having a narrower molecular weight distribution. Also provided is a process for narrowing the molecular weight distribution of a polyolefin comprising contacting an olefin, a Ziegler-Natta catalyst and a compound specified herein. Further provided are novel polyethylenes, and films and articles produced therefrom.

    摘要翻译: 提供了一种用于烯烃聚合的新方法。 该过程涉及在指定的化合物的存在下使至少一种烯烃与齐格勒 - 纳塔型催化剂的确在生产具有窄的分子量分布的聚合物产品的结果。 这样提供了一种用于缩小的聚烯烃包括烯烃的接触的分子量分布的方法,齐格勒 - 纳塔催化剂和在指定的化合物。 进一步提供的是由其产生新颖的聚乙烯和膜和制品。