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公开(公告)号：EP3230408B1
公开(公告)日：2020-02-05
申请号：EP15804756.3
申请日：2015-12-02
Applicant: BP P.L.C.
Inventor： FERGUSON, Ewen , OJEDA PINEDA, Manuel , PATERSON, Alexander , WELLS, Matthew James
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Patent Agency Ranking2.发明公开
公开(公告)号：EP3230408A1
公开(公告)日：2017-10-18
申请号：EP15804756.3
申请日：2015-12-02
Applicant: BP P.L.C.
Inventor： FERGUSON, Ewen , OJEDA PINEDA, Manuel , PATERSON, Alexander , WELLS, Matthew James
CPC classification number: C10G2/332 , B01J21/063 , B01J23/75 , B01J23/8892 , B01J37/0009 , B01J37/0201 , B01J37/18
Abstract: A process for the conversion of a feed comprising a mixture of hydrogen and carbon monoxide to hydrocarbons, the hydrogen and carbon monoxide in the feed being present in a ratio of from 1:9 to 9:1 by volume, the process comprising the steps of: pre-treating a catalyst composition comprising titanium dioxide support and oxidic cobalt or a cobalt compound decomposable thereto, for a period of from 1 to 50 hours, with a hydrogen gas-containing stream comprising less than 10% carbon monoxide gas by volume of carbon monoxide gas and hydrogen gas, to form a reductively-activated catalyst; and contacting the feed at elevated temperature and atmospheric or elevated pressure with the reductively-activated catalyst; wherein the step of pre-treating the catalyst composition is conducted within a temperature range of from 200° C. to less than 300° C., preferably from 220° C. to 280° C., more preferably from 250° C. to 270° C.
Abstract translation: 一种将包含氢气和一氧化碳的混合物的进料转化成烃的方法，进料中的氢气和一氧化碳以体积比1:9-9:1存在，该方法包括以下步骤： ：预处理包含二氧化钛载体和氧化钴或可分解于其中的钴化合物的催化剂组合物1-50小时，其中含氢气流包含小于10体积％的一氧化碳气体 一氧化碳气体和氢气，以形成还原活化的催化剂; 以及在升高的温度和常压或升高的压力下使进料与还原活化的催化剂接触; 其中预处理催化剂组合物的步骤在200℃至小于300℃，优选220℃至280℃，更优选250℃至270℃的温度范围内进行。
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公开(公告)号：EP3229957A1
公开(公告)日：2017-10-18
申请号：EP15808555.5
申请日：2015-12-02
Applicant: BP P.L.C.
Inventor： FERGUSON, Ewen , KRAWIEC, Piotr , OJEDA PINEDA, Manuel , PATERSON, Alexander , WELLS, Matthew James
CPC classification number: B01J37/18 , B01J21/063 , B01J23/75 , B01J37/0009 , B01J37/0201 , C10G2/332
Abstract: A process for the conversion of a feed comprising a mixture of hydrogen and carbon monoxide to hydrocarbons, the hydrogen and carbon monoxide in the feed being present in a ratio of from 1:9 to 9:1 by volume, the process comprising the step of contacting the feed at elevated temperatures and atmospheric or elevated pressure with a catalyst comprising titanium dioxide and cobalt wherein the catalyst initially comprises from 30% to 95% metallic cobalt by weight of cobalt.
Abstract translation: 一种将包含氢气和一氧化碳的混合物的进料转化成烃的方法，进料中的氢气和一氧化碳以1:9至9:1的体积比存在，该方法包括以下步骤： 在升高的温度和常压或升高的压力下使进料与包含二氧化钛和钴的催化剂接触，其中所述催化剂最初包含30重量％至95重量％的钴金属钴。
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公开(公告)号：EP3580307A1
公开(公告)日：2019-12-18
申请号：EP18705130.5
申请日：2018-02-09
Applicant: BP P.L.C.
Inventor： OJEDA PINEDA, Manuel , PATERSON, Alexander, James
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