公开(公告)号：EP1440961B1

公开(公告)日：2009-07-15

申请号：EP02778017.0

申请日：2002-10-30

申请人： ASAHI GLASS COMPANY LTD.

发明人： KASHIWAGI, Kimiaki, Asahi Glass Company, Limited ,  OGAWA, Gen, Asahi Glass Company, Limited ,  OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  MUROTANI, Eisuke, Asahi Glass Company, Limited ,  OHARU, Kazuya, Asahi Glass Company, Limited

IPC分类号： C07C43/17 ,  C07C41/24 ,  C08L29/10 ,  C08F216/12 ,  G02B6/00

CPC分类号： G02B6/02038 ,  C07C43/17 ,  C08F16/32 ,  C08F214/18 ,  G02B1/046 ,  G02B6/02033 ,  C08L29/10

摘要： The invention provides novel fluoropolymers capable of forming optical elements having low refractive indexes and excellent heat resistance; novel fluorine-containing diene compounds having two unsaturated bonds capable of giving the above fluoropolymers; and light transmitters and plastic optical fibers made by using the fluoropolymers, which exhibit high performance by virtue of the low refractive indexes and excellent heat resistance, specifically, fluorine-containing diene compounds represented by the general formula: CF2=CFCF(ORf)CF2OCF=CF2 [wherein Rf is perfluoroalkyl such as trifluoromethyl]; fluoropolymers of the diene compounds; light transmitters made by using the fluoropolymers; and plastic optical fibers wherein the core is made of a composition comprising a fluoropolymer described above and a low-molecular fluorine compound serving to enhance the refractive index.

公开(公告)号：EP1323704A1

公开(公告)日：2003-07-02

申请号：EP01967793.9

申请日：2001-09-21

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Ltd ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  SHIRAKAWA, Daisuke, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited

IPC分类号： C07C67/293 ,  C07C45/41 ,  C07C49/167 ,  C07C51/58 ,  C07C53/46 ,  C07C69/63

CPC分类号： C07C67/14 ,  C07C45/54 ,  C07C51/60 ,  C07C67/287 ,  C07C67/29 ,  C07C67/297 ,  C07C67/307 ,  C07C59/21 ,  C07C53/46 ,  C07C69/63

摘要： A fluorinated polyvalent carbonyl compound is produced by an economically advantageous method from inexpensive materials without requiring a complicated synthetic process step. Namely, the present invention comprises reacting a polyvalent alcohol having at least two kinds of alcohol skeletons selected among a primary alcohol, a secondary alcohol and a tertiary alcohol, with an acid halide to obtain a polyvalent ester compound, fluorinating it in a liquid phase to obtain a perfluorinated polyvalent ester compound, and cleaving the ester bonds derived from primary and secondary alcohols in the perfluoropolyvalent ester compound to obtain a fluorinated polyvalent carbonyl compound.

摘要翻译： 通过经济上有利的方法从便宜的材料制备氟化多价羰基化合物，而不需要复杂的合成工艺步骤。 即，本发明包括使具有选自伯醇，仲醇和叔醇中的至少两种醇骨架的多元醇与酰卤反应，得到多价酯化合物，将其氟化成液相， 得到全氟代多价酯化合物，并在全氟多价酯化合物中裂解衍生自伯醇和仲醇的酯键，得到含氟多价羰基化合物。

公开(公告)号：EP1288183A1

公开(公告)日：2003-03-05

申请号：EP01908356.7

申请日：2001-03-06

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited ,  SATO, Masakuni, Asahi Glass Company, Limited ,  MUROFUSHI, Hidenobu, Asahi Glass Company, Limited ,  YANASE, Koichi, Asahi Glass Company, Limited ,  SUZUKI, Yasuhiro, Asahi Glass Company, Limited

IPC分类号： C07C41/01 ,  C07C43/17 ,  C07C27/00 ,  C07C51/58

CPC分类号： C07C43/17 ,  C07C41/18 ,  C07C41/28 ,  C07C43/172 ,  C07C2601/14

摘要： The present invention produces an unsaturated compound (Formula 2) useful as a fluororesin starting material and the like by using a compound of the Formula 1 as a starting material.
That is, the present invention provides a method for preparing a compound expressed by CR b R c =CR d R e (Formula 2) such as CF 3 CF 2 CF 2 OCF=CF 2 by pyrolyzing a compound having at least one partial structure expressed by -COOCF 2 CR b R c -CXR d R e (Formula 1) such as
CF 3 CF 2 CF 2 OCF(CF 3 )COOCF 2 CF(CF 3 )OCF 2 CF 2 CF 3 , wherein R b to R e are a hydrogen atom, a halogen atom or a monovalent organic group unchangeable by pyrolysis reaction.

公开(公告)号：EP1440961A1

公开(公告)日：2004-07-28

申请号：EP02778017.0

申请日：2002-10-30

申请人： ASAHI GLASS COMPANY LTD.

发明人： KASHIWAGI, Kimiaki, Asahi Glass Company, Limited ,  OGAWA, Gen, Asahi Glass Company, Limited ,  OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  MUROTANI, Eisuke, Asahi Glass Company, Limited ,  OHARU, Kazuya, Asahi Glass Company, Limited

IPC分类号： C07C43/17 ,  C07C41/24 ,  C08L29/10 ,  C08F216/12 ,  G02B6/00

CPC分类号： G02B6/02038 ,  C07C43/17 ,  C08F16/32 ,  C08F214/18 ,  G02B1/046 ,  G02B6/02033 ,  C08L29/10

摘要： A novel fluoropolymer which can be an optical resin material having a low refractive index and excellent heat resistance, and a novel fluorinated diene compound having two unsaturated bonds, capable of presenting such a fluoropolymer, are presented. Further, by virtue of the low refractive index and excellent heat resistance, the polymer presents a high performance optical transmitter and a plastic optical fiber.
A fluorinated diene compound represented by CF 2 =CFCF(OR f )CF 2 OCF=CF 2 (wherein R f is a perfluoroalkyl group such as a trifluoromethyl group), and a fluoropolymer thereof. Further, an optical transmitter made by using such a fluoropolymer, and a plastic optical fiber having a core comprising such a fluoropolymer and a fluorinated low molecular compound contained therein as a refractive index-increasing agent.

摘要翻译： 本发明提供一种可以作为具有低折射率和优异的耐热性的光学树脂材料的新的含氟聚合物，以及具有两个不饱和键的氟化二烯化合物，能够呈现这种含氟聚合物。 此外，由于低折射率和优异的耐热性，聚合物呈现高性能的光发射机和塑料光纤。 由CF 2 = CFCF（OR f）CF 2 OCF = CF 2（其中R f是全氟烷基如三氟甲基）表示的氟化二烯化合物及其含氟聚合物。 此外，使用这种含氟聚合物制成的光发送器，以及包含其中包含这样的含氟聚合物和含有氟化低分子化合物的芯的塑料光纤作为折射率增加剂。

公开(公告)号：EP1352892A1

公开(公告)日：2003-10-15

申请号：EP02715755.1

申请日：2002-01-16

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited ,  MUROFUSHI, Hidenobu, Asahi Glass Company, Limited ,  SATO, Masakuni, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  YANASE, Koichi, Asahi Glass Company, Limited ,  SUZUKI, Yasuhiro, Asahi Glass Company, Limited

IPC分类号： C07C67/03 ,  C07C67/287 ,  C07C67/14 ,  C07C69/708 ,  C07C41/18 ,  C07C43/17

CPC分类号： C07C67/287 ,  C07C41/24 ,  C07C51/60 ,  C07C67/03 ,  C07C67/14 ,  C07C59/135 ,  C07C69/708 ,  C07C69/63 ,  C07C43/17

摘要： A process for producing a fluorinated ester through a small number of steps, is presented. The process for producing a fluorinated ester, comprises a transesterification step in which R AF -COOCF 2 -R AF and R A -CH 2 OH are subjected to a transesterification reaction to obtain R AF -COOCH 2 -R A , and a fluorination step in which the obtained compound is fluorinated to obtain a reaction product containing R AF -COOCF 2 -R AF . Here, in the formulae, R A is a monovalent organic group, and R AF is the same group as R A or a monovalent organic group obtained by fluorination of R A .

公开(公告)号：EP1306362A1

公开(公告)日：2003-05-02

申请号：EP01954358.6

申请日：2001-07-26

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  SHIRAKAWA, Daisuke, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited

IPC分类号： C07C51/58 ,  C07C59/135 ,  C07C41/24 ,  C07C43/303 ,  C07C45/43 ,  C07C47/14 ,  C07D317/42 ,  C08F16/24 ,  C08F24/00

CPC分类号： C08F24/00 ,  C07C41/48 ,  C07C51/58 ,  C07D317/42 ,  C08F16/24 ,  C07C59/135 ,  C07C43/313

摘要： The present invention provides novel processes for preparing a fluorinated acyl fluoride and a fluorinated vinyl ether.
Namely, it provides a process for preparing a fluorinated acyl fluoride (3), which comprises reacting a compound (1) having a fluorine content of 30 mass% or above with fluorine in a liquid phase to form a compound (2) and then dissociating the ester bond in the compound (2), and a process for preparing a fluorinated vinyl ether (10), which comprises pyrolyzing the fluorinated acyl fluoride:



wherein R A and R B are alkyl groups or the like, or the combination R A and R B is an ethereal oxygen-containing alkylene group or the like, R C and R D are perfluoro(ethereal oxygen-containing alkyl) groups or the like, or the combination of R C and R D is a perfluoro(ethereal oxygen-containing alkylene) group or the like, X 1 , X 2 , X 3 , X 4 , X 5 and X 6 are hydrogen atoms, fluorine atoms or the like, R AF , R BF , R CF and R DF are groups derived respectively from R A , R B , R C and R D by replacing substantially all of the hydrogen atoms by fluorine atoms.

摘要翻译： 本发明提供了制备氟化氟化物和氟化乙烯基醚的新方法。 即，提供一种制备氟化氟化物（3）的方法，其包括使氟含量为30质量％以上的化合物（1）与氟在液相中反应以形成化合物（2），然后解离 化合物（2）中的酯键和制备氟化乙烯基醚（10）的方法，其包括热解氟化酰基氟化物：其中R A和R B是烷基等，或R A和R B的组合是含醚的亚烷基等，R C和R D均为全氟（醚类含氧的 烷基）基团等，或者R C和R D的组合是全氟（醚性含氧亚烷基）基团等，X 1，X 2，X 3， X 4，X 5和X 6为氢原子，氟原子等，R AF，R“，R”CF“和”R“ 通过用氟化物代替基本上所有的氢原子，可以是A，R B，R C和R D e原子。

公开(公告)号：EP1323704B1

公开(公告)日：2011-08-17

申请号：EP01967793.9

申请日：2001-09-21

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Ltd ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  SHIRAKAWA, Daisuke, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited

IPC分类号： C07C67/293 ,  C07C45/41 ,  C07C49/167 ,  C07C51/58 ,  C07C53/46 ,  C07C69/63 ,  C07C51/60 ,  C07C67/14 ,  C07C67/287 ,  C07C67/29 ,  C07C67/297 ,  C07C67/307

CPC分类号： C07C67/14 ,  C07C45/54 ,  C07C51/60 ,  C07C67/287 ,  C07C67/29 ,  C07C67/297 ,  C07C67/307 ,  C07C59/21 ,  C07C53/46 ,  C07C69/63

摘要： An economically advantageous process for producing a fluorinated polyvalent carbonyl compound from inexpensive materials without the need of a complicated synthesis step. The process comprises reacting a polyhydric alcohol having at least two kinds of alcohol skeletons selected among a primary alcohol, secondary alcohol, and tertiary alcohol with an acid halide to obtain a polyvalent ester compound, fluorinating it in a liquid phase to obtain a perfluorinated polyvalent ester compound, and cleaving the perfluorinated polyvalent ester compound at the ester bonds derived from primary and secondary alcohols to obtain a fluorinated polyvalent carbonyl compound.

公开(公告)号：EP1352892B1

公开(公告)日：2010-06-09

申请号：EP02715755.1

申请日：2002-01-16

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited ,  MUROFUSHI, Hidenobu, Asahi Glass Company, Limited ,  SATO, Masakuni, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  YANASE, Koichi, Asahi Glass Company, Limited ,  SUZUKI, Yasuhiro, Asahi Glass Company, Limited

IPC分类号： C07C67/03 ,  C07C67/287 ,  C07C67/14 ,  C07C69/708 ,  C07C59/135 ,  C07C43/17 ,  C07C69/63 ,  C07C41/24 ,  C07C51/60

CPC分类号： C07C67/287 ,  C07C41/24 ,  C07C51/60 ,  C07C67/03 ,  C07C67/14 ,  C07C59/135 ,  C07C69/708 ,  C07C69/63 ,  C07C43/17

摘要： A process for producing a fluorinated ester through a small number of steps. The process is characterized by comprising: a transesterification step in which RAF-COOCF¿2?-R?AF and RA-CH¿2OH are subjected to transesterification to thereby obtain RAF-COOCH¿2-R?A; and a fluorination step in which the compound obtained is fluorinated in a liquid phase to obtain a reaction product containing RAF-COOCF¿2-R?AF. In the formulae, RA is a monovalent organic group and RAF is the same group as RA or is a monovalent organic group obtained through fluorination of RA.

公开(公告)号：EP1306362B1

公开(公告)日：2008-11-05

申请号：EP01954358.6

申请日：2001-07-26

申请人： ASAHI GLASS COMPANY LTD.

发明人： OKAZOE, Takashi, Asahi Glass Company, Limited ,  WATANABE, Kunio, Asahi Glass Company, Limited ,  ITO, Masahiro, Asahi Glass Company, Limited ,  SHIRAKAWA, Daisuke, Asahi Glass Company, Limited ,  TATEMATSU, Shin, Asahi Glass Company, Limited

IPC分类号： C07C51/58 ,  C07C59/135 ,  C07C41/24 ,  C07C43/303 ,  C07C45/43 ,  C07C47/14 ,  C07D317/42 ,  C08F16/24 ,  C08F24/00 ,  C07C41/48 ,  C07C43/313

CPC分类号： C08F24/00 ,  C07C41/48 ,  C07C51/58 ,  C07D317/42 ,  C08F16/24 ,  C07C59/135 ,  C07C43/313

摘要： The invention provides novel processes for the preparation of fluorinated acyl fluorides and fluorinated vinyl ethers, i.e., a process for the preparation of fluorinated acyl fluorides (3) which comprises reacting a compound (1) having a fluorine content of 30 % by mass or above with fluorine in a liquid phase to thereby obtain a compound (2) and subjecting the compound (2) to ester linkage cleavage, and a process for the preparation of fluorinated vinyl ethers (10) which comprises subjecting a fluorinated acyl fluoride (3) to pyrolysis. In the formulae, R?A and RB¿ are each alkyl or the like, or alternatively R?A and RB¿ may be united to form alkylene containing one or more etheric oxygen atoms, or the like; R?C and RD¿ are each perfluoroalkyl containing one or more etheric oxygen atoms, or the like, or alternatively R?C and RD¿ may be united to form perfluoroalkylene containing one or more etheric oxygen atoms, or the like; X1 to X6 are each hydrogen, fluoro, or the like; and R?AF, RBF, RCF and RDF¿ are groups derived respectively from R?A, RB, RC and RD¿ by replacing substantially all of the hydrogen atoms by fluorine atoms, or the like.