公开(公告)号：EP0801027B1

公开(公告)日：1999-09-08

申请号：EP95941571.2

申请日：1995-12-25

申请人： CHINA PETRO-CHEMICAL CORPORATION ,  DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES ,  Fushun Petro-Chemical Company, Sinopec

发明人： WANG, Qingxia ,  ZHANG, Shurong ,  CAI, Guangyu ,  LI, Feng ,  XU, Longya ,  HUANG, Zuxian ,  LI, Yuying

IPC分类号： C01B39/36 ,  B01J29/40 ,  C07C2/66 ,  C07C2/00 ,  C07C1/20

CPC分类号： C01B39/365 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  Y10S423/22 ,  Y10S423/29

公开(公告)号：EP0801027A1

公开(公告)日：1997-10-15

申请号：EP95941571.2

申请日：1995-12-25

申请人： CHINA PETRO-CHEMICAL CORPORATION ,  DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES ,  Fushun Petro-chemical Company, Sinopec

发明人： WANG, Qingxia ,  ZHANG, Shurong ,  CAI, Guangyu ,  LI, Feng ,  XU, Longya ,  HUANG, Zuxian ,  LI, Yuying

IPC分类号： C01B39/36 ,  C01B39/04 ,  B01J29/04

CPC分类号： C01B39/365 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  Y10S423/22 ,  Y10S423/29

摘要： A rare earth-containing zeolite with a cocrystalline structure of ZSM-5 and ZSM-11, wherein the weight ratio of the moiety having the crystalline structure of ZSM-5 to the moiety having the crystalline structure of ZSM-11 is 0.1 to 10, which has, in the sodium form, the X-ray diffraction pattern set forth in Table 1, and in its originally synthesized anhydrous state, a chemical formula in terms of mole ratios of oxides as follows: 0.1-1.0 Na 2 O · 0.01-1.0 RE 2 O 3 · Al 2 O 3 · 20-300 SiO 2 . Said zeolite has good acid hydrothermal stability and resistance against impurity contamination, and is useful as catalyst in various hydrocarbon conversions.

摘要翻译： 一种具有ZSM-5和ZSM-11的共晶体结构的含稀土沸石，其中具有ZSM-5晶体结构的部分与具有ZSM-11晶体结构的部分的重量比为0.1至10， 其以钠形式具有表1所列的X射线衍射图，并且在其最初合成的无水状态下具有如下氧化物摩尔比的化学式：0.1-1.0 Na 2 O 0.01-1.0 RE 2 O 3 ·Al2O3·20-300SiO2。 所述沸石具有良好的酸水热稳定性和抗杂质污染性，并且可用作各种烃转化中的催化剂。

公开(公告)号：EP0801027A4

公开(公告)日：1997-09-29

申请号：EP95941571

申请日：1995-12-25

申请人： CHINA PETROCHEMICAL CORP ,  DALIAN CHEMICAL PHYSICS INST ,  FUSHUN PETRO CHEMICAL COMPANY

发明人： WANG QINGXIA ,  ZHANG SHURONG ,  CAI GUANGYU ,  LI FENG ,  XU LONGYA ,  HUANG ZUXIAN ,  LI YUYING

IPC分类号： B01J29/48 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  C07B37/00 ,  C07B37/02 ,  C07B61/00 ,  B01J29/04 ,  C01B39/04

CPC分类号： C01B39/365 ,  B01J29/40 ,  B01J29/70 ,  B01J29/80 ,  C01B39/36 ,  Y10S423/22 ,  Y10S423/29

摘要： This invention concerns a zeolite containing rare earth elements and possessing cocrystallization structure of ZSM-5 and ZSM-11, wherein, weight rate of crystal phase structure portion of ZSM-5 and ZSM-11 is from 0.1 to 10. Chemical composition of the prototype zeolite synthesized under anhydrous state is as follows: 0.1-1.0 Na2O, 0.01-1.0 RE2O3, Al2O3. 20-300 SiO2. X-ray diffraction spectral lines of the zeolite Na-type are shown in table 1. The zeolite possesses good acidic hydrothermal stability and anti-impurities contamination ability, and can be used as catalyst in varied hydrocarbon conversion processes.

摘要翻译： 本发明涉及含有稀土元素并具有ZSM-5和ZSM-11的共晶结构的沸石，其中ZSM-5和ZSM-11的晶相结构部分的重量比为0.1-10。原型的化学组成 在无水状态下合成的沸石如下：0.1-1.0Na 2 O，0.01-1.0 RE 2 O 3，Al 2 O 3。 20-300SiO2。 Na型沸石的X射线衍射谱线示于表1中。该沸石具有良好的酸性水热稳定性和抗杂质污染能力，并且可用作各种烃转化过程中的催化剂。

公开(公告)号：EP0913196A4

公开(公告)日：2000-03-22

申请号：EP97930290

申请日：1997-06-24

申请人： CHINA PETROCHEMICAL CORP ,  DALIAN CHEMICAL PHYSICS INST ,  FUSHUN PETRO CHEMICAL COMPANY

发明人： WANG QINGXIA ,  ZHANG SHURONG ,  CAI GUANGYU ,  LI FENG ,  XU LONGYA ,  HUANG ZUXIAN ,  LI YUYING

IPC分类号： B01J29/40 ,  C07B61/00 ,  C07C2/66 ,  C07C15/073

CPC分类号： B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2/66 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52

摘要： An alkylation catalyst comprises from 50 to 70 wt.% of hydrogen type ZSM-5/ZSM-11 co-crystalline zeolite containing rare earth element and the rest amount of porous inorganic oxide matrix material. The zoelite has particular chemical composition and X-ray diffraction line. This catalyst has higher activity, selectivity and stability in alkylation process than that of the prior art. With this catalyst the process for preparing ethyl benzene by alkylation of benzene with ethylene has higher ethylene conversion and ethyl benzene selectivity.

公开(公告)号：EP0913196A1

公开(公告)日：1999-05-06

申请号：EP97930290.8

申请日：1997-06-24

申请人： CHINA PETROCHEMICAL CORPORATION ,  DALIAN INSTITUTE OF CHEMICAL PHYSICS, CHINESE ACADEMY OF SCIENCES ,  Fushun Petro-Chemical Company, Sinopec

发明人： WANG, Qingxia ,  ZHANG, Shurong ,  CAI, Guangyu ,  LI, Feng ,  XU, Longya ,  HUANG, Zuxian ,  LI, Yuying

IPC分类号： B01J29/40 ,  C07C15/073

CPC分类号： B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  C07C2/66 ,  C07C2529/40 ,  C07C2529/70 ,  Y02P20/52

摘要： An alkylation catalyst comprises from 50 to 70 wt% of hydrogen type ZSM-5/ZSM-11 co-crystalline zeolite containing rare earth element and the rest amount of porous inorganic oxide matrix material. The zeolite has particular chemical composition and X-ray diffraction lines. This catalyst has higher activity, selectivity and stability in alkylation process than that of the prior art. With this catalyst the process for preparing ethyl benzene by alkylation of benzene with ethylene has higher ethylene conversion and ethyl benzene selectivity.

摘要翻译： 烷基化催化剂含有50〜70重量％的含有稀土元素的氢型ZSM-5 / ZSM-11共晶沸石和剩余量的多孔无机氧化物基质材料。 沸石具有特定的化学成分和X射线衍射线。 该催化剂在烷基化方法中具有比现有技术更高的活性，选择性和稳定性。 使用该催化剂，通过用乙烯烷基化苯制备乙苯的方法具有较高的乙烯转化率和乙苯选择性。