PROCESS FOR THE PRODUCTION OF CHLORINATED PROPENES
    61.
    发明公开
    PROCESS FOR THE PRODUCTION OF CHLORINATED PROPENES 审中-公开
    生产氯化丙烷的方法

    公开(公告)号:EP2935165A1

    公开(公告)日:2015-10-28

    申请号:EP13817817.3

    申请日:2013-12-18

    申请人: Blue Cube IP LLC

    摘要: Processes for the production of chlorinated propenes are provided. The processes make use of 1,2-dichloropropane as a starting material and subject a feedstream comprising the same to an ionic chlorination process. At least a portion of any tri- and tetrachlorinated propanes not amenable to ionic chlorination conditions are removed from the ionic chlorination product stream, or, are subjected to chemical base dehydrochlorination step. In this way, recycle of intermediates not amenable to ionic chlorination reactions is reduced or avoided, as is the buildup of these intermediates within the process. Selectivity and, in some embodiments, yield of the process is thus enhanced.

    摘要翻译: 提供了生产氯化丙烯的方法。 该方法使用1,2-二氯丙烷作为起始原料并使包含其的进料流进行离子氯化过程。 从离子氯化产物流中除去不适合离子氯化条件的任何三氯化和四氯化丙烷的至少一部分,或者进行化学碱脱氯化氢步骤。 以这种方式,减少或避免了不适合于离子氯化反应的中间体的再循环,这些中间体在该过程中的积聚也是如此。 因此,选择性和在一些实施方案中该方法的收率得到提高。

    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES
    62.
    发明公开
    PROCESS FOR THE PRODUCTION OF CHLORINATED ALKANES 有权
    VERFAHREN ZUR HERSTELLUNG VON CHLORIERTEN PROPANEN

    公开(公告)号:EP2785671A1

    公开(公告)日:2014-10-08

    申请号:EP12799450.7

    申请日:2012-11-30

    IPC分类号: C07C17/10 C07C19/01

    CPC分类号: C07C17/06 C07C17/10 C07C19/01

    摘要: Processes for the production of chlorinated alkanes are provided. The present processes comprise catalyzing the chlorination of a feedstream comprising one or more alkanes and/or alkenes with a catalyst system comprising one or more inorganic iodine salts and/or lower than conventional levels of elemental iodine and at least one Lewis acid. The processes are conducted in a nonaqueous media, and so, the one or more inorganic iodine salts are recoverable and/or reusable, in whole or in part.

    摘要翻译: 提供了生产氯代烷烃的方法。 本发明的方法包括用包含一种或多种无机碘盐和/或低于常规水平的元素碘和至少一种路易斯酸的催化剂体系催化包含一种或多种烷烃和/或烯烃的进料流的氯化。 该方法在非水介质中进行,因此,一种或多种无机碘盐可全部或部分回收和/或可重复使用。

    METHOD FOR PURIFYING CHLORINATED HYDROCARBON
    63.
    发明公开
    METHOD FOR PURIFYING CHLORINATED HYDROCARBON 审中-公开
    程序对清洁氯代烃

    公开(公告)号:EP2755937A2

    公开(公告)日:2014-07-23

    申请号:EP12770267.8

    申请日:2012-09-13

    摘要: The present invention provides a method for purifying chlorinated hydrocarbon(s), comprising cooling a mixture containing hydrogen fluoride and at least one chlorinated hydrocarbon selected from the group consisting of 2-chloro-3,3,3-trifluoropropene, 2,3-dichloro-3,3-difluoropropene, 1,2,3-trichloro-1,1-difluoropropane, and 1,1,1,2,3-pentachloropropane to cause liquid-liquid separation of the mixture into an upper liquid phase having a high hydrogen fluoride concentration and a lower liquid phase having a high chlorinated hydrocarbon concentration, and a method for purifying a chlorinated hydrocarbon, comprising subjecting the lower liquid phase obtained by the liquid-liquid separation to a distillation operation. According to the present invention, a chlorinated hydrocarbon can be purified by separating and removing hydrogen fluoride from a chlorinated hydrocarbon-hydrogen fluoride mixture under simple and economically advantageous conditions.

    CATALYTIC DEHYDROCHLORINATION OF HYDROCHLOROFLUOROCARBONS
    66.
    发明公开
    CATALYTIC DEHYDROCHLORINATION OF HYDROCHLOROFLUOROCARBONS 审中-公开
    催化氢氯氟烃的脱氢氯化反应

    公开(公告)号:EP2678300A1

    公开(公告)日:2014-01-01

    申请号:EP12708435.8

    申请日:2012-02-21

    摘要: A dehydrochlorination process is disclosed. The process involves contacting RfCHClCH2Cl with a chromium oxyfluoride catalyst in a reaction zone to produce a product mixture comprising RfCCl═CH2, wherein Rf is a perfluorinated alkyl group.

    摘要翻译: 公开了一种脱氢过程。 该方法包括在反应区中使R fCHClCH 2 Cl与氟氧化铬催化剂接触以产生包含R f CCl = CH 2的产物混合物,其中R f是全氟化烷基。

    Swing reactor and process for oxychlorination
    69.
    发明公开
    Swing reactor and process for oxychlorination 审中-公开
    Schwingungsreaktor und Verfahren zur Oxychlorierung

    公开(公告)号:EP2383033A1

    公开(公告)日:2011-11-02

    申请号:EP10250776.1

    申请日:2010-04-14

    申请人: Stauffer, John E.

    发明人: Stauffer, John E.

    摘要: A reactor with swing feeds is provided for oxychlorination. This reactor comprises multiple inlets with controls capable of introducing feed streams sequentially to the reactor. In one configuration, a feed stream comprises a paraffin or olefin hydrocarbon such as methane or ethylene, and a second feed stream comprises oxygen and hydrogen chloride. By segregating these feeds, combustion reactions can be minimized and yields of chlorinated components increased.

    摘要翻译: 提供具有摆动进料的反应器用于氧氯化。 该反应器包括具有能够将进料流顺序地引入反应器的控制器的多个入口。 在一种构型中,进料流包含链烷烃或烯烃如甲烷或乙烯,第二进料流包含氧和氯化氢。 通过分离这些进料,燃烧反应可以最小化,并且氯化组分的产率增加。