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1.发明授权
公开(公告)号：EP0401388B1
公开(公告)日：1995-04-19
申请号：EP90901010.0
申请日：1989-12-19
发明人： KATANO, Hiroaki 14-204 Machida Co-op Town , TANAKA, Tetsuya Aoba-ryo 5-1, Tsutsujigaoka , OHTA, Takayuki 24-14, Yabe 3-chome , SAWAI, Takeshi 11-14, Ohira 3-chome
CPC分类号： C08G77/02 , B22C1/22 , B22C1/2273 , C08G18/3895 , C08G77/50
摘要： This invention relates to a new modified silicate composition prepared by the reaction of an alkyl silicate or its oligomer with a specified active hydrogen compound in a specified ratio and to a method of producing a sand mold therefrom. More particularly the invention relates to an improvement in the production of a sand mold by using an organic binder and a hardener therefor, and a ceramic binder and a hardener therefor to produce economically a mold having an excellent strength without resort to complicated procedures.
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公开(公告)号：EP0516855A1
公开(公告)日：1992-12-09
申请号：EP91918925.8
申请日：1991-10-31
发明人： YAMAGUCHI, Shigeru Dow Mitsubishi Kasei Limited , KATANO, Hiroaki Dow Mitsubishi Kasei Limited , TANAKA, Tetsuya Dow Mitsubishi Kasei Limited
IPC分类号： C08G18/08 , C08G18/76 , C08G18/61 , C08G18/79 , C08L75/04 , C08G18/38 , C08G18/70 , C08G18/80
CPC分类号： C08G18/8054 , C08G18/70 , C08G18/7664
摘要： A polyisocyanate composition comprising at least one polyisocyanate compound selected from the group consisting of diphenylmethane diisocyanate oligomers containing 20 to 60 wt % of diphenylmethane diisocyanate and derivatives of said oligomers and, dissolved or dispersed therein, from 0.1 wt % to less than 10 wt % of a silicate compound. The composition is remarkably excellent in low-temperature storage stability.
摘要翻译： 一种多异氰酸酯组合物，其包含至少一种选自二苯基甲烷二异氰酸酯低聚物的二异氰酸酯化合物，所述二异氰酸酯化合物含有20至60重量％的二苯基甲烷二异氰酸酯和所述低聚物的衍生物，并且其溶解或分散在其中的为0.1重量％至小于10重量％ 硅酸盐化合物。 该组合物在低温储存稳定性方面非常优异。
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3.发明公开AMINATED SILICATE COMPOSITION AND DEHYDRATING AGENT CONTAINING THE SAME 失效AMINIERTE SILIKATZUSAMMENSTELLUNG UNDESE ENTHALTENDES TROCKNUNGSMITTEL。
公开(公告)号：EP0450093A1
公开(公告)日：1991-10-09
申请号：EP90915176.3
申请日：1990-10-19
CPC分类号： C08G77/54 , C07F7/025 , C07F7/045 , C08G18/0885 , C08G59/504 , C08G77/02 , C08L63/00 , C08L83/00
摘要： A reaction product of a tetraalkoxysilane or a silicate oligomer obtained by the partial hydrolysis and dehydrating polycondensation of the same with an amino alcohol having one or two hydroxyl groups. It is suitable for the dehydration of a moisture of about several hundreds of ppm, and especially suitable for use as a dehydrating agent for the raw materials employed for the preparation of a urethane resin and an epoxy resin, because it produces an amino alcohol by the dehydration.
摘要翻译： 以下要求保护：（1）硅酸盐组合物。 contg。 氨基gp obtd。 通过使四烷氧基硅烷（I）或硅酸酯低聚物反应物 通过部分水解（0-65，优选0-50，％水解度）和脱水缩聚物。 （I）与具有1或2个OH gps的氨基醇反应; （2）脱水剂，其包含（1）; （3）非发泡聚氨酯树脂。 通过使添加有（2）的多元醇与异氰酸酯反应; （4）环氧树脂用硬化剂，其包含（1）和（5）环氧树脂。 通过环氧树脂cpd反应。 contg。 至少一种环氧gp。 使用（4）。
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4.发明授权
公开(公告)号：EP0450093B1
公开(公告)日：1997-01-29
申请号：EP90915176.3
申请日：1990-10-19
CPC分类号： C08G77/54 , C07F7/025 , C07F7/045 , C08G18/0885 , C08G59/504 , C08G77/02 , C08L63/00 , C08L83/00
摘要： A reaction product of a tetraalkoxysilane or a silicate oligomer obtained by the partial hydrolysis and dehydrating polycondensation of the same with an amino alcohol having one or two hydroxyl groups. It is suitable for the dehydration of a moisture of about several hundreds of ppm, and especially suitable for use as a dehydrating agent for the raw materials employed for the preparation of a urethane resin and an epoxy resin, because it produces an amino alcohol by the dehydration.
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公开(公告)号：EP0561568A1
公开(公告)日：1993-09-22
申请号：EP93301893.9
申请日：1993-03-12
IPC分类号： C07C263/18 , C08G18/70
CPC分类号： C08G18/70 , C07C265/14
摘要： Storage stable high reactive polyisocyanate composition capable of withstanding a wide range of storage and handling conditions contain from 30 to 500 ppm of an organometallic based urethane catalyst and from 30 to 10,000 ppm of an acyl chloride compound based on the polyisocyanate compound. The composition can be utilized effectively in various spot applications such as spray foaming, painting for water-proofing, floor painting and paving, or the production of various polyurethane resins or foams.
摘要翻译： 能够承受宽范围的储存和处理条件的储存稳定的高反应性多异氰酸酯组合物含有30至500ppm的有机金属基氨基甲酸酯催化剂和30至10,000ppm基于多异氰酸酯化合物的酰氯化合物。 该组合物可以有效地用于各种现场应用，如喷雾发泡，防水涂漆，地板涂漆和铺路，或生产各种聚氨酯树脂或泡沫。
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公开(公告)号：EP0517527A3
公开(公告)日：1993-01-27
申请号：EP92305144.5
申请日：1992-06-04
CPC分类号： C08G18/708 , C08G18/7664
摘要： [Construction] A polyisocyanate composition comprising diphenylmethane diisocyanate oligomer and from 40 to 62 weight percent based on the total polyisocyanate of diphenylmethane diisocyanate or a derivative thereof, wherein the composition also comprises from 0.0001 to 4 parts by weight per 100 parts by weight of polyisocyanate of a denatured silicone oil which is inactive to the polyisocyanate. [Advantages] A polyisocyanate composition according to the present invention has excellent storage stability at low temperature and can be effectively used in the production field of polyurethane resins.
摘要翻译： 一种具有优异的低温储存稳定性的多异氰酸酯组合物，其特征在于包含特定二苯基甲烷二异氰酸酯低聚物或含有特定量的对多异氰酸酯无活性的变性硅油的衍生物。
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公开(公告)号：EP0517527A2
公开(公告)日：1992-12-09
申请号：EP92305144.5
申请日：1992-06-04
CPC分类号： C08G18/708 , C08G18/7664
摘要： [Construction]
A polyisocyanate composition comprising diphenylmethane diisocyanate oligomer and from 40 to 62 weight percent based on the total polyisocyanate of diphenylmethane diisocyanate or a derivative thereof, wherein the composition also comprises from 0.0001 to 4 parts by weight per 100 parts by weight of polyisocyanate of a denatured silicone oil which is inactive to the polyisocyanate.
[Advantages]
A polyisocyanate composition according to the present invention has excellent storage stability at low temperature and can be effectively used in the production field of polyurethane resins.摘要翻译： 一种具有优异的低温储存稳定性的多异氰酸酯组合物，其特征在于包含特定二苯基甲烷二异氰酸酯低聚物或含有特定量的对多异氰酸酯无活性的变性硅油的衍生物。
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8.发明公开MODIFIED SILICATE COMPOSITION AND PRODUCTION OF SAND MOLD THEREFROM 失效MODIFIZIERTE SILICATZUSAMMENSETZUNG UND VERFAHREN ZUR HERSTELLUNG EINER SANDGIESSFORM DARAUS。
公开(公告)号：EP0401388A1
公开(公告)日：1990-12-12
申请号：EP90901010.0
申请日：1989-12-19
发明人： KATANO, Hiroaki 14-204 Machida Co-op Town , TANAKA, Tetsuya Aoba-ryo 5-1, Tsutsujigaoka , OHTA, Takayuki 24-14, Yabe 3-chome , SAWAI, Takeshi 11-14, Ohira 3-chome
CPC分类号： C08G77/02 , B22C1/22 , B22C1/2273 , C08G18/3895 , C08G77/50
摘要： This invention relates to a new modified silicate composition prepared by the reaction of an alkyl silicate or its oligomer with a specified active hydrogen compound in a specified ratio and to a method of producing a sand mold therefrom. More particularly the invention relates to an improvement in the production of a sand mold by using an organic binder and a hardener therefor, and a ceramic binder and a hardener therefor to produce economically a mold having an excellent strength without resort to complicated procedures.
摘要翻译： 一种新的改性硅酸盐化合物。 是通过使硅酸盐低聚物（1）与活性氢cpd反应制备的。 （a）或（b）。 （1）是obtd。 通过水解脱水冷凝。 使用水解系统聚合四烷氧基硅烷。 为0-65％（优先10-60％，尤其是40-60％）。 （a）有一个摩尔。 重量。 在80和500之间，包含一个功能gp。 （b）具有摩尔。 重量。 500或更高，并且具有一个或两个功能性gps。反应以不同的比例进行。 的烷氧基gps。 到不。 当（a）为活性H cpd时，活性H为1-15。 和（b）为活性H cpd时为10-100。通过向模型砂中加入至少一种有机粘合剂，硬化剂和异氰酸酯组合物来生产砂模。 contg。 这种改性硅酸盐化合物。 包括多异氰酸酯和改性硅酸盐组合物。 （聚氰酸酯重量的1/9-9倍）。 主动H cpd 是聚醚或聚酯醇。 有机粘合剂是酚醛树脂，聚酯树脂，脲呋喃树脂，苯酚 - 呋喃树脂，苯酚 - 异氰酸酯树脂或聚酯 - 异氰酸酯树脂。
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公开(公告)号：EP0650501A1
公开(公告)日：1995-05-03
申请号：EP94916718.0
申请日：1994-05-10
IPC分类号： C08G18
CPC分类号： C08G18/632 , C08G18/10 , C08G18/4854 , C08G2101/0033 , C08G2101/0083 , C08G18/7664 , C08G18/63
摘要： This invention relates to molded polyurethane foams prepared by reacting a specific polyisocyanate with a specific polyol in the presence of water as a blowing agent and a catalyst, wherein (a) the polyisocyanate comprises a mixture of (i) a specified amount of polymethylene polyphenyl polyisocyanate and (ii) an NCO-terminated prepolymer prepared from the reaction of an organic polyisocyanate with a specified amount of poly(oxytetramethylene)glycol, or a specific NCO-terminated prepolymer prepared from the reaction of (i) an organic polyisocyanate, (ii) a specified amount of polymethylene polyphenyl polyisocyanate and (iii) a specified amount of poly(oxytetramethylene)glycol, (b) the polyol contains a specified amont of polymer polyol prepared from the reaction of a polyetherpolyol with an ethylenic unsaturated monomer, and (c) the catalyst contains an organotin compound. The molded polyurethane foams can be prepared under good demoldability and have excellent abrasion resistance, and therefore, can be useful for automotive steering wheels, headrests, armrests and the like.
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公开(公告)号：EP0567824A1
公开(公告)日：1993-11-03
申请号：EP93105882.0
申请日：1993-04-08
CPC分类号： C08G18/4854 , C08G18/10 , C08G2101/0083 , C08G18/7664 , C08G18/63
摘要： This invention relates to polyurethane foam moldings prepared by reacting a specific polyisocyanate with a polyol in the presence of water as the primary blowing agent, wherein the polyisocyanate comprises a specific polyisocyanate mixture of a NCO-terminated prepolymer prepared employing poly(oxytetramethylene)glycol ("PTMG") with polymethylene polyphenyl polyisocyanate ("Polymeric MDI"), or a specific NCO-terminated prepolymer prepared from the reaction of an organic polyisocyanate containing Polymeric MDI as an essential component with PTMG. The polyurethane foam moldings have excellent abrasion resistance and can be useful for automotive steering wheels, headrests, armrests and the like.
摘要翻译： 本发明涉及聚氨酯泡沫模塑制品，其通过使特定多异氰酸酯与多元醇在作为主发泡剂的水的存在下反应而制备，其中多异氰酸酯包含使用聚（氧四亚甲基）二醇（“四亚甲基”二醇）制备的NCO-封端的预聚物的特定多异氰酸酯混合物 PTMG“）与聚亚甲基聚苯基多异氰酸酯（”Polymeric MDI“）或由含有聚合物MDI作为基本组分的有机多异氰酸酯与PTMG反应制备的特定NCO封端的预聚物。 聚氨酯泡沫模制品具有优异的耐磨性，并且可用于汽车转向轮，头枕，扶手等。
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