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公开(公告)号：EP0272017A3
公开(公告)日：1990-07-04
申请号：EP87310590.2
申请日：1987-12-01
IPC分类号： C08F240/00
CPC分类号： C08F240/00 , B05B12/24
摘要： A light color aliphatic hydrocarbon petroleum resin including a piperylene component and a chain transfer agent component useful as a tackifying agent, especially with copolymers. The resin of the invention has a softening point of about 0-40°C, a number average molecular weight of from 100 to about 900, a low Gardner color of about 3 or less, and is formed by the aluminum chloride catalyzed polymerization of a feed stream essentially free of butadiene.
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">52.发明公开Method for producing "poly-N-butene oils" from C4-fraction residues 无效Verfahren zur Herstellung von Poly-N-butylenölaus einer Rest-C4-Fraktion。
公开(公告)号：EP0337737A2
公开(公告)日：1989-10-18
申请号：EP89303576.6
申请日：1989-04-11
申请人： NESTE OY
IPC分类号： C08F240/00
CPC分类号： C08F240/00
摘要： The method consists in the polymerization of olefins with a prevailing content of 1-butene and cis- and trans-2-butenes in the mixture of hydrocarbons known as rafinate II, which is derived from the C₄-fractions after separation of 1,3-butadiene and isobutylene, under initiation with boron trifluoride (BF₃) or alkylaluminium chlorides with the general formulae R₂AlCl and RAlCl₂ (in which each R represents a C₁ to C₆-alkyl group) in the presence of hydrogen chloride (HCl), hydrogen fluoride (HF), or organic compounds with a reactive chlorine or fluorine bonded to a tertiary-, benzyl- or allyl-carbon atom, as coinitiators.
The method according to the solution may be carried out in such a way, that rafinate II derived from the production of methyl tert-butyl ether or from the selective polymerization of isobutylene, in which 1-butene present in a concentration at least 20% is polymerized together with cis- and trans-2-butenes present in a concentration of at least 15%, at a temperature of +100°C to -70°C, to form to oily products with molar mass M n = 300 to 1200. Preferably the mixture derived as rafinate II from the production of methyl tert-butyl ether is first freed of methanol to the content lower than 300p ppm.摘要翻译： 该方法包括在称为rafinate II的烃混合物中以1-丁烯和顺式 - 和反式 - 2-丁烯为主成分的烯烃的聚合反应，其分离出1,3-二丁烯， 丁二烯和异丁烯，在氯化氢（HCl），氟化氢（HF），氟化氢（HF）存在下，用三氟化硼（BF 3）或通式为R 2 AlCl和RACl 2的烷基氯化铝（其中每个R代表C1至C6-烷基） ）或具有与叔 - 苄基 - 或烯丙基 - 碳原子键合的反应性氯或氟的有机化合物作为共引发剂。 根据该溶液的方法可以以这样的方式进行，即从生产甲基叔丁基醚或由异丁烯的选择性聚合衍生的拉夫他II，其中以至少20％浓度存在的1-丁烯为 与-100至-70℃的温度下以至少15％的浓度存在的顺式和反式-2-丁烯一起聚合，以形成摩尔质量Mn = 300至1200的油状产物。优选地， 从生产甲基叔丁基醚得到的rafinate II衍生物的混合物首先从甲醇中除去低于300p ppm的含量。
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公开(公告)号：EP0183448B1
公开(公告)日：1989-04-05
申请号：EP85308323.6
申请日：1985-11-14
IPC分类号： C08F240/00 , C09J3/14
CPC分类号： C08F240/00
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54.发明公开Hydrogenated liquid aliphatic hydrocarbon resins 无效Hydrogeniertes，flüssiges，aliphatisches Kohlenwasserstoffharz。
公开(公告)号：EP0308137A1
公开(公告)日：1989-03-22
申请号：EP88308302.4
申请日：1988-09-08
IPC分类号： C09J147/00 , C08F8/04 , C08F240/00
CPC分类号： C08F8/04 , C08F240/00 , C08L2666/04 , C09J157/02 , Y10S525/94
摘要： A light color hydrogenated aliphatic hydrocarbon petroleum resin including a piperylene component and a chain transfer agent component useful as a tackifying agent, especially with copolymers. The resin of the invention has a softening point of about 0-40°C, a number average molecular weight of from 100 to about 900, a low Gardner color of about 3 or less, and is formed by the aluminum chloride catalyzed polymerization of a feed stream essentially free of butadiene.
摘要翻译： 一种浅色氢化脂族烃石油树脂，其包括可用作增粘剂的戊间二烯成分和链转移剂组分，特别是共聚物。 本发明的树脂的软化点为约0-40℃，数均分子量为100至约900，加纳尔色低约3或更低，并且通过氯化铝催化聚合形成 进料流基本上不含丁二烯。
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公开(公告)号：EP0272017A2
公开(公告)日：1988-06-22
申请号：EP87310590.2
申请日：1987-12-01
IPC分类号： C08F240/00
CPC分类号： C08F240/00 , B05B12/24
摘要： A light color aliphatic hydrocarbon petroleum resin including a piperylene component and a chain transfer agent component useful as a tackifying agent, especially with copolymers. The resin of the invention has a softening point of about 0-40°C, a number average molecular weight of from 100 to about 900, a low Gardner color of about 3 or less, and is formed by the aluminum chloride catalyzed polymerization of a feed stream essentially free of butadiene.
摘要翻译： 一种浅色脂族烃石油树脂，其包括可用作增粘剂的戊间二烯组分和链转移剂组分，特别是共聚物。 本发明的树脂的软化点为约0-40℃，数均分子量为100至约900，加纳尔色低约3或更低，并且通过氯化铝催化聚合形成 进料流基本上不含丁二烯。
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56.发明公开Rubber compounding material and composition 失效MischungsmaterialfürKautschuk und dessen Zusammensetzung。
公开(公告)号：EP0249904A2
公开(公告)日：1987-12-23
申请号：EP87108510.6
申请日：1987-06-12
IPC分类号： C08F240/00 , C08F232/00 , C08L21/00
CPC分类号： C08F240/00 , C08L21/00 , C08L2666/06
摘要： A rubber compounding material incorporating a cyclopentadiene-based pertroleum resin prepared by thermally copolymerizing 100 parts by weight of a cyclopentadiene-based feed or dicyclopentadiene-based feed with about 5 to 100 parts by weight of an α-olefin having from 6 to 16 carbon atoms at a temperature of from about 200 to 300°C for a period of from about 10 minutes to 10 hours in the presence or absence of a solvent.
A rubber composition is also disclosed, composed of this rubber compounding material in combination with a diene-based polymer.
In rubber compositions for tires, the compounding material and rubber composition of the present invention greatly improve resistance to cutting and chipping of the tread.摘要翻译： 通过将100重量份的环戊二烯基进料或二环戊二烯基进料与约5至100重量份的具有6至16个碳原子的α-烯烃热共聚而制备的包含环戊二烯基的石油树脂的橡胶配混材料 在约200至300℃的温度下，在存在或不存在溶剂的情况下约10分钟至10小时。 还公开了一种橡胶组合物，其由与该二烯基聚合物组合的该橡胶配混材料组成。 在用于轮胎的橡胶组合物中，本发明的配混材料和橡胶组合物大大提高了胎面的切割和切屑的抗性。
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57.发明授权Fully saturated petroleum resin and hot melt pressure sensitive adhesive formulations utilizing same as a tackifier 失效完全饱和的石油树脂和热熔胶敏感胶粘剂配方使用同一个作为一个TACKIFIER
公开(公告)号：EP0131460B1
公开(公告)日：1987-09-09
申请号：EP84304661.6
申请日：1984-07-06
IPC分类号： C09J3/14 , C08F240/00 , C08F8/04
CPC分类号： C09J157/02 , C08F240/00 , C08L2666/04 , C09J153/025
摘要： This invention relates to pressure sensitive adhesive formulations which include a saturated midblock thermoplastic elastomer such as a block copolymer of polystyrene and hydrogenated polydiene such as Kraton TM G and a fully saturated tackifying resin derived from petroleum feedstock polymerized in the presence of aluminium chloride and having a Mn ranging from 400 to 800, a softening point of 40 to 70 DEG C and a glass transition temperature less than 45 DEG C whereby the adhesive formulations have a rolling ball tack of less than 10 cm., a 180 DEG peel of from 1 to 4 pounds per inch, a 90 DEG quick stick of from 0.5 to 2.0 pounds per inch and a Polyken probe tack of higher than 400 g/cm with a formulation containing 100 to 180 phr of the saturated tackifying resin.
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58.发明公开Light color, low softening point petroleum hydrocarbon resins and pressure sensitive adhesives containing such resins 失效低软化点和含这些树脂的压敏粘合剂的小有色烃石油树脂。
公开(公告)号：EP0234856A2
公开(公告)日：1987-09-02
申请号：EP87301405.4
申请日：1987-02-18
IPC分类号： C08F240/00 , C09J125/02 , A61L15/16 , A61L15/00
CPC分类号： C08F240/00 , B05B12/24 , C09J7/383
摘要： A light color petroleum hydrocarbon resin including an aromatic hydrocarbon component useful for tackifying block copolymers is described which has a softening point of about 0°C to about 40°C, a number average molecular weight (Mn) of from 350 to 600 and a molecular weight distribution (Mw/ Mn) of from 1:1 to about 2.0. An adhesive comprising a copolymer and such resins.
摘要翻译： 粘合剂compsn。 含20-80重量％的共聚物（I）的％和80-20重量软化点0-40℃温度，锰100-600和Garner的颜色小于的增粘石油烃树脂（II）的％。7 （II）是prepd。 由三氯化铝催化的，其包括5-75重量％8-10Ç乙烯基芳族烃料流（III），10-35％（重量）丙烯浓缩物（IV）和25-70重量％的烃进料的在Friedel Crafts聚合。％4-8C 式RR'C = CHR的单烯烃的链转移剂（V）“各自1-5C烷基和R”“是1-4C-”，R和R，其中“烷基。 县。 （I）是一种苯乙烯 - 丁二烯共聚物和在50-65重量被使用。％（III）是一个混合。 苯乙烯和α-甲基苯乙烯的并且形成（II）的5-35重量％。 （IV）是热浸并形成10-26％; （V）是二聚丙烯前置混合6C单烯烃流。 该compsn。 80-120℃温度的含有至多软化PT的树脂的60重量％。，E.G. 到脂族，脂族/芳族的，萜烯，萜烯/脂肪族，萜烯/芳族或松香酯，其可以是氢化的和至多50％（重量）惰性填料。
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59.发明公开
公开(公告)号：EP0134592A3
公开(公告)日：1986-08-20
申请号：EP84200620
申请日：1984-05-02
IPC分类号： C08F240/00 , C08F12/00 , C08F06/00
CPC分类号： C08F240/00 , C08F12/00
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公开(公告)号：EP0183448A2
公开(公告)日：1986-06-04
申请号：EP85308323.6
申请日：1985-11-14
IPC分类号： C08F240/00 , C09J3/14
CPC分类号： C08F240/00
摘要： Petroleum Resins particularly effective for use as tackifiers for hot melt adhesives and in tackifiers for solvent-based pressure sensitive adhesives are prepared by a process
Wherein (1) a C 8 - and/or C 9 aromatic unsaturated hydrocarbon-containing feed (optionally containing up to 18 wt.% or C 4 or C 5 unsaturated aliphatic hydrocarbons( is first polymerised completely and thereafter a C s -aliphatic unsaturated hydrocarbon-containing feed is added, polymerisation continued and the reactor effluent stripped to obtain the resin. The order of polymerisation may be reversed.
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