摘要:
Optical resolution of (±)-phenyl glycin and/or (±)-camphor sulfonic acid by way of diastereomeric salts thereof can be carried out efficiently by using mixtures of optically active forms and racemic forms of phenyl glycin and camphor sulfonic acid as mutual resolution agents in a liquid medium so as to form and crystalize the two kinds of the diastereomeric salts alternately.
摘要:
Disclosed is a method of optical resolution of DL-cysteine by forming diastereoisomers with optically active mandelic acid, followed by preferential crystallisation. The method facilitates commercial production of optically active cysteine, particularly L-cysteine which is in great demand.
摘要:
A liquid crystal composition, comprising a main chain-type mesomorphic polymer and a mesomorphic monomer and showing a smectic phase including a plurality of molecular layers, wherein a linkage of a covalent bond is present between adjacent molecular layers among the plurality molecular layers. Because of the presence of the covalent bond linkage between the molecular layers, the elastic energy of the liquid crystal per se relating to the elastic energy between the smectic liquid crystal molecular layers can be controlled to provide a uniform alignment. The mesomorphic polymer preferably has a structure represented by the following formula (1 ): wherein A denotes a terminal flexible chain group, M denotes a mesogen group, F denotes a spacer flexible chain group, x is 0 or 1, B denotes an ester bond group, ether bond group, thioester bond group, dimethylsiloxane bond group or thioether bond group, and y is 1 - 200.
摘要:
A liquid crystal composition, comprising a main chain-type mesomorphic polymer and a mesomorphic monomer and showing a smectic phase including a plurality of molecular layers, wherein a linkage of a covalent bond is present between adjacent molecular layers among the plurality molecular layers. Because of the presence of the covalent bond linkage between the molecular layers, the elastic energy of the liquid crystal per se relating to the elastic energy between the smectic liquid crystal molecular layers can be controlled to provide a uniform alignment. The mesomorphic polymer preferably has a structure represented by the following formula (1 ): wherein A denotes a terminal flexible chain group, M denotes a mesogen group, F denotes a spacer flexible chain group, x is 0 or 1, B denotes an ester bond group, ether bond group, thioester bond group, dimethylsiloxane bond group or thioether bond group, and y is 1 - 200.
摘要:
(±)-2-Amino-1-butanoi and/or (±)-mandelic acid are optically resolved with a high resolution efficiency and high optical purities by preferentially crystallizing out one of the pair of less soluble enantiomeric salts (or optical antipodes), namely (+)-2-amino-1-butanol- (+)-mandelic acid salt and (-)-2-amino-1-butanol- (-)-mandelic acid salt.
摘要:
A liquid crystal composition, comprising a main chain-type mesomorphic polymer and a mesomorphic monomer and showing a smectic phase including a plurality of molecular layers, wherein a linkage of a covalent bond is present between adjacent molecular layers among the plurality molecular layers. Because of the presence of the covalent bond linkage between the molecular layers, the elastic energy of the liquid crystal per se relating to the elastic energy between the smectic liquid crystal molecular layers can be controlled to provide a uniform alignment. The mesomorphic polymer preferably has a structure represented by the following formula (1):
wherein A denotes a terminal flexible chain group, M denotes a mesogen group, F denotes a spacer flexible chain group, x is 0 or 1, B denotes an ester bond group, ether bond group, thioester bond group, dimethylsiloxane bond group or thioether bond group, and y is 1 - 200.