Alkali/transition metal halo - and hydroxy-phosphates and related electrode active materials
    61.
    发明公开
    Alkali/transition metal halo - and hydroxy-phosphates and related electrode active materials 审中-公开
    卤素和羟基改性剂磷酸盐铀碱/Übergangsmetallenund verwandte elektrodenmaterialien

    公开(公告)号:EP2242134A1

    公开(公告)日:2010-10-20

    申请号:EP10172159.5

    申请日:2002-10-18

    IPC分类号: H01M4/58 C01B25/455

    摘要: Electrode active materials comprising lithium or other alkali metals, a transition metal, a phosphate or similar moiety, and a halogen or hydroxyl moiety. Such electrode actives include those of the formula:

             A a M b (XY 4 ) c Z d ,

    wherein
    (a) A is selected from the group consisting of Li, Na, K, and mixtures thereof, and 0
    (b) M comprises one or more metals, comprising at least one metal which is capable of undergoing oxidation to a higher valence state, and 1 ≤ b ≤ 3;
    (c) XY 4 is selected from the group consisting of X'O 4-x Y' x , X'O 4-y Y' 2y , and mixtures thereof, where X' is S; Y' is halogen; 0 ≤ x
    (d) Z is OH, halogen, or mixtures thereof, and 0

    wherein M, X, Y, Z, a, b, c, d, x and y are selected so as to maintain electroneutrality of said compound.
    In a preferred embodiment, M comprises two or more transition metals from Groups 4 to 11 of the Periodic Table. In another preferred embodiment, M comprises M'M", where M' is at least one transition metal from Groups 4 to 11 of the Periodic Table; and M" is at least one element from Groups 2, 3, 12, 13, or 14 of the Periodic Table. Preferred embodiments include those having where c = 1, those where c = 2, and those where c=3. Preferred embodiments include those where a 3 and c = 3. This invention also provides electrodes comprising an electrode active material of this invention, and batteries that comprise a first electrode having an electrode active material of this invention; a second electrode having a compatible active material; and an electrolyte.

    摘要翻译: 包含锂或其它碱金属,过渡金属,磷酸盐或类似部分的电极活性材料以及卤素或羟基部分。 这种电极活性物质包括下列物质:ƒ€ƒ€ƒ€ƒ€ƒ€ƒA a M b(XY 4)c Z d,其中(a)A选自Li ,Na,K及其混合物,0 3和c = 3的那些。本发明还提供包含本发明的电极活性材料的电极和电池 其包括具有本发明的电极活性材料的第一电极; 具有相容的活性物质的第二电极; 和电解质。

    PREPARATION OF LITHIUM HEXAFLUOROPHOSPHATE SOLUTIONS
    64.
    发明公开
    PREPARATION OF LITHIUM HEXAFLUOROPHOSPHATE SOLUTIONS 失效
    HERSTELLUNG VON锂电池

    公开(公告)号:EP0735983A4

    公开(公告)日:1997-03-26

    申请号:EP94926652

    申请日:1994-09-02

    申请人: FMC CORP

    摘要: A process for preparing solutions of lithium hexafluorophosphate comprising reacting, under basic conditions, a lithium salt with a salt selected from sodium, potassium, ammonium, or organo ammonium hexafluorophosphate salt in a low boiling, non-protic organic solvent to produce a solution of lithium hexafluorophosphate and a precipitated sodium, potassium, ammonium, or organo ammonium salt containing the anion of the reactant lithium salt.

    摘要翻译: 一种制备六氟磷酸锂溶液的方法,包括在碱性条件下,使锂盐与选自钠,钾,铵或有机铵六氟磷酸盐的盐在低沸点非质子有机溶剂中反应,以产生锂 六氟磷酸盐和含有反应物锂盐阴离子的沉淀钠,钾,铵或有机铵盐。

    VERFAHREN ZUR HERSTELLUNG VON ALKALIMONOFLUORPHOSPHAT
    65.
    发明授权
    VERFAHREN ZUR HERSTELLUNG VON ALKALIMONOFLUORPHOSPHAT 失效
    用于生产碱单氟磷酸钠。

    公开(公告)号:EP0564451B1

    公开(公告)日:1994-09-07

    申请号:EP91902196.4

    申请日:1990-12-24

    IPC分类号: C01B25/455

    CPC分类号: C01B25/455

    摘要: In a method for manufacturing alkalimonofluorophosphate of general formaula M2PO3F (I), where M stands for the cation of a metal of the first main group of the periodic system, in particular potassium, a reaction mixture containing alkali metal cations M, phosphate, fluoride, particularly in the form of alkali hydroxyde, phosphoric acid and hydrofluoric acid, and water, the molar ratio of M:P:F being (2±0,1):(1±0.05):(1±0.1) and the molar ratio of water:P being at least 1:1, is heated to a temperature of 150 °C to 400 °C. Alkalimonofluorophosphate of general formula (I) occurs, with evaporation of water, as a reaction product, which is then isolated.

    Process for producing calcium phosphate
    68.
    发明公开
    Process for producing calcium phosphate 失效
    Verfahren zur Herstellung von Kalziumphosphat。

    公开(公告)号:EP0265945A2

    公开(公告)日:1988-05-04

    申请号:EP87115903.4

    申请日:1987-10-29

    IPC分类号: C01B25/32 C01B25/455

    CPC分类号: C01B25/322 C01B25/455

    摘要: A process for producing a calcium phosphate comprising the steps of (a) dissolving at least one member selected from the group consisting of calcium hydroxide and calcium oxide in water with at least one member selected from the group consisting of a sugar, a sugar alcohol, and a polyhydric alcohol; (b) and adding phosphoric acid to the solution obtained to precipitate a calcium phosphate.

    摘要翻译: 一种生产磷酸钙的方法,包括以下步骤:(a)将选自氢氧化钙和氧化钙的至少一种物质与水中的至少一种物质一起溶解,所述至少一种选自糖,糖醇, 和多元醇; (b),并向得到的溶液中加入磷酸以沉淀磷酸钙。

    Mittel und Verfahren zum Konservieren von Holz und Holzwerkstoffen
    69.
    发明公开
    Mittel und Verfahren zum Konservieren von Holz und Holzwerkstoffen 失效
    Mittel und Verfahren zum Konservieren von Holz und Holzwerkstoffen。

    公开(公告)号:EP0139142A1

    公开(公告)日:1985-05-02

    申请号:EP84109718.1

    申请日:1984-08-16

    CPC分类号: B27K3/163 B27K3/32 B27K5/02

    摘要: Die vorliegende Erfindung betrifft ein Mittel zum Konservieren von Holz und Holzwerkstoffen, das Alkalimonofluorphosphat und/oder Alkalidifluorphosphat der allgemeinen Formel M 2 PO 3 F und/oder MP0 3 F 2 , in der M Natrium, Kalium und/oder Ammonium bedeutet, enthält oder daraus besteht. Das Holzkonservierungsmittel besteht nach einer bevorzugten Ausführungsform aus einem Gemisch von Alkalimonofluorphosphat und/oder Alkalidifluorphosphat, mindestens einer bioziden und/oder feuerhemmenden chemischen Verbindung oder einem Verbindungsgemisch, das als mindestens ein Bestandteil eine biozide und/oder feuerhemmende chemische Verbindung enthält, und/oder mindestens einem Netzmittel, Emulgator, Farbstoff und/oder Pigment unter Einhaltung bestimmter Gewichtsmengen dieser Verbindungen.
    Die Erfindung betrifft weiterhin ein Verfahren zum Konservieren von Holz, wobei das Holz im Tauch- oder Sprühverfahren mit einer 5 bis 35 gew.-%igen, vorzugsweise 8 bis 25 gew.-%igen, wäßrigen Lösung oder im Druck-und oder Vakuum- oder Doppelvakuumverfahren mit einer 1,5 bis 7 gew.-%igen, vorzugsweise 2 bis 5 gew.-%igen, wäßrigen Lösung dieses Holzschutzmittels behandelt wird.

    摘要翻译: 1.一种基于至少一种含氟或氟离子的碱金属盐来保存木材和木材的试剂,其特征在于,作为含有氟或氟离子的碱金属盐,所述木材防腐剂包括或由其组成。1.碱式氟磷酸盐和/ 或通式为M 2 PO 3 F和/或MPO 3 F 2的碱式二氟磷酸盐,其中M表示钠,钾和/或铵。

    METHOD FOR PREPARING CARBON-COATED SODIUM IRON FLUOROPHOSPHATE FROM WASTE LITHIUM IRON PHOSPHATE, AND USE THEREOF

    公开(公告)号:EP4406915A1

    公开(公告)日:2024-07-31

    申请号:EP23843969.9

    申请日:2023-12-13

    IPC分类号: C01B25/455

    CPC分类号: Y02W30/84

    摘要: The present invention relates to the field of sodium-ion battery technology, and specifically, to a method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate and the application thereof. The method for preparing carbon-coated sodium iron fluorophosphate from waste lithium iron phosphate includes: mixing a waste lithium iron phosphate material with an alkaline solution for reaction, followed by solid-liquid separation, to obtain an aluminum-containing filtrate and a lithium iron phosphate filter residue; mixing the lithium iron phosphate filter residue, aluminum chloride and sodium chloride uniformly, followed by vacuum calcination, to obtain a calcination material; and mixing the calcination material with at least one of a sodium source, an iron source and a phosphorus source uniformly to obtain a mixture to which a fluorine source, a carbon source and a solvent are added for uniformly mixing, followed by drying and calcination sequentially to obtain the carbon-coated sodium iron fluorophosphate. The method has the advantages of low costs, a high added value, a short process, and a high recovery rate, and the carbon-coated sodium iron fluorophosphate obtained from the method has excellent electrochemical performance.