公开(公告)号：EP2513195A1

公开(公告)日：2012-10-24

申请号：EP10838031.2

申请日：2010-01-12

申请人： Invista Technologies S.à.r.l.

发明人： OSBORNE, Robert, B. ,  SUN, Qun ,  SUN, Yanhui ,  SISLER, Gregg, M. ,  EISSMANN, Roy, N. ,  ORLANDI, Robert, D.

IPC分类号： C08G65/20 ,  C08G65/28 ,  C08G65/30

CPC分类号： C08G65/20 ,  C08G65/2678 ,  C08G65/2684 ,  C08G65/2696 ,  C08G65/30

摘要： The present invention relates to an improved, fully-integrated continuous process of enhanced process operability for manufacturing copolyether glycols having enhanced physical properties by polymerization of a reaction mixture comprising tetrahydrofuran and at least one alkylene oxide in the presence of an acid catalyst and at least one compound containing reactive hydrogen atoms. The copolyether glycols manufactured by the present process have enhanced physical properties of increased alkylene oxide incorporation, average molecular weight and polydispersity, as well as reduced crystallinity, color, oligomeric cyclic ether content, and linear oligomer having an average molecular weight of up to about 400 dalton content.

摘要翻译： 本发明涉及一种改进的完全整合的连续工艺，其通过在酸催化剂存在下聚合包含四氢呋喃和至少一种烯化氧的反应混合物而具有增强的物理性质的共聚醚二醇， 含有活性氢原子的化合物。 通过本发明方法制造的共聚醚二醇具有提高的烯化氧结合物的物理性质，平均分子量和多分散性，以及降低的结晶度，颜色，低聚环醚含量和平均分子量高达约400的直链低聚物 道尔顿含量。

公开(公告)号：EP1361243B1

公开(公告)日：2010-11-24

申请号：EP01919942.1

申请日：2001-04-16

申请人： Asahi Kasei Fibers Corporation

发明人： KODAMA, Tamotsu ,  MINOURA, Haruyuki ,  TSUNEMATSU, Yoshiyuki ,  FUKUZONO, Toshihiko ,  FURUBEPPU, Satoshi,

IPC分类号： C08G65/20 ,  C08G65/30 ,  C08G65/28

CPC分类号： C08G65/30 ,  C08G65/20 ,  C08G65/2609 ,  C08G65/2696

摘要： An oxytetramethylene glycol copolymer which is obtained by copolymerizing tetrahydrofuran with neopentyl glycol and has specific values of number-average molecular weight (Mn), molecular-weight distribution (Mn/Mw), degree of total neopentyl glycol copolymerization (Nw), and degree of partial neopentyl glycol copolymerization (Nh); a process for producing the copolymer; and a method of purifying the oxytetramethylene glycol copolymer contained in a copolymerization reaction mixture comprising the copolymer and an unreacted diol which comprises adding fresh tetrahydrofuran to the mixture in an amount at least the same as that of the unreacted diol by weight and distilling off the unreacted diol together with the tetrahydrofuran.

公开(公告)号：EP2028177B1

公开(公告)日：2009-11-18

申请号：EP08161171.7

申请日：2008-07-25

申请人： Air Products and Chemicals, Inc.

发明人： Wang, Andrew Wilson ,  Grossmann, George Ernest

IPC分类号： C07C227/14

CPC分类号： C07C227/18 ,  C08G65/20 ,  C08G65/3312 ,  C08G65/3326 ,  C08G65/33313 ,  C07C229/60

公开(公告)号：EP2079776A1

公开(公告)日：2009-07-22

申请号：EP08803272.7

申请日：2008-08-27

申请人： BASF SE

发明人： WABNITZ, Tobias ,  FERRE GIMENEZ, Ricardo ,  LAUBNER, Robert ,  STOLLE, Ralf

IPC分类号： C08G65/20

CPC分类号： C08G65/20

摘要： The invention relates to a method for the depolymerization of mixtures that contain mono- and/or diesters of polytetrahydrofurane in the presence of an acid catalyst and of a C1 to C3 alcohol at temperatures of 80 to 200 °C and a pressure of 0.05 to 0.5 MPa, the molar ratio of the C1 to C3 alcohol to the carboxyl groups contained in the mixture being greater than 1.

公开(公告)号：EP2028177A1

公开(公告)日：2009-02-25

申请号：EP08161171.7

申请日：2008-07-25

申请人： Air Products and Chemicals, Inc.

发明人： Wang, Andrew Wilson ,  Grossmann, George Ernest

IPC分类号： C07C227/14

CPC分类号： C07C227/18 ,  C08G65/20 ,  C08G65/3312 ,  C08G65/3326 ,  C08G65/33313 ,  C07C229/60

摘要： The present invention herein provides a process for making an aminobenzoate ester of an alcoholic organic compound. In one aspect, there is provided a process for making an aminobenzoate ester comprising the steps of: (a) providing a reaction mixture comprising an alkyl aminobenzoate an alcohol reagent and a suitable transesterification catalyst; (b) introducing an auxilliary alcohol to the reaction mixture; and (c) exposing the reaction mixture to conditions effective to provide an end-product mixture comprising the aminobenzoate ester.

摘要翻译： 本发明提供了制备醇有机化合物的氨基苯甲酸酯的方法。 一方面，提供一种制备氨基苯甲酸酯的方法，包括以下步骤：（a）提供包含烷基氨基苯甲酸酯与醇试剂和合适的酯交换催化剂的反应混合物; （b）将辅助醇引入反应混合物中; 和（c）将反应混合物暴露于有效提供包含氨基苯甲酸酯的最终产物混合物的条件下。

公开(公告)号：EP0811004B1

公开(公告)日：2006-12-06

申请号：EP96903699.5

申请日：1996-01-16

申请人： AEROJET-GENERAL CORPORATION

发明人： MALIK, Aslam, A. ,  MANSER, Gerald, E. ,  ARCHIBALD, Thomas, G. ,  DUFFY-MATZNER, Jetty, L. ,  HARVEY, William, L. ,  GRECH, Gary, J. ,  CARLSON, Roland, P.

IPC分类号： C07D305/06 ,  C08G65/22 ,  C08G81/00

CPC分类号： C08G65/226 ,  C07D305/06 ,  C08G18/10 ,  C08G18/5015 ,  C08G18/6677 ,  C08G65/00 ,  C08G65/18 ,  C08G65/20 ,  C08G18/32

摘要： This application is directed to fluorinated oxetane monomers and methods for making the monomers. The mono-substituted fluorinated oxetane monomers having fluorinated alkoxymethylene side-chains are prepared in high yield by the reaction of fluorinated alkoxides with either 3-halomethyl-3-methyloxetane premonomers or aryl sulfonate derivatives of 3-hydroxymethyl-3-methyloxetane premonomers. Preparation of a mono-substituted 3-bromomethyl-3-methyloxetane premonomer via a simple, high yield process amenable to commercial scale-up is also disclosed. The fluorinated oxetane monomers are useful for the production of fluorinated prepolymers and elastomers which exhibit an improved contact angle for drops of water on a fluorinated oxetane elastomer as compared to a TeflonTM surface.

公开(公告)号：EP1200204B1

公开(公告)日：2006-08-09

申请号：EP00940564.8

申请日：2000-06-19

申请人： THE SECRETARY OF STATE FOR DEFENCE

发明人： WILLIS, Colin, Robert ,  BADYAL, Jas, Pal, Singh University of Durham ,  BREWER, Stuart, Anson

IPC分类号： B05D7/24 ,  C08G65/22

CPC分类号： B05D1/62 ,  C08G65/20 ,  C09D171/02

摘要： A method for applying a reactive epoxy containing coating to a substrate, said method comprising subjecting said substrate to a plasma discharge in the presence of a compound of formula (I) or (IA) where R?1 or R1a¿ is an optionally substituted hydrocarbyl group or heterocyclic group; R2 is an optionally substituted straight or branched alkylene chain; and Y is oxygen or a bond. Surfaces obtained in this way may subsequently be derivatised as desired, or adhered to other surfaces.

公开(公告)号：EP1539854B1

公开(公告)日：2006-04-26

申请号：EP03798891.2

申请日：2003-09-04

申请人： BASF Aktiengesellschaft

发明人： PINKOS, Rolf ,  GERSTLAUER, Achim ,  HAUBNER, Martin ,  SCHLITTER, Stephan ,  KÄSHAMMER, Stefan ,  PFAFF, Klaus-Peter

IPC分类号： C08G65/20

CPC分类号： C08G65/20

摘要： The invention relates to a method for producing monoesters or diesters of polytetrahydrofuran or of tetrahydrofuran copolymers by polymerizing tetrahydrofuran in the presence of at least one telogen and/or comonomer on an acid catalyst. According to the invention, the polymerization reactor is started up with a mixture consisting of polytetrahydrofuran, the monoesters or diesters of the polytetrahydrofuran and/or of the THF copolymers, tetrahydrofuran, optionally, a comonomer and of at least one carboxylic acid and/or of a carboxylic acid anhydride.

公开(公告)号：EP1613684A1

公开(公告)日：2006-01-11

申请号：EP04724282.1

申请日：2004-03-30

申请人： BASF Aktiengesellschaft

发明人： HAUBNER, Martin ,  PINKOS, Rolf

IPC分类号： C08G65/20

CPC分类号： C08G65/2666 ,  C08G65/20

摘要： The invention relates to a method for the single-step production of polyoxyalkylene glycols by the copolymerisation of THF and alpha, omega diols in the presence of a heteropoly acid. Said method is characterised in that the content of organically bonded nitrogen in the alpha, omega diol is less than 15 ppm.

公开(公告)号：EP1219658B1

公开(公告)日：2006-01-11

申请号：EP00953515.4

申请日：2000-08-18

申请人： Asahi Kasei Kabushiki Kaisha

发明人： KODAMA, Tamotsu ,  MORI, Takeshi ,  AKEDO, Takaharu

IPC分类号： C08G65/20 ,  C08G65/26

CPC分类号： C08G65/30 ,  C08G65/20 ,  C08G65/2666

摘要： A polyoxytetramethylene glycol (PTMG) with improved heat resistance and low-viscosity characteristics which has the following properties (1) to (4): (1) the number-average molecular weight is 500 to 3,000; (2) the molecular-weight distribution which is the ratio of the weight-average molecular weight Mw to the number-average molecular weight Mn, Mw/Mn, is 1.8 or less; (3) the content of PTMG molecules having a molecular weight at least 6 times the number-average molecular weight is 2 to 5 wt.% based on the total amount of all the PTMG molecules; and (4) the content of heteropolyacids is 10 to 900 ppb by weight.