A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom
    72.
    发明公开
    A process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains and the products obtained therefrom 有权
    一种制备具有聚烯烃骨架和一种或多种聚合物的多个侧链和由此获得的产物的接枝共聚物的过程

    公开(公告)号:EP3034544A1

    公开(公告)日:2016-06-22

    申请号:EP14198476.5

    申请日:2014-12-17

    摘要: The present invention relates to a cascade process for the preparation of a graft copolymer comprising a polyolefin main chain and one or a multiple polymer side chains. The process comprising step A) of copolymerizing at least one first type of olefin monomer and at least one second type of metal-pacified functionalized olefin monomer using a catalyst system to obtain a polyolefin main chain having one or multiple metal-pacified functionalized short chain branches, the catalyst system comprising: i) a metal catalyst or metal catalyst precursor comprising a metal from Group 3-10 of the IUPAC Periodic Table of elements; and ii) optionally a co-catalyst; and step B) of forming one or multiple polymer side chains on the polyolefin main chain having one or multiple metal-pacified functionalized short chain branches to obtain the graft copolymer.

    摘要翻译: 本发明涉及一种用于接枝共聚物的包含聚烯烃的主链和一个或多个聚合物侧链的制备级联过程。 使用催化剂系统,以获得具有一个或多个金属平定官能短链分支的聚烯烃主链共聚至少一种第一类型的烯烃单体和至少一种第二类型的金属平定官能化烯烃单体的方法,包括步骤A) ,该催化剂体系包含:i)金属或金属催化剂催化剂前体,包含选自第3至元件的IUPAC周期表的第10族的金属; 和ii)任选的助催化剂; 并形成在具有一个或多个金属官能平定短链分支,以获得接枝共聚物中的聚烯烃主链的一个或多个聚合物侧链的步骤B)。

    METHOD OF PREPARING POLY(ALKYLENE CARBONATE) VIA COPOLYMERIZATION OF CARBON DIOXIDE/EPOXIDE IN THE PRESENCE OF NOVEL COMPLEX
    75.
    发明公开
    METHOD OF PREPARING POLY(ALKYLENE CARBONATE) VIA COPOLYMERIZATION OF CARBON DIOXIDE/EPOXIDE IN THE PRESENCE OF NOVEL COMPLEX 审中-公开
    用于生产聚(ALKYLENKARBONAT)关于新型复合物的存在共聚碳/环氧

    公开(公告)号:EP2976348A1

    公开(公告)日:2016-01-27

    申请号:EP14769258.6

    申请日:2014-03-20

    IPC分类号: C07F15/00 C07F11/00 C08G64/30

    摘要: Provided is a method of preparing poly(alkylene carbonate) using a molecular weight regulator in a process of preparing a copolymer of carbon dioxide/epoxide using a novel complex synthesized from salen-type ligand including a quaternary ammonium salt as a catalyst. According to the present invention, even though the molecular weight regulator is used, an activity of the catalyst may be stably maintained, whereby the low molecular weight of poly(alkylene carbonate) having a desirable level may be effectively provided. In addition, it is expected that since the novel complex as the catalyst of the present invention has a simple structure as compared to the existing copolymerization catalyst, due to the economical preparation cost thereof, the novel complex may be effectively applied to a large-scale commercial process.

    PROCÉDÉ DE SYNTHÈSE D'OLIGOMÈRES DE GLYCÉROL ACYLÉS
    76.
    发明公开
    PROCÉDÉ DE SYNTHÈSE D'OLIGOMÈRES DE GLYCÉROL ACYLÉS 有权
    PROCÉDÉDESYNTHÈSED'OLIGOMÈRESDEGLYCÉROLACYLÉS

    公开(公告)号:EP2970573A1

    公开(公告)日:2016-01-20

    申请号:EP14715358.9

    申请日:2014-03-12

    IPC分类号: C08G64/02 C08G64/30

    CPC分类号: C08G64/0216 C08G64/305

    摘要: The invention relates to a method for the synthesis of acylglycerol oligomers, characterised in that it comprises reacting: at least one precursor selected from the group formed by cyclic carbonic esters of α/α'-acylglycerol having general formula (IV) (Formula); at least one metal catalyst selected from the group formed by metal cation salts, organometallic compounds and metal oxides; and at least one organic primer selected from the group formed by hydroxyl organic compounds, at a reaction temperature below 220° C.

    摘要翻译: 酰基甘油低聚物的合成方法技术领域本发明涉及酰基甘油低聚物的合成方法,其特征在于,该方法包括使至少一种选自具有通式(IV)(式)的α/α'-酰基甘油的环状碳酸酯形成的前体; 至少一种选自金属阳离子盐,有机金属化合物和金属氧化物的金属催化剂; 和至少一种选自羟基有机化合物的有机引物,反应温度低于220℃

    POLYCARBONATE RESIN COMPOSITION AND MOLDED ARTICLE

    公开(公告)号:EP2554598A4

    公开(公告)日:2015-10-21

    申请号:EP11759572

    申请日:2011-03-25

    发明人: SASAKI HARUO

    摘要: The invention is to provide a polycarbonate resin having excellent light resistance, transparency, hue, heat resistance, thermal stability, and mechanical strength. The invention relates to a polycarbonate resin composition which includes a polycarbonate resin at least containing structural units derived from a dihydroxy compound having the portion represented by the following general formula (1) as part of the structure thereof, the polycarbonate resin composition giving a molded object having a thickness of 3 mm which has a haze, as measured in accordance with JIS K7105, of 12 or less after having undergone a 1,200-hour irradiation treatment with a sunshine carbon arc lamp through a type-A glass filter in accordance with JIS B7753 in an environment having a black panel temperature of 63°C, a relative humidity of 50%, and a rainfall spray period per hour of 12 minutes at a discharge voltage of 50 V and a discharge current of 60 A. (The case where the portion represented by the general formula (1) is part of -CH 2 -O-H is excluded.)