X-Ray imaging photostimulable phosphor screen or panel.
    1.
    发明公开
    X-Ray imaging photostimulable phosphor screen or panel. 审中-公开
    Röntgenbildschirmoder -tafel mit photostimulierbarem Leuchtstoff

    公开(公告)号:EP2067841A1

    公开(公告)日:2009-06-10

    申请号:EP07122464.6

    申请日:2007-12-06

    IPC分类号: C09K11/77 G21K4/00

    CPC分类号: G21K4/00 C09K11/7733

    摘要: In a method of preparing a phosphor or scintillator layer to become deposited on a support, a vapour depositing step is applied from a crucible unit by heating as phosphor precursor raw materials present in said crucible, a Cs(X,X') matrix compound and an activator or dopant precursor compound, wherein said crucible unit comprises at least a bottom and surrounding side walls as a container for phosphor precursor raw materials present in said crucible in liquefied form after heating said crucible, and wherein said Cs(X,X') matrix compound has a higher vapour pressure than said activator or dopant precursor compound, said method comprising a step of providing said activator or dopant compound in form of a precursor raw material represented by the formula Cs x Eu y X' (x+αy) , wherein x, y and α are integers, wherein x/y is more than 0.25 and wherein α is at least 2, wherein X represents Br and wherein X' stands for F, Cl, Br, I or a combination thereof; followed by an annealing step after a vapour depositing step, provided that said annealing step proceeds in an ambient atmosphere after cooling said phosphor or scintillator layer, deposited on said support; and wherein as a result a binderless needle-shaped Cs(X,X'):Eu phosphor or scintillator layer becomes provided, having on top of its needle-shaped phosphors, aligned in parallel, an average ratio of divalent to trivalent europium dopant of more than 1:1; wherein said average ratio decreases to an extent of less than 2% per hour, while being exposed to X-rays having an energy in the range from 1 to 100 keV.

    摘要翻译: 在制备荧光体或闪烁体层以沉积在载体上的方法中,通过作为荧光体前体原料加热坩埚,使用Cs(X,X')基质化合物和 活化剂或掺杂剂前体化合物,其中所述坩埚单元至少包括作为用于在加热所述坩埚之后以液化形式存在于所述坩埚中的荧光体前体原料的容器的底部和周围侧壁,并且其中所述Cs(X,X') 基质化合物具有比所述活化剂或掺杂剂前体化合物更高的蒸气压,所述方法包括以由式Cs x Eu y X'(x +±y)表示的前体原料的形式提供所述活化剂或掺杂剂化合物的步骤, 其中x,y和±是整数,其中x / y大于0.25,其中±至少为2,其中X表示Br,其中X'代表F,Cl,Br,I或它们的组合; 然后在气相沉积步骤之后进行退火步骤,条件是所述退火步骤在冷却沉积在所述载体上的所述荧光体或闪烁体层之后在环境气氛中进行; 并且其中结果是提供无粘合剂的针状Cs(X,X'):Eu荧光体或闪烁体层,其在其针状荧光体的顶部平行排列,二价至三价铕掺杂剂的平均比例 超过1:1; 其中所述平均比例降低到小于2%/小时的程度,同时暴露于能量在1至100keV范围内的X射线。

    Method of stabilising storage phosphor panels.
    2.
    发明公开
    Method of stabilising storage phosphor panels. 审中-公开
    稳定存储荧光屏的方法

    公开(公告)号:EP1793388A3

    公开(公告)日:2008-10-08

    申请号:EP06124429.9

    申请日:2006-11-21

    IPC分类号: G21K4/00 C09K11/61

    摘要: In a method of increasing humidity stability of a storage phosphor panel having a phosphor layer coated onto a support by vapour depositing raw phosphor precursor materials of a matrix and an activator component from one or more crucible(s) and/or crucible unit(s) in a vapour deposition apparatus, after ending vapour depositing, an additional "over-annealing" step is performed in humidity conditions wherein more than 10 g of water per cubic meter of dry conditioning air is present.

    Radiation image storage panel and method of preparing said panel
    3.
    发明公开
    Radiation image storage panel and method of preparing said panel 有权
    Strahlungsbildspeicherschirm und Herstellungsverfahrendafür

    公开(公告)号:EP1818943A1

    公开(公告)日:2007-08-15

    申请号:EP07100085.5

    申请日:2007-01-04

    IPC分类号: G21K4/00 C09K11/85

    CPC分类号: G21K4/00 C09K11/7733

    摘要: A radiation image storage panel comprising as a layer arrangement of consecutive layers: a support, a sublayer and a stimulable phosphor layer comprising needle-shaped stimulable phosphor crystals, wherein said sublayer is a binderless non-vapour deposited layer, at least comprising an inorganic alkali metal halide salt compound, thereby providing good adhesiveness.

    摘要翻译: 一种包括连续层的层布置的辐射图像存储面板:支撑体,子层和包含针状可刺激荧光体晶体的可刺激磷光体层,其中所述子层是无粘合剂的非气相沉积层,至少包含无机碱 金属卤化物盐化合物,从而提供良好的粘附性。

    Method of stabilising storage phosphor panels.
    4.
    发明公开
    Method of stabilising storage phosphor panels. 审中-公开
    Verfahren zum Stabilisieren von Speicherleuchtschirmen

    公开(公告)号:EP1793388A2

    公开(公告)日:2007-06-06

    申请号:EP06124429.9

    申请日:2006-11-21

    IPC分类号: G21K4/00 C09K11/61

    摘要: In a method of increasing humidity stability of a storage phosphor panel having a phosphor layer coated onto a support by vapour depositing raw phosphor precursor materials of a matrix and an activator component from one or more crucible(s) and/or crucible unit(s) in a vapour deposition apparatus, after ending vapour depositing, an additional "over-annealing" step is performed in humidity conditions wherein more than 10 g of water per cubic meter of dry conditioning air is present.

    摘要翻译: 在通过气相沉积来自一个或多个坩埚和/或坩埚单元的基质和活化剂组分的原料荧光体前体材料来提高具有涂覆在载体上的荧光体层的存储荧光体面板的湿度稳定性的方法中, 在气相沉积设备中,在结束气相沉积之后,在湿度条件下进行额外的“超退火”步骤,其中每立方米干燥空气中存在超过10g的水。

    Method of vaporisation of phosphor precursor raw materials.
    5.
    发明公开
    Method of vaporisation of phosphor precursor raw materials. 有权
    Verfahren zur Verdampfung von Rohstoffen eines Leuchtstoffvorprodukts

    公开(公告)号:EP1790755A2

    公开(公告)日:2007-05-30

    申请号:EP06122186.7

    申请日:2006-10-12

    IPC分类号: C23C14/24 G21K4/00

    摘要: In a method of preparing a storage phosphor layer on a support by vapour deposition from a crucible unit by heating as phosphor precursor raw materials a matrix component and an activator component or a precursor component thereof, wherein said crucible unit comprises at least a bottom and surrounding side walls as a crucible for phosphor precursor raw materials present in said crucible in liquid form, wherein said crucible unit further comprises at least a chimney as part of the crucible unit and a slit allowing phosphor precursor raw materials to escape in vaporised form from said crucible unit in order to deposit it as a phosphor layer onto said support, the step of heating said precursor raw materials in the crucible in liquid form proceeds up to a temperature T1 and the step of heating said precursor raw materials in vaporised form in said chimney, proceeds up to a temperature T2, characterised in that a positive difference in temperature [T2 - T1] is maintained.

    摘要翻译: 在通过作为荧光体前体原料加热作为荧光体前体原料的基体组分和活化剂组分或其前体组分通过气相沉积在载体上制备存储磷光体层的方法中,其中所述坩埚单元至少包括底部和周围 作为用于以液体形式存在于所述坩埚中的荧光体前体原料的坩埚的侧壁,其中所述坩埚单元还包括至少一个作为坩埚单元的一部分的烟囱和允许荧光体前体原料从所述坩埚以汽化形式逸出的狭缝 单元以将其作为荧光体层沉积到所述载体上,以液体形式加热坩埚中的前体原料的步骤达到温度T1,并且将所述前体原料以汽化形式加热到所述烟囱中的步骤, 进行到温度T2,其特征在于保持温差[T2-T1]的正差。

    Method of vaporisation of phosphor precursor raw materials.
    7.
    发明公开
    Method of vaporisation of phosphor precursor raw materials. 有权
    一种用于Leuchtstoffvorprodukts的原料的蒸发方法

    公开(公告)号:EP1790755A3

    公开(公告)日:2010-08-18

    申请号:EP06122186.7

    申请日:2006-10-12

    IPC分类号: C23C14/24 G21K4/00

    摘要: In a method of preparing a storage phosphor layer on a support by vapour deposition from a crucible unit by heating as phosphor precursor raw materials a matrix component and an activator component or a precursor component thereof, wherein said crucible unit comprises at least a bottom and surrounding side walls as a crucible for phosphor precursor raw materials present in said crucible in liquid form, wherein said crucible unit further comprises at least a chimney as part of the crucible unit and a slit allowing phosphor precursor raw materials to escape in vaporised form from said crucible unit in order to deposit it as a phosphor layer onto said support, the step of heating said precursor raw materials in the crucible in liquid form proceeds up to a temperature T1 and the step of heating said precursor raw materials in vaporised form in said chimney, proceeds up to a temperature T2, characterised in that a positive difference in temperature [T2 - T1] is maintained.

    Method of preparing stabilised storage phosphor panels.
    9.
    发明公开
    Method of preparing stabilised storage phosphor panels. 有权
    Verfahren zur Stabilisierung von Speicherleuchtschirmen

    公开(公告)号:EP1783246A2

    公开(公告)日:2007-05-09

    申请号:EP06122188.3

    申请日:2006-10-12

    IPC分类号: C23C14/24 G21K4/00

    摘要: In a method of preparing a storage phosphor panel having a phosphor layer coated onto a dedicate substrate by vapour depositing raw phosphor precursor materials comprising a matrix component,an activator component and/or a combination thereof from one or more crucible unit(s) in a vapour deposition apparatus, wherein said crucible unit comprises a crucible container and a vaporisation chimney; said method comprises the steps of (1)adding said raw phosphor precursor materials to said crucible unit, and (2)vapour depositing a phosphor layer from said raw phosphor precursor materials, wherein vapour depositing proceeds at an increased temperature in the crucible unit, said temperature exceeding the melting temperature of said matrix raw material with more than 70°C; characterised in that an "activator coating weight number" for said phosphor layer reaches a value of at least 7,000; said "activator coating weight number" being defined herein.

    摘要翻译: 在通过气相沉积原料荧光体前体材料制备具有荧光体层的存储荧光体层的方法中,所述荧光体层包含基体组分,活化剂组分和/或它们的组合,其中一个或多个坩埚单元 气相沉积设备,其中所述坩埚单元包括坩埚容器和汽化烟囱; 所述方法包括以下步骤:(1)将所述原料荧光体前体材料添加到所述坩埚单元,以及(2)从所述原料荧光体前体材料中气相沉积荧光体层,其中在所述坩埚单元中气相沉积在升高的温度下进行,所述 温度超过70℃以上的所述基体原料的熔​​融温度; 其特征在于,所述荧光体层的“活化剂涂层重量数”达到至少7,000的值; 所述“活化剂涂层重量数”在本文中定义。

    Method of preparing stabilised storage phosphor panels.
    10.
    发明公开
    Method of preparing stabilised storage phosphor panels. 有权
    一种用于存储荧光屏稳定过程

    公开(公告)号:EP1783246A3

    公开(公告)日:2013-03-27

    申请号:EP06122188.3

    申请日:2006-10-12

    摘要: In a method of preparing a storage phosphor panel having a phosphor layer coated onto a dedicate substrate by vapour depositing raw phosphor precursor materials comprising a matrix component,an activator component and/or a combination thereof from one or more crucible unit(s) in a vapour deposition apparatus, wherein said crucible unit comprises a crucible container and a vaporisation chimney; said method comprises the steps of (1)adding said raw phosphor precursor materials to said crucible unit, and (2)vapour depositing a phosphor layer from said raw phosphor precursor materials, wherein vapour depositing proceeds at an increased temperature in the crucible unit, said temperature exceeding the melting temperature of said matrix raw material with more than 70°C; characterised in that an "activator coating weight number" for said phosphor layer reaches a value of at least 7,000; said "activator coating weight number" being defined herein.