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公开(公告)号:EP1863856B1
公开(公告)日:2013-09-18
申请号:EP06725065.4
申请日:2006-03-15
发明人: MORINI, Giampiero, Basell Poliolefine Italia S.p.A , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
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公开(公告)号:EP3983454A1
公开(公告)日:2022-04-20
申请号:EP20727644.5
申请日:2020-05-26
发明人: CAVALIERI, Claudio , MASSARI, Paola , CAMURATI, Isabella Maria Vittoria , PANTALEONI, Roberto , COLLINA, Gianni , VITALE, Gianni , CIARAFONI, Marco , GADDI, Benedetta
IPC分类号: C08F210/06 , C08F2/00 , C08J5/18 , C08F210/14 , C08F210/16
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公开(公告)号:EP1863856A1
公开(公告)日:2007-12-12
申请号:EP06725065.4
申请日:2006-03-15
发明人: MORINI, Giampiero, Basell Poliolefine Italia S.p.A , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC分类号: C08F10/00 , C08F210/16 , C08F4/6543 , C08F4/6565 , C08F210/08 , C08F2500/12
摘要: A process for preparing crystalline ethylene (co)polymers comprising (co)polymerizing ethylene in the presence of carried out in the presence catalyst system comprising (a) a solid catalyst component comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having ORI/Ti molar ratio of at least 0.5, an amount of titanium, with respect to the total weight of said solid catalyst component, higher than 4% by weight, and showing a specific pattern of the SS-NMR; and (b) an aluminum alkyl compound as a cocatalyst. The process allows to obtain in good yelds ethylene polymers with narrow MWD.
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公开(公告)号:EP3759169A1
公开(公告)日:2021-01-06
申请号:EP19703375.6
申请日:2019-02-13
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公开(公告)号:EP2454293B1
公开(公告)日:2013-08-21
申请号:EP10730444.6
申请日:2010-07-02
CPC分类号: C08F210/08 , C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6494 , C08F2500/15 , C08F2500/17 , C08F210/06
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公开(公告)号:EP2454293A1
公开(公告)日:2012-05-23
申请号:EP10730444.6
申请日:2010-07-02
IPC分类号: C08F210/08 , C08F4/649 , C08F4/651
CPC分类号: C08F210/08 , C08F10/08 , C08F110/08 , C08F4/651 , C08F4/6494 , C08F2500/15 , C08F2500/17 , C08F210/06
摘要: A process for the preparation of 1-butene homopolymers or 1-butene/alpha olefin copolymers wherein the alpha olefins are selected from ethylene, propylene or alpha olefins of formula CH
2 =CHZ wherein Z is a C
3 -C
20 alkyl radical, comprising contacting 1-butene or 1-butene and one or more alpha olefins under polymerization conditions in the presence of a catalyst system comprising: (a) a solid component comprising a Ti compound and an internal electron-donor compound supported on MgCl
2 (b) an alkylaluminum cocatalyst; and (c) a compound of formula (I) as external donor wherein R
1 , R
2 , R
3 , R
4 and R
5 hydrogen atoms or C
1 -C
20 hydrocarbon radicals, or two R
1 , R
2 , R
3 and R
4 can be joined to form a C
5 -C
20 , saturated or unsaturated, ring.-
公开(公告)号:EP3681916A1
公开(公告)日:2020-07-22
申请号:EP18759120.1
申请日:2018-08-30
发明人: MASSARI, Paola , CAVALIERI, Claudio , TARTARI, Davide , CAPUTO, Tiziana , CAMURATI, Isabella Maria Vittoria
IPC分类号: C08F210/16 , C08L23/14 , C08F210/06
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公开(公告)号:EP1863853B1
公开(公告)日:2011-12-21
申请号:EP06708772.6
申请日:2006-03-15
发明人: MORINI, Giampiero Basell Poliolefine Italia S.p.A. , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC分类号: C08F10/00 , C08F4/6565 , C08F4/6548
摘要: Catalysts components for the polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having specific relationship among ORI/Ti and Mg/Ti molar ratio and characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
摘要翻译: 用于乙烯聚合的催化剂组分包括Ti,Mg,卤素,ORI基团,其中R1是任选含有杂原子的C1-C12烃基,其具有ORI / Ti与Mg / Ti摩尔比之间的特定关系,并且由特定的SS- NMR图案对制备窄MWD结晶乙烯聚合物特别有用。
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公开(公告)号:EP1863853A1
公开(公告)日:2007-12-12
申请号:EP06708772.6
申请日:2006-03-15
发明人: MORINI, Giampiero Basell Poliolefine Italia S.p.A. , CAMURATI, Isabella Maria Vittoria , DALL'OCCO, Tiziano , LIGUORI, Dario , VITALE, Gianni
CPC分类号: C08F10/00 , C08F4/6565 , C08F4/6548
摘要: Catalysts components for the polymerization of ethylene comprising Ti, Mg, halogen, ORI groups, where RI is a C1-C12 hydrocarbon group optionally containing heteroatoms, having specific relationship among ORI/Ti and Mg/Ti molar ratio and characterized by a specific SS-NMR pattern are particularly useful for preparing narrow MWD crystalline ethylene polymers.
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