摘要:
A gas-phase olefin polymerisation system is provided with means for sensing a potentially dangerous condition such as a rapidly increasing temperature and/or pressure, and means for introducing carbon dioxide into the system to at least reduce the rate of polymerisation. The system may be a stirred-bed system provided with means for automatically introducing carbon dioxide into the system in response to failure of the stirrer motor.
摘要:
The present specification relates to an olefin oligomerization method and specifically to an olefin oligomerization method comprising the step of subjecting an olefin to a multimerization reaction by controlling a reaction temperature such that the weight ratio of 1-hexene to 1-octene within a product comprising 1-hexene and 1-octene has a predetermined value, in the presence of an oligomerization catalyst system comprising a ligand compound, a transition metal compound, and a cocatalyst, wherein the predetermined value for the weight ratio of 1-hexene to 1-octene within the product is selected in a range of 1:0.5 to 1:7. By the method, 1-hexene and 1-octene can be produced in a desired ratio.
摘要:
A polyolefin manufacturing system and method including polymerizing olefin in a first reactor to form a polyolefin, transferring the polyolefin to a second reactor, polymerizing olefin in the second reactor, and discharging a product polyolefin from the second reactor. The system and method including operating the first reactor with a first reactor pressure relief system and the second reactor with a second reactor pressure relief system, both pressure relief systems to discharge to a flare system, and wherein a relief instrumented system (RIS) is configured to direct at least one process interlock that mitigates an excess reaction scenario as an overpressure relief scenario.
摘要:
The present invention relates to a process for restabilization of free-radically polymerizable monomers. The process comprises the steps of (a) introducing a solution of an inhibitor of the free-radical polymerization together with an inert pressurized gas into a vessel (1) containing the monomers via a line (10) comprising an ascending portion and (b) mixing the contents of the vessel and the inhibitor solution by blowing in gas through the line (10). In step (a), the flow rate of the pressurized gas is adjusted so as to result in, as the flow regime of the inhibitor solution, a plug flow or ring flow, and, in step (b), the superficial gas velocity is adjusted to ≥ 0.1 mm/s. The present invention further relates to a supply unit (11) for performance of the process.
摘要:
Embodiments of the present application provide a method for manufacturing a polyolefin and a system for implementing the method. The method comprises combining a catalyst with a diluent mixture containing a diluent and an olefin monomer in a polymerization reactor. The diluent may comprise propane, butane, or isobutane, or a combination thereof. The polymerization reactor is operated at a pressure above a critical pressure of the diluent, but below the critical temperature of the diluent.
摘要:
There is provided a bubble column type hydrocarbon synthesis reactor which synthesizes a hydrocarbon compound by a chemical reaction of a synthesis gas including hydrogen and carbon monoxide as main components, and a slurry having solid catalyst particles suspended in liquid. The hydrocarbon synthesis reactor includes a reactor main body which accommodates the slurry, a synthesis gas supplying section which supplies the synthesis gas to the slurry, and an introducing portion which introduces a cooling fluid having a lower temperature than the slurry into the reactor main body.
摘要:
Embodiments of the present application provide a method for manufacturing a polyolefin and a system for implementing the method. The method comprises combining a catalyst with a diluent mixture containing a diluent and an olefin monomer in a polymerization reactor. The diluent may comprise propane, butane, or isobutane, or a combination thereof. The polymerization reactor is operated at a pressure above a critical pressure of the diluent, but below the critical temperature of the diluent.