摘要:
Un système pulsé à résonance magnétique nucléaire destiné à une utilisation industrielle comprend un système de passage de l'échantillon (P, LI, V1, V2), un dispositif de réglage du champ magnétique (120, 124) et un dispositif de réglage thermique (134-138 et 142-146). La résonance est établie par une bobine (100) excitée par un émetteur récepteur (104) et interagissant avec l'échantillon et le champ magnétique en résonance pour établir des formes de courbe (C) de décroissance d'induction libre reçues et numérisées qui sont automatiquement analysées et mises sous forme de composantes Gaussiennes et exponentielles --. Le système prévoit des moyens de calcul à haute vitesse simplifiés avec une séquence de tests répétitive et des commandes thermiques qui minimisent systématiquement les erreurs pour garantir une détermination fiable de quantités de noyaux cibles dans des échantillons successifs provenant d'un processus industriel et utilisant un appareil fonctionnant selon le principe de l'écho de Spin Hahn pour régler automatiquement l'analyse de l'une ou de plusieurs des composantes analysées.
摘要:
Pulsed NMR system for industrial purposes comprising sample throughput system (P, LI, V1, V2) magnetic field adjustment (120, 124) and thermal adjustment (134-138 and 142-146). The resonance is established by a coil (100), excited by a transceiver (104) and interacting with the sample and the magnetic field at resonance to establish received and digitized free induction decay curve forms (C) which are automatically analyzed into Gaussian and exponential components -- providing simplified high speed computation means with repetitive test sequence and thermal controls that systematically minimize errors to assure reliable determination of target nuclei quantities in successive samples from an industrial process and utilizing Hahn spin echo based equipment to automatically adjust the analysis of one or more of the analyzed components.
摘要:
Flow measuring apparatus comprising a probe (1) coupled via a coaxial cable (2) to control circuitry with a current to voltage convertor (10), absolute value circuit (12), auto zero switch and integration (11, 27) and voltage to current circuit (18) yielding an analog output, corresponding to flow at the probe.
摘要:
In a method of and an apparatus for measuring a liquid content of a mixed phase fluid in a container, an oscillating voltage is applied to the fluid and a current with conductive and capacitive components derived, the conductive component being cancelled out. The capacitive component is phase shifted (34) into phase with the oscillating input voltage. A feedback loop (32, 23, ∑) attenuates the conductive component, avoiding amplifier saturation.
摘要:
An on-line nuclear magnetic resonance (NMR) system, and related methods, are useful for predicting one or more properties of interest of a polymer. In one embodiment, a neural network is used to develop a model which correlates process variables in addition to manipulated NMR output to predict a polymer property of interest. In another embodiment, a partial least square regression technique is used to develop a model of enhanced accuracy. Either the neural network technique or the partial least square regression technique may be used in conjunction with a described multi-model or best-model-selection scheme according to the invention. The polymer can be a plastic such as polyethylene, polypropylene, or polystyrene, or a rubber such as ethylene propylene rubber.
摘要:
Pulser NMR system for industrial measurements comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which Abragam, Gaussian, and exponential components are determined using a Marquardt-Levenberg iteration technique, and using regression techniques to correlate the curve components to the target nuclei.
摘要:
A pulsed nmr analysis system (figure 1a) for polymer materials (S2) extracted from industrial processes at a mobility enhancing temperature (figure 3) (at or above glass transition temperature for amorphous polymers, at the crystalline transition temperature for crystalline and semi-crystalline polymers). The sample is measured via nmr techniques and results correlated to viscosity and melt index or melt flow (which are related to average molecular weights). Substantial improvement of correlation of nmr derived constants and equations of a free induction decay curve with the foregoing polymer properties is obtained via (1) conducting the nmr process at a mobility enhancing temperature (normally elevated compared to the industrial process temperature of the industrial process) and (2) holding temperature substantially constant at such elevated temperature.
摘要:
A pulsed NMR analysis system and process comprising an air curtain (137), sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using linear or non-linear regression techniques to correlate the curve components to the target nuclei and to flow rates in plastic (MI and FRR for polyethylene and MF for polypropylene).
摘要:
A pulsed NMR analysis system and process comprising sample throughput system (P, LI, V1, V2) and user system controls (104) to establish digitized free induction decay curves (C), from which components functions are determined using non-linear regression techniques to correlate the curve components to the target nuclei.