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1.
公开(公告)号:EP0552809A1
公开(公告)日:1993-07-28
申请号:EP93101010.2
申请日:1993-01-22
CPC分类号: B01J8/228 , B01J8/222 , B01J2208/0084 , C07C5/11 , C07C2523/46 , C07C2601/16 , C07C13/20
摘要: Disclosed is a method for partially hydrogenating a monocyclic aromatic hydrocarbon to produce a cycloolefin, comprising reacting a monocyclic aromatic hydrocarbon with hydrogen in the presence of a particulate hydrogenation catalyst comprised mainly of metallic ruthenium, in a reaction system comprising a continuous aqueous phase having the particulate hydrogenation catalyst suspended therein, an oil phase containing the monocyclic aromatic hydrocarbon, and a gaseous phase comprising hydrogen gas, while applying a shearing force to the reaction system at a specific maximum shear rate. By the method of the present invention, not only can a cycloolefin be produced at high selectivity and in high yield, but also the catalytic activity can be stably maintained at a high level for a prolonged period of time.
摘要翻译: 公开了一种用于部分氢化的单环芳族烃生产环烯烃,包括在主要由金属钌的颗粒加氢催化剂的存在下反应用氢的单环芳香族烃,在反应系统,包括具有所述颗粒的连续wässrige相位的方法 催化剂氢化。其中悬浮,油相含有单环芳烃的速率,和气相包含氢气,而在一个特定的最大剪切施加剪切力到反应体系中。 通过本发明的方法中,不仅可以在环烯烃以高选择性和高产率地制备,因此但催化活性可以稳定地维持在一个高的水平的长时间。
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2.
公开(公告)号:EP0552809B2
公开(公告)日:1999-06-09
申请号:EP93101010.2
申请日:1993-01-22
CPC分类号: B01J8/228 , B01J8/222 , B01J2208/0084 , C07C5/11 , C07C2523/46 , C07C2601/16 , C07C13/20
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公开(公告)号:EP0614866A1
公开(公告)日:1994-09-14
申请号:EP93104041.4
申请日:1993-03-12
CPC分类号: C07C35/08 , B01J14/005 , B01J19/18 , B01J19/1875 , B01J2219/00094 , B01J2219/00777 , B01J2219/185 , C07C29/04 , C07C2601/08 , C07C2601/14 , C07C35/06
摘要: Disclosed is a method for hydrating a cycloolefin, in which the hydration is conducted in a reaction system comprising a continuous aqueous phase including water and a crystalline aluminosilicate catalyst suspended therein and an oil phase including a cycloolefin, while dispersing the oil phase as globules having a specific diameter. By the method of the present invention, not only can a cyclic alcohol be produced at high selectivity and in high yield, but the activity of the catalyst can also be stably maintained at a high level for a prolonged period of time, and the produced cyclic alcohol can be readily separated.
摘要翻译: 公开了一种水合环烯烃的方法,其中水合在包括连续水相的反应体系中进行,该反应体系包括水和悬浮在其中的结晶硅铝酸盐催化剂和包含环烯烃的油相,同时将油相分散为具有 比直径。 通过本发明的方法,不仅可以以高选择性和高产率生产环醇,而且催化剂的活性也可以在较长时间内稳定地保持在高水平,并且所产生的环状 酒精可以容易地分离。
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公开(公告)号:EP0614866B1
公开(公告)日:1997-01-02
申请号:EP93104041.4
申请日:1993-03-12
CPC分类号: C07C35/08 , B01J14/005 , B01J19/18 , B01J19/1875 , B01J2219/00094 , B01J2219/00777 , B01J2219/185 , C07C29/04 , C07C2601/08 , C07C2601/14 , C07C35/06
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5.
公开(公告)号:EP0552809B1
公开(公告)日:1996-07-10
申请号:EP93101010.2
申请日:1993-01-22
CPC分类号: B01J8/228 , B01J8/222 , B01J2208/0084 , C07C5/11 , C07C2523/46 , C07C2601/16 , C07C13/20
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