公开(公告)号：EP2958673A1

公开(公告)日：2015-12-30

申请号：EP14705194.0

申请日：2014-02-19

申请人： Arkema France

发明人： DUBOIS, Jean-Luc ,  MEKKI-BERRADA, Adrien ,  AUROUX, Aline ,  BENNICI, Simona

IPC分类号： B01J35/00 ,  B01J21/04 ,  B01J21/06 ,  B01J23/745 ,  B01J23/835 ,  B01J23/847 ,  C07C253/22

CPC分类号： B01J23/8474 ,  B01J21/066 ,  B01J23/745 ,  B01J23/835 ,  B01J23/8476 ,  B01J35/0006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/108 ,  B01J37/04 ,  C07C253/22 ,  C07C255/03 ,  C07C255/07

摘要： The invention relates to a process for nitrilation of a fatty acid or of a fatty acid ester, which is optionally unsaturated, by reacting ammonia in a reactor operating continuously in the gas phase or in the mixed gas-liquid phase in a temperature range of from 180 to 400°C, in the presence of a solid catalyst comprising - at least one metal oxide, the metal of which belongs to column 8 of the Periodic Table, as a mixture with - at least one metal oxide chosen from aluminium oxides, zirconium oxides, niobium oxide, tantalum oxides and tin oxides, wherein the metal oxide(s), the metal of which belongs to column 8, are present in a volume ratio of 0.1 to 0.6 relative to the volume of the mixture of all the oxides.

摘要翻译： 本发明涉及一种通过使氨在连续操作的反应器中在气相中或在气 - 液混合相中反应的条件下使脂肪酸或任选不饱和的脂肪酸酯腈化的方法， 在固体催化剂存在下进行，所述固体催化剂包含 - 至少一种金属氧化物，所述金属氧化物的金属属于元素周期表第8列，作为与 - 至少一种金属氧化物的混合物，所述金属氧化物选自氧化铝，锆 氧化物，氧化铌，氧化钽和氧化锡，其中金属属于第8列的金属氧化物相对于所有氧化物混合物的体积以0.1-0.6的体积比存在。