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公开(公告)号：EP2821423B1
公开(公告)日：2016-07-20
申请号：EP13797500.9
申请日：2013-05-23
CPC分类号： C08G18/4277 , C08G2/10 , C08G18/10 , C08G18/3206 , C08G18/4275 , C08G18/664 , C08G18/69 , C08G18/694 , C08G18/7621
摘要： A polybutadiene having a hydroxyl group at a terminal end thereof is reacted with a lactone compound such as an µ-caprolactone to obtain a polymer polyol represented by formula (I): HO-X 1 -Y-X 2 -OH (wherein X 1 and X 2 each independently represents a polyester component and Y represents a polybutadiene component), the polymer polyol is reacted with an unsymmetric diisocyanate to obtain a urethane prepolymer, and then the urethane prepolymer is reacted with a chain extender to obtain a polyurethane.
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公开(公告)号：EP3061781B1
公开(公告)日：2020-03-18
申请号：EP14856067.5
申请日：2014-10-21
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3.发明授权METHOD FOR PRODUCING A HYDROGENATED UNSATURATED POLYHYDROXYHYDROCARBON POLYMER 有权用于生产不饱和羟基烃类型的氢化聚合物
公开(公告)号：EP2944656B1
公开(公告)日：2017-05-31
申请号：EP13871157.7
申请日：2013-12-25
IPC分类号： C08C19/02 , C08F36/04 , C08F136/06
CPC分类号： C08F136/06 , C08C19/02 , C08F8/04 , C08F36/04
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4.发明公开
公开(公告)号：EP2944656A1
公开(公告)日：2015-11-18
申请号：EP13871157.7
申请日：2013-12-25
CPC分类号： C08F136/06 , C08C19/02 , C08F8/04 , C08F36/04
摘要： Provided is a method for producing a hydrogenated unsaturated polyhydroxyhydrocarbon polymer capable of suppressing side reactions such as a hydrogenolysis reaction of a terminal hydroxyl group and achieving a high hydrogenation rate in a short reaction time. A hydrogenated unsaturated polyhydroxyhydrocarbon polymer is obtained by a method including: hydrogenating an unsaturated polyhydroxyhydrocarbon polymer under the presence of a hydrogenation catalyst and a reaction solvent in the following two stages (I) and (II): (I) carrying out a hydrogenation reaction in a temperature range of 80°C to 130°C until a hydrogenation rate of at least 30 mol% is achieved; and then (II) carrying out a hydrogenation reaction at a temperature higher than 130°C until a hydrogenation rate of at least 98 mol% is achieved.
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公开(公告)号：EP3061781A1
公开(公告)日：2016-08-31
申请号：EP14856067.5
申请日：2014-10-21
CPC分类号： C08G18/6208 , C08F8/14 , C08G18/10 , C08G18/4277 , C08G18/69 , C08G18/7621 , C08G63/823 , C08G18/3206
摘要： The present invention provides a polyol composition comprising a polyol having a polyester chain, wherein the polyol composition substantially contains no metal-base polymerization catalyst and an amount of phosphorus element derived from a polymerization catalyst is 1 to 1000 ppm. Furthermore, the present invention provides a method for producing a polyol composition comprising reacting a compound having an active hydrogen with a compound having at least one selected from the group consisting of carboxyl group, ester group and acid halide group in the presence of 0.0001-0.05 parts by mol of a phosphorus compound with respect to 1 part by mol of the active hydrogen without using a metal-based polymerization catalyst.
摘要翻译： 本发明提供一种多元醇组合物，其含有具有聚酯链的多元醇，其中所述多元醇组合物基本上不含金属 - 基聚合催化剂，并且来自聚合催化剂的磷元素的量为1〜1000ppm。 此外，本发明提供一种多元醇组合物的制造方法，其包括在0.0001-0.05的存在下使具有活性氢的化合物与选自羧基，酯基和酰卤基中的至少一种的化合物反应 相对于1摩尔的活性氢而言，不使用金属类聚合催化剂，磷化合物的摩尔数为1摩尔。
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公开(公告)号：EP2821423A1
公开(公告)日：2015-01-07
申请号：EP13797500.9
申请日：2013-05-23
IPC分类号： C08G18/66
CPC分类号： C08G18/4277 , C08G2/10 , C08G18/10 , C08G18/3206 , C08G18/4275 , C08G18/664 , C08G18/69 , C08G18/694 , C08G18/7621
摘要： A polybutadiene having a hydroxyl group at a terminal end thereof is reacted with a lactone compound such as an ε-caprolactone to obtain a polymer polyol represented by formula (I): HO-X 1 -Y-X 2 -OH (wherein X 1 and X 2 each independently represents a polyester component and Y represents a polybutadiene component), the polymer polyol is reacted with an unsymmetric diisocyanate to obtain a urethane prepolymer, and then the urethane prepolymer is reacted with a chain extender to obtain a polyurethane.
摘要翻译： 将其末端具有羟基的聚丁二烯与内酯化合物如μ-己内酯反应，得到式（I）表示的聚合物多元醇：HO-X 1 -YX 2 -OH（其中X 1和X 2各自独立地表示聚酯组分，Y表示聚丁二烯组分），聚合物多元醇与不对称二异氰酸酯反应以获得氨基甲酸酯预聚物，然后将氨基甲酸酯预聚物与扩链剂反应以获得聚氨酯。
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