公开(公告)号：EP2852566A4

公开(公告)日：2016-02-10

申请号：EP13794067

申请日：2013-05-23

申请人： REACTION 35 LLC

发明人： JULKA VIVEK ,  GADEWAR SAGAR ,  STOIMENOV PETER K ,  GROSSO PHILIP ,  SHERMAN JEFFREY H ,  ZHANG AIHUA ,  MCFARLAND ERIC W

IPC分类号： C07C1/30 ,  C07C17/10 ,  C07C17/23

CPC分类号： C07C1/30 ,  C01B7/096 ,  C07C17/10 ,  C07C17/23 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/44 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/10 ,  C07C11/107 ,  C07C19/075

公开(公告)号：EP3154921B1

公开(公告)日：2020-02-26

申请号：EP15806024.4

申请日：2015-06-09

申请人： Reaction 35, LLC

发明人： STOIMENOV, Peter K. ,  SHERMAN, Jeffrey H.

IPC分类号： C07C1/30 ,  C07C5/25 ,  C07C5/23 ,  C07C11/167 ,  C07C19/075 ,  C07C17/10

公开(公告)号：EP3194351A4

公开(公告)日：2018-03-28

申请号：EP15841725

申请日：2015-09-15

申请人： REACTION 35 LLC

发明人： STOIMENOV PETER K ,  SHERMAN JEFFREY H

IPC分类号： C07C5/00 ,  C07C5/42

CPC分类号： C07C17/23 ,  C07C1/30 ,  C07C5/2789 ,  C07C5/44 ,  C07C11/02 ,  C07C17/10 ,  C07C2527/08 ,  C07C2527/125 ,  C07C9/18 ,  C07C9/12 ,  C07C11/09 ,  C07C11/10 ,  C07C19/075

摘要： A method includes brominating a butanes feed stream including i-butane in a bromination reactor to form a bromination effluent stream including t-butyl bromide. The method includes dehydrobrominating the t-butyl bromide to form isobutylene. Another method includes brominating a mixed pentanes feed stream including i-pentane and n-pentane in a bromination reactor to form a bromination effluent stream including t-pentyl bromide. The method includes dehydrobrominating the t-pentyl bromide to form isoamylene and HBr.

公开(公告)号：EP3936472A3

公开(公告)日：2022-04-06

申请号：EP21184174.7

申请日：2021-07-07

申请人： Reaction 35, LLC

发明人： WAYCUILIS, John

IPC分类号： C01B7/09

摘要： A hydrogen bromide (HBr) oxidation/quench system includes a heat exchanger reactor and an adiabatic catalytic reactor in fluid communication with the heat exchanger reactor. The system also includes a quench vessel, the quench vessel in fluid communication with the adiabatic catalytic reactor. The quench vessel has a flange. In addition, the system includes a joined three phase separator and absorber column, wherein both the three phase separator and the absorber column are in fluid communication with the quench vessel and an aqueous stripping column in fluid communication the heat exchanger reactor and the absorber column.

公开(公告)号：EP3154921A4

公开(公告)日：2018-01-03

申请号：EP15806024

申请日：2015-06-09

申请人： REACTION 35 LLC

发明人： STOIMENOV PETER K ,  SHERMAN JEFFREY H

IPC分类号： C07C1/30 ,  C07C5/23 ,  C07C5/25 ,  C07C11/167 ,  C07C17/10 ,  C07C19/075

CPC分类号： C07C1/30 ,  C07C5/23 ,  C07C5/2512 ,  C07C5/2518 ,  C07C17/10 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2527/22 ,  C07C2527/224 ,  C07C2529/035 ,  C07C2529/04 ,  C07C11/167 ,  C07C19/075

摘要： Olefins and diolefins, such as 1,3-butiadiene, may be produced by a method utilizing a series of bromination and dehydrobromination reactions. Bromine may be reacted with n-butane to form dibromobutane. The dibromobutanes may be dehydrobrominating to form 1,3-butadiene. The method may include reacting butene with bromine to form bromobutenes, and dehydrobrominating the bromobutenes to form 1,3-butadiene. The method may include reacting butene with hydrogen bromide in the presence of oxygen to form bromobutenes, and dehydrobrominating the bromobutenes to form 1,3-butadiene. The method may include reacting butene with bromine to form dibromobutanes, and dehydrobrominating the dibromobutanes to form 1,3-butadiene.

公开(公告)号：EP3154921A1

公开(公告)日：2017-04-19

申请号：EP15806024.4

申请日：2015-06-09

申请人： Reaction 35, LLC

发明人： STOIMENOV, Peter K. ,  SHERMAN, Jeffrey H.

IPC分类号： C07C1/32

CPC分类号： C07C1/30 ,  C07C5/23 ,  C07C5/2512 ,  C07C5/2518 ,  C07C17/10 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2527/22 ,  C07C2527/224 ,  C07C2529/035 ,  C07C2529/04 ,  C07C11/167 ,  C07C19/075

摘要： Olefins and diolefins, such as 1,3-butiadiene, may be produced by a method utilizing a series of bromination and dehydrobromination reactions. Bromine may be reacted with n-butane to form dibromobutane. The dibromobutanes may be dehydrobrominating to form 1,3-butadiene. The method may include reacting butene with bromine to form bromobutenes, and dehydrobrominating the bromobutenes to form 1,3-butadiene. The method may include reacting butene with hydrogen bromide in the presence of oxygen to form bromobutenes, and dehydrobrominating the bromobutenes to form 1,3-butadiene. The method may include reacting butene with bromine to form dibromobutanes, and dehydrobrominating the dibromobutanes to form 1,3-butadiene.

摘要翻译： 烯烃和二烯烃如1,3-丁二烯可以通过使用一系列溴化和脱氢溴化反应的方法来制备。 溴可以与正丁烷反应形成二溴丁烷。 二溴丁烷可以是脱氢溴化以形成1,3-丁二烯。 该方法可以包括使丁烯与溴反应形成溴丁烯，并将溴代丁烷脱溴形成1,3-丁二烯。 该方法可以包括在氧气存在下使丁烯与溴化氢反应形成溴代丁烷，并将溴代丁烷脱溴形成1,3-丁二烯。 该方法可以包括使丁烯与溴反应以形成二溴丁烷，并将二溴丁烷脱氢形成1,3-丁二烯。

公开(公告)号：EP2852566A2

公开(公告)日：2015-04-01

申请号：EP13794067.2

申请日：2013-05-23

申请人： Reaction 35, LLC

发明人： JULKA, Vivek ,  GADEWAR, Sagar ,  STOIMENOV, Peter, K. ,  GROSSO, Philip ,  SHERMAN, Jeffrey, H. ,  ZHANG, Aihua ,  MCFARLAND, Eric, W.

IPC分类号： C07C5/44

CPC分类号： C07C1/30 ,  C01B7/096 ,  C07C17/10 ,  C07C17/23 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/44 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  C07C11/09 ,  C07C11/10 ,  C07C11/107 ,  C07C19/075

摘要： A process is disclosed that includes brominating a C
2 , C
3 , C
4 , C
5 or C
6 alkane with elemental bromine to form a bromo-alkane. The bromo-alkane is reacted to form a C
2 , C
3 , C
4 , C
5 or C
6 alkene and HBr. The HBr is oxidized to form elemental bromine.

公开(公告)号：EP3126046A4

公开(公告)日：2018-01-17

申请号：EP15772595

申请日：2015-03-27

申请人： REACTION 35 LLC

发明人： STOIMENOV PETER K

IPC分类号： B01J29/00 ,  B01J29/40 ,  C01B39/36

CPC分类号： B01J29/48 ,  B01J29/40 ,  B01J2229/16 ,  B01J2229/186 ,  B01J2229/32 ,  B01J2229/34 ,  B01J2229/36 ,  B01J2229/37 ,  C01B39/38

摘要： A method of manufacturing a modified zeolite catalyst may include reacting a zeolite with a metal salt to form a zeolite/metal salt complex. The zeolite may be a ZSM-5 or ZSM-11. The method may include heating the zeolite/metal salt complex to form an intermediate modified zeolite, and reacting the intermediate modified zeolite with an acid. The method may include ion exchanging the intermediate modified zeolite following the reaction with the acid to form a modified zeolite catalyst.

公开(公告)号：EP3194351A1

公开(公告)日：2017-07-26

申请号：EP15841725.3

申请日：2015-09-15

申请人： Reaction 35, LLC

发明人： STOIMENOV, Peter K. ,  SHERMAN, Jeffrey H.

IPC分类号： C07C5/00 ,  C07C5/42

CPC分类号： C07C17/23 ,  C07C1/30 ,  C07C5/2789 ,  C07C5/44 ,  C07C11/02 ,  C07C17/10 ,  C07C2527/08 ,  C07C2527/125 ,  C07C9/18 ,  C07C9/12 ,  C07C11/09 ,  C07C11/10 ,  C07C19/075

摘要： A method includes brominating a butanes feed stream including i-butane in a bromination reactor to form a bromination effluent stream including t-butyl bromide. The method includes dehydrobrominating the t-butyl bromide to form isobutylene. Another method includes brominating a mixed pentanes feed stream including i-pentane and n-pentane in a bromination reactor to form a bromination effluent stream including t-pentyl bromide. The method includes dehydrobrominating the t-pentyl bromide to form isoamylene and HBr.

摘要翻译： 一种方法包括在溴化反应器中溴化包含异丁烷的丁烷进料流以形成包含叔丁基溴的溴化流出物流。 该方法包括使叔丁基溴脱溴化氢以形成异丁烯。 另一种方法包括在溴化反应器中溴化包括异戊烷和正戊烷的混合戊烷进料流以形成包含叔戊基溴的溴化流出物流。 该方法包括使叔戊基溴脱溴化氢以形成异戊烯和HBr。

公开(公告)号：EP3936472A2

公开(公告)日：2022-01-12

申请号：EP21184174.7

申请日：2021-07-07

申请人： Reaction 35, LLC

发明人： WAYCUILIS, John

IPC分类号： C01B7/09

摘要： A hydrogen bromide (HBr) oxidation/quench system includes a heat exchanger reactor and an adiabatic catalytic reactor in fluid communication with the heat exchanger reactor. The system also includes a quench vessel, the quench vessel in fluid communication with the adiabatic catalytic reactor. The quench vessel has a flange. In addition, the system includes a joined three phase separator and absorber column, wherein both the three phase separator and the absorber column are in fluid communication with the quench vessel and an aqueous stripping column in fluid communication the heat exchanger reactor and the absorber column.