摘要:
There are described color-providing compounds having at least two cyclic 1,3-sulfur-nitrogen moieties and one complete dye or dye intermediate. The color-providing compound is stable in the photographic processing composition but capable of undergoing cleavage in the presence of an imagewise distribution of silver ions and/or soluble silver complex made available as a function of development to liberate a complete dye or dye intermediate in an imagewise distribution corresponding to that of the silver ion and/or the soluble silver complex. The color-providing compounds are useful as image-forming materials in color photographic, photothermographic, thermographic, and other processes.
摘要:
There are described heat-developable photosensitive image-recording materials which include a compound having at least one cyclic 1,3-sulfur-oxygen moiety. The compound is stable in the photographic processing composition but capable of undergoing cleavage in the presence of an imagewise distribution of silver ions and/or soluble silver complex made available as a function of development to liberate a reagent in an imagewise distribution corresponding to that of the silver ion and/or the soluble silver complex. The reagent includes a photographically useful group such as a complete dye or dye intermediate.
摘要:
A photothermographic element comprising a support bearing at least one heat-developable, photosensitive, image-forming photothermographic emulsion layer comprising: (a) a photosensitive silver halide; (b) a non-photosensitive, reducible source of silver; (c) a reducing agent for the non-photosensitive reducible silver source; and (d) a binder; wherein the reducing agent is a hydrazide redox-dye-releasing compound of the general formulae: R 1 -[-C(O)-NH-NH-SO 2 -X-D] n or [D-X-C(O)-NH-NH-SO 2 -] n -R 2 wherein: D represents the chromophore of a thermally mobile dye; X represents a single bond or a divalent linking group; R 1 and R 2 independently represent an organic group; and n ≧ 1.
摘要:
A method which comprises the steps of: providing a heat-processible color photosensitive material that has at least a light-sensitive silver halide, a reducing agent, a binder and a dye-providing material on a support, which dye-providing material contains either a dye portion represented by the following general formula (1) or a dye portion represented by the following general formula (2) or both; performing imagewise exposure on said photosensitive material; subsequent to or simultaneously with the imagewise exposure, thermally developing said photosensitive material in close contact with an image-receiving material; transferring onto said image-receiving material all or part of the diffusible dye containing said dye portion which is formed from said dye-providing material as a function of development; during or after the transfer, chelating part or all of the diffusible dye with a metal to thereby form an image of the chelated dye in said image-receiving material:
where X represent the atomic group necessary to form an aromatic nitrogenous heterocyclic ring; R₁ is a hydrogen atom, a halogen atom or a monovalent organic group; m is an integer of 0 or 1 - 3, provided that when m is 2 or 3, R₁ may be the same or different; Y is a hydroxyl group or a group
(where R and R₇ each represents a hydrogen atom or an optionally substituted alkyl group); and R², R³, R⁴ and R⁵ each represents a hydrogen atom, a halogen atom, or a monovalent organic group.
摘要:
The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I) wherein EAG represents a group which accepts an electron from a reducing substance; N and 0 each represents nitrogen atom and an oxygen atom, respectively; R' and R 2 each represents a substituent other than a hydrogen atom, and when R' or R 2 is bonded to -(Time)̵― t ― PUG, R' or R 2 is a mere bond or a substituent other than a hydrogen atom, and R' and R 2 may be bonded to each other to form a ring; Time represents a group for releasing PUG via the subsequent reaction as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound of general formula (I); PUG represents a photographically useful group; t is an integer of 0 or 1; the full lines in the formula each mean a bond; and the dotted lines therein mean that at least one of the dotted lines is a bond. In particular, compounds of the following formula (II) and (III) are preferred among those of the formula (I): wherein R 3 is bonded to the nitrogen atom or oxygen atom in the formula, and represents an atomic group necessary for the formation of a 3 to 8-membered mono-or fused-hetero ring; wherein R 4 and R 5 each represents a mere bond, a hydrogen atm or a substituent group, and they may be . bonded to each other to form a saturated or unsaturated carbon ring or hetero ring; and X represents a divalent binding group.
摘要:
The present invention provides silver halide photographic materials containing a havel compound, which when reduced, releases a photographically useful group as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound and which is represented by the following general formula (I) wherein EAG represents a group which accepts an electron from a reducing substance; N and 0 each represents nitrogen atom and an oxygen atom, respectively; R' and R 2 each represents a substituent other than a hydrogen atom, and when R' or R 2 is bonded to -(Time)̵― t ― PUG, R' or R 2 is a mere bond or a substituent other than a hydrogen atom, and R' and R 2 may be bonded to each other to form a ring; Time represents a group for releasing PUG via the subsequent reaction as triggered off by the cleavage of the nitrogen-oxygen single bond in the compound of general formula (I); PUG represents a photographically useful group; t is an integer of 0 or 1; the full lines in the formula each mean a bond; and the dotted lines therein mean that at least one of the dotted lines is a bond. In particular, compounds of the following formula (II) and (III) are preferred among those of the formula (I): wherein R 3 is bonded to the nitrogen atom or oxygen atom in the formula, and represents an atomic group necessary for the formation of a 3 to 8-membered mono-or fused-hetero ring; wherein R 4 and R 5 each represents a mere bond, a hydrogen atm or a substituent group, and they may be . bonded to each other to form a saturated or unsaturated carbon ring or hetero ring; and X represents a divalent binding group.