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1.发明授权VERFAHREN ZUR DESTILLATIVEN AUFTRENNUNG EINES FLÜSSIGEN ROHALDEHYDGEMISCHES 有权维多利亚ZUR DESTILLATIVEN AUFTRENNUNG EINESFLÜSSIGENROHALDEHYDGEMISCHES
公开(公告)号：EP1165480B1
公开(公告)日：2003-09-10
申请号：EP00917005.1
申请日：2000-03-28
发明人： MÜLLER, Rolf , SCHÖNMANN, Willi
IPC分类号： C07C45/82
CPC分类号： C07C45/50 , B01D3/143 , C07C45/82 , Y10S203/20 , C07C47/02
摘要： The present invention relates to a method for separating a liquid crude aldehyde mixture by distillation. Said mixture contains unbranched and branched aldehydes. In a first distillation column, the product mixture is separated into a first product flow of branched aldehyde, a product flow of unbranched aldehyde and an additional product flow which contains unbranched aldehyde and the high-boiling components. In a second distillation column whose product flow is smaller by a factor of 50 to 200 than the product flow from the first distillation column, the additional product flow is then separated into a product flow of unbranched aldehyde and a high-boiling product flow.
摘要翻译： 在包括直链和支链醛的液体粗醛混合物的分馏的方法中，将产物混合物在第一蒸馏塔中分馏，得到支链醛的产物流，直链醛的产物流和 进一步的产品流包括直链醛和高沸点成分。 然后将另外的产物流在第二蒸馏塔中分馏，其包装体积比第一蒸馏塔的填充体积小50至200倍，得到直链醛和高锅炉产物流的产物流。
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公开(公告)号：EP0927203B1
公开(公告)日：2001-06-13
申请号：EP97909234.3
申请日：1997-09-19
发明人： BLANKERTZ, Heinrich-Josef , GRENACHER, Armin, Volker , SAUER, Friedrich , SCHWAHN, Harald , SCHÖNMANN, Willi , ROEPER, Michael
摘要： A process is disclosed for hydroformylating olefins with 12 to 100 C atoms in the presence of a cobalt carbonyl catalyst, under pressures from 100 to 400 bars and at a temperature from 100 to 200 °C. After expansion the cobalt catalyst is recovered by extraction with an aqueous acid solution in the presence of atmospheric oxygen. The extraction is carried out (a) in the presence of a polymer emulsion breaker selected in the group of the alkoxylated compounds which contain amino-, imino- or OH-groups, and (b) during a coalescence phase, larger drops of the dispersed aqueous phase are caused to form in the organic phase which still contains small amounts of aqueous phase to achieve a complete phase separation.
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3.发明授权VERFAHREN ZUR KONTINUIERLICHEN HYDROFORMYLIERUNG VON POLYALKENEN MIT 30 BIS 700 KOHLENSTOFFATOMEN 有权METHOD FOR聚烯烃具有30至700个碳原子的连续氢甲酰化
公开(公告)号：EP1317491B1
公开(公告)日：2004-12-01
申请号：EP01967331.8
申请日：2001-09-11
发明人： RÖPER, Michael , BLANKERTZ, Heinrich-Josef , GRENACHER, Armin, Volker , KROKOSZINSKI, Roland , SCHÖNMANN, Willi
CPC分类号： C08F8/00 , Y02P20/584 , Y10S585/901 , C08F110/10
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公开(公告)号：EP1294668A1
公开(公告)日：2003-03-26
申请号：EP01960406.5
申请日：2001-06-27
摘要： Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 carbon atoms, whereby (i) an inflow containing olefins and an added saturated hydrocarbon comprising 2 to 8 carbon atoms, as well as carbon monoxide and hydrogen, are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, (ii) a flow consisting essentially of unreacted olefins and saturated hydrocarbons is separated from the discharge from the reaction zone, (iii) said flow is separated into an olefin-enriched fraction and an olefin-depleted fraction by means of rectification, and (iv) the olefin-enriched fraction is at least partially redirected into the reaction zone.
摘要翻译： 本发明公开了一种包含2至8个碳原子的烯烃的加氢甲酰基化方法，其中（i）将包含烯烃和包含2至8个碳原子的加入的饱和烃以及一氧化碳和氢气的流入物送入反应区 并且在加氢甲酰化催化剂存在下反应，（ii）基本上由未反应的烯烃和饱和烃组成的流体从排出物中从反应区中分离出来，（iii）所述流体被分离成富烯烃馏分和烯烃 - （iv）富烯烃级分至少部分地重新导入反应区中。
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5.发明公开
公开(公告)号：EP1165480A1
公开(公告)日：2002-01-02
申请号：EP00917005.1
申请日：2000-03-28
发明人： MÜLLER, Rolf , SCHÖNMANN, Willi
IPC分类号： C07C45/82
CPC分类号： C07C45/50 , B01D3/143 , C07C45/82 , Y10S203/20 , C07C47/02
摘要： The present invention relates to a method for separating a liquid crude aldehyde mixture by distillation. Said mixture contains unbranched and branched aldehydes. In a first distillation column, the product mixture is separated into a first product flow of branched aldehyde, a product flow of unbranched aldehyde and an additional product flow which contains unbranched aldehyde and the high-boiling components. In a second distillation column whose product flow is smaller by a factor of 50 to 200 than the product flow from the first distillation column, the additional product flow is then separated into a product flow of unbranched aldehyde and a high-boiling product flow.
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6.发明授权
公开(公告)号：EP1294668B1
公开(公告)日：2006-02-22
申请号：EP01960406.5
申请日：2001-06-27
摘要： Disclosed is a method for the hydroformylation of olefins comprising 2 to 8 carbon atoms, whereby (i) an inflow containing olefins and an added saturated hydrocarbon comprising 2 to 8 carbon atoms, as well as carbon monoxide and hydrogen, are fed into a reaction zone and reacted in the presence of a hydroformylation catalyst, (ii) a flow consisting essentially of unreacted olefins and saturated hydrocarbons is separated from the discharge from the reaction zone, (iii) said flow is separated into an olefin-enriched fraction and an olefin-depleted fraction by means of rectification, and (iv) the olefin-enriched fraction is at least partially redirected into the reaction zone.
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7.发明公开VERFAHREN ZUR KONTINUIERLICHEN HYDROFORMYLIERUNG VON POLYALKENEN MIT 30 BIS 700 KOHLENSTOFFATOMEN 有权METHOD FOR聚烯烃具有30至700个碳原子的连续氢甲酰化
公开(公告)号：EP1317491A1
公开(公告)日：2003-06-11
申请号：EP01967331.8
申请日：2001-09-11
发明人： RÖPER, Michael , BLANKERTZ, Heinrich-Josef , GRENACHER, Armin, Volker , KROKOSZINSKI, Roland , SCHÖNMANN, Willi
CPC分类号： C08F8/00 , Y02P20/584 , Y10S585/901 , C08F110/10
摘要： The invention relates to a method for the continuous hydroformylation of polyalkenes having 30 to 700 carbon atoms and being unsaturated essentially once. The inventive method involves i) producing a cobalt carbonyl catalyst which is active for hydroformylation from a catalyst precursor which is dissolved in an aqueous phase, in the absence of the polyalkenes, ii) hydroformylating the polyalkenes with synthesis gas in the presence of the cobalt carbonyl catalyst in a reaction zone, and iii) separating the cobalt carbonyl catalyst from the discharge from the reaction zone while at least partially regenerating the catalyst precursor, and returning the catalyst precursor to step i).
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公开(公告)号：EP0927203A1
公开(公告)日：1999-07-07
申请号：EP97909234.0
申请日：1997-09-19
发明人： BLANKERTZ, Heinrich-Josef , GRENACHER, Armin, Volker , SAUER, Friedrich , SCHWAHN, Harald , SCHÖNMANN, Willi , ROEPER, Michael
摘要： A process is disclosed for hydroformylating olefins with 12 to 100 C atoms in the presence of a cobalt carbonyl catalyst, under pressures from 100 to 400 bars and at a temperature from 100 to 200 °C. After expansion the cobalt catalyst is recovered by extraction with an aqueous acid solution in the presence of atmospheric oxygen. The extraction is carried out (a) in the presence of a polymer emulsion breaker selected in the group of the alkoxylated compounds which contain amino-, imino- or OH-groups, and (b) during a coalescence phase, larger drops of the dispersed aqueous phase are caused to form in the organic phase which still contains small amounts of aqueous phase to achieve a complete phase separation.
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