摘要:
Provided is a method for producing an α-olefin polymer, comprising the step of polymerizing one or more kinds of α-olefins each having 3 to 30 carbon atoms with a polymerization catalyst obtained by using: (A) a metallocene compound; (B) an ionic compound capable of reacting with the metallocene compound to transform the compound into a cation; (C) an organometallic compound; and (D) one or more kinds of compounds selected from the group consisting of (d-1) an alcohol, (d-2) a phenol, and (d-3) an ether compound, the catalyst having a ratio between the component (A) and the component (D) of from 10:1 to 1:100 in terms of a molar ratio, and having a ratio of the component (D) to the component (C) of less than 1 in terms of a molar ratio.
摘要:
Provided is a method for producing a hydrogenated unsaturated polyhydroxyhydrocarbon polymer capable of suppressing side reactions such as a hydrogenolysis reaction of a terminal hydroxyl group and achieving a high hydrogenation rate in a short reaction time. A hydrogenated unsaturated polyhydroxyhydrocarbon polymer is obtained by a method including: hydrogenating an unsaturated polyhydroxyhydrocarbon polymer under the presence of a hydrogenation catalyst and a reaction solvent in the following two stages (I) and (II): (I) carrying out a hydrogenation reaction in a temperature range of 80°C to 130°C until a hydrogenation rate of at least 30 mol% is achieved; and then (II) carrying out a hydrogenation reaction at a temperature higher than 130°C until a hydrogenation rate of at least 98 mol% is achieved.
摘要:
In accordance with the present disclosure there is provided a process for preparing a hydrogenated olefin polymer by hydrogenation of a polyoctene; said polyoctene being prepared by reacting a C8-olefm feed comprising an isomeric mixture of an alpha-olefin and a non-alpha olefin monomer in a controlled manner with the help of an ionic catalyst, while controlling at least one condition of the reaction selected from the group of condition consisting of exotherm, contact time of the olefin feed with ionic catalyst and molar ratio of the ionic catalyst to the olefin feed within predetermined ranges to obtain an oligomerized mixture comprising at least one polyoctene and unreacted ionic catalyst.
摘要:
An object of the present invention is to provide a thermoplastic resin having excellent heat resistance, excellent thermal stability, low water absorption properties, excellent surface hardness, and excellent mechanical strength. The present invention is a thermoplastic resin comprising a constituent unit (a) that is derived from a (meth)acrylate monomer and represented by the formula (1); a constituent unit (b) that is derived from a vinyl monomer and represented by the following formula (2); and a constituent unit (c) that is derived from a vinyl monomer and represented by the following formula (3), and the weight percentage of the constituent unit (a), based on the total weight of the all constituent units, is 60 to 85% by weight, the weight percentage of the constituent unit (b), based on the total weight of the all constituent units, is 5 to 30% by weight, and the weight percentage of the constituent unit (c), based on the total weight of the all constituent units, is 5 to 15% by weight.
摘要:
A method for hydrogenating a polymer containing vinyl aromatic block and the hydrogenated polymer are provided. The method includes providing a polymer having at least one vinyl aromatic block; and hydrogenating the polymer in presence of a heterogeneous catalyst on a support, wherein the heterogeneous catalyst consists essentially of Ru, Zn and B, or Ru, Zn and P.