ULTRAFILTRATION OF POLYISOOLEFIN COPOLYMERS AND POLYISOOLEFIN COPOLYMERS WITH REDUCED OLIGOMER CONTENT
    1.
    发明公开
    ULTRAFILTRATION OF POLYISOOLEFIN COPOLYMERS AND POLYISOOLEFIN COPOLYMERS WITH REDUCED OLIGOMER CONTENT 审中-公开
    降低低聚物含量的聚烯烃酯共聚物和聚烯烃醚共聚物的超滤

    公开(公告)号:EP3233936A1

    公开(公告)日:2017-10-25

    申请号:EP15868760.8

    申请日:2015-07-07

    发明人: SIEGERS, Conrad

    IPC分类号: C08F6/12 C08J3/24 C08F210/12

    摘要: A method of separating a polyisoolefin elastomer from non-polymeric components in an organic solvent involves ultrafiltration of a solution of the polyisoolefin elastomer and non-polymeric components in an organic solvent through a semipermeable membrane to substantially retain the polyisoolefin elastomer in a retentate and provide the non-polymeric components in a permeate. Advantageously, stabilizers for the polyisoolefin elastomer are retained in the retentate along with the polyisoolefin elastomer, permeate flux through the membrane is higher as concentration of the polyisoolefin elastomer in the solution increases up to a concentration limit, the separated polyisoolefin elastomer in the retentate has a molecular weight that can be substantially unchanged even when ultrafiltration is conducted at elevated temperature and the amount of polyisoolefin elastomer in the permeate is unmeasurable providing an oligomer-rich permeate uncontaminated by polyisoolefin elastomer. A process for curing a polyisoolefin copolymer involves reducing content of an oligomer to 900 ppm or less in a mixture of the oligomer and the polyisoolefin copolymer to produce an oligomer-depleted mixture, and adding a resin cure system to the oligomer-depleted mixture to cure the polyisoolefin copolymer.

    摘要翻译: 从有机溶剂中的非聚合物组分分离聚异烯烃弹性体的方法包括将聚异烯烃弹性体和非聚合物组分在有机溶剂中的溶液通过半渗透膜超滤以基本上保持聚异烯烃弹性体在渗余物中并提供 渗透物中的非聚合物组分。 有利地,用于聚异烯烃弹性体的稳定剂与聚异烯烃弹性体一起保留在保留物中,随着溶液中聚异烯烃弹性体的浓度增加至浓度极限,渗透通过膜的通量更高,保留物中分离的聚异烯烃弹性体具有 即使当在高温下进行超滤并且渗透液中聚异烯烃弹性体的量是不可测量的时,分子量也可以基本上不变,从而提供未被聚异烯烃弹性体污染的富含低聚物的渗透物。 固化聚异烯烃共聚物的方法涉及在低聚物和聚异烯烃共聚物的混合物中将低聚物的含量降低至900ppm或更低,以产生低聚物消耗的混合物,并将树脂固化体系加入到低聚物消耗的混合物中以固化 聚异烯烃共聚物。

    ULTRAFILTRATION OF POLYISOOLEFIN COPOLYMERS
    2.
    发明公开
    ULTRAFILTRATION OF POLYISOOLEFIN COPOLYMERS 审中-公开
    超声波聚苯乙烯聚合物

    公开(公告)号:EP3166979A1

    公开(公告)日:2017-05-17

    申请号:EP15819182.5

    申请日:2015-07-07

    发明人: SIEGERS, Conrad

    IPC分类号: C08F6/12 C08F210/12

    摘要: A method of separating a polyisoolefin elastomer from non-polymeric components in an organic solvent involves ultrafiltration of a solution of the polyisoolefin elastomer and non-polymeric components in an organic solvent through a semipermeable membrane to substantially retain the polyisoolefin elastomer in a retentate and provide the non-polymeric components in a permeate. Advantageously, stabilizers for the polyisoolefin elastomer are retained in the retentate along with the polyisoolefin elastomer, permeate flux through the membrane is higher as concentration of the polyisoolefin elastomer in the solution increases up to a concentration limit, the separated polyisoolefin elastomer in the retentate has a molecular weight that can be substantially unchanged even when ultrafiltration is conducted at elevated temperature and the amount of polyisoolefin elastomer in the permeate is unmeasurable providing an oligomer-rich permeate uncontaminated by polyisoolefin elastomer.

    摘要翻译: 从有机溶剂中的非聚合物组分中分离聚异烯烃弹性体的方法包括通过半透膜将聚异烯烃弹性体和非聚合物组分在有机溶剂中的溶液超滤以将聚异烯烃弹性体基本上保留在滞留物中,并提供 渗透物中的非聚合物组分。 有利地,聚异烯烃弹性体的稳定剂与聚异烯烃弹性体一起保留在滞留物中,通过膜的渗透物质通过溶液中的聚异烯烃弹性体的浓度增加到达浓度极限时,渗余物中的分离聚异烯烃弹性体具有 即使在高温下进行超滤也可以基本上不变的分子量,并且渗透物中的聚异烯烃弹性体的量是不可测量的,从而提供未被聚异烯烃弹性体污染的富含低聚物的渗透物。