摘要:
The invention relates to a method for the production of terylene-3,4:11,12-tetracarboxydiimides (I) in which the variables have the following meanings: R, R' independently = H, optionally substituted alkyl or cycloalkyl, aryl or heteroaryl, R1 = H or alkyl; R2 = H, alkyl, optionally substituted aryl or heteroaryl, whereby a perylene-3,4-dicarboxyimide (II) is reacted with a naphthalene-1,8-dicarboxyimide (III), where X = H, bromine or chlorine, in the presence of a base-stable, high boiling organic solvent and an alkali or alkaline earth metal base.
摘要:
The invention relates to heptarylene and octarylene tetracarboxylic acid diimides of general formula (I), precursors thereof or mixtures thereof, methods for the production thereof, and the use thereof.
摘要:
The invention relates to heptarylene and octarylene tetracarboxylic acid diimides of general formula (I), precursors thereof or mixtures thereof, methods for the production thereof, and the use thereof.
摘要:
Use of rylene derivatives (I) in which the variables are defined as follows: X together Formulae (x1) (x2) (x3) both -COOM; Y a radical -L-NR1R2 (y1) -L- Z-R3 (y2) the other radical hydrogen; together Formulae (y3) (y4) both hydrogen; R optionally substituted (Het)aryloxy, (Het)arylthio; P -NR1R2; B alkylene; optionally substituted phenylene; combinations thereof; A -COOM; -SO3M; -PO3M2; D optionally substituted phenylene, naphthylene, pyridylene; M hydrogen; alkali metal cation; [NR5]4+; L chemical bond; optionally indirectly bonded, optionally substituted (Het)arylene radical; R1, R2 optionally substituted (cyclo)alkyl, (Het)aryl; together the nitrogen atom containing, optionally substituted ring; Z -O-; -S-; R3 optionally substituted alkyl, (Het)aryl; R' hydrogen; optionally substituted (cyclo)alkyl, (Het)aryl; R5 hydrogen; optionally substituted alkyl, (Het)aryl; m 0, 1, 2; n, p m=0: 0, 2, 4 with: n+p = 2, 4, optionally 0; m=1: 0, 2, 4 with: n+p = 0, 2, 4; m=2: 0, 4, 6 with: n+p = 0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要:
The invention relates to novel perylenetetracarboxylic acid bisimides of structural formula (l), wherein R and R independently represent an organic radical that is bonded to the imide nitrogen atom via a secondary or tertiary carbon atom while at least two of R , R , R , and R independently represent organic radicals containing at least one positively or/and negatively charged group.
摘要:
The invention relates to a method for the production of terylene-3,4:11,12-tetracarboxydiimides (I) in which the variables have the following meanings: R, R' independently = H, optionally substituted alkyl or cycloalkyl, aryl or heteroaryl, R1 = H or alkyl; R2 = H, alkyl, optionally substituted aryl or heteroaryl, whereby a perylene-3,4-dicarboxyimide (II) is reacted with a naphthalene-1,8-dicarboxyimide (III), where X = H, bromine or chlorine, in the presence of a base-stable, high boiling organic solvent and an alkali or alkaline earth metal base.
摘要:
The invention relates to novel perylenetetracarboxylic acid bisimides of structural formula (I), wherein R and R represent different organic radicals, one of said radicals comprising a group for coupling to a bonding partner, while at least two of R , R , R , and R independently represent organic radicals containing at least one hydrophilic group.
摘要:
The invention relates to novel perylenetetracarboxylic acid bisimides of structural formula (l), wherein R1 and R2 independently represent an organic radical that is bonded to the imide nitrogen atom via a secondary or tertiary carbon atom while at least two of R3, R4, R5, and R6 independently represent organic radicals containing at least one positively or/and negatively charged group.
摘要:
The invention relates to novel perylenetetracarboxylic acid bisimides of structural formula (I), wherein R1 and R2 represent different organic radicals, one of said radicals comprising a group for coupling to a bonding partner, while at least two of R3, R4, R5, and R6 independently represent organic radicals containing at least one hydrophilic group.