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    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
    4.
    发明公开
    CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS 审中-公开
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2545082A1

    公开(公告)日：2013-01-16

    申请号：EP11705595.4

    申请日：2011-03-01

    申请人： Basell Poliolefine Italia S.r.l.

    发明人： BRITA, Diego ,  COLLINA, Gianni ,  EVANGELISTI, Daniele ,  GADDI, Benedetta ,  CARBONARA, Maria ,  VINCENZI, Paolo

    IPC分类号： C08F4/654 ,  C08F4/649

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F4/022 ,  C08F4/6543 ,  C08F2500/12 ,  C08F2500/18 ,  C08F4/651

    摘要： The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH
    2 =CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.

    摘要翻译： 本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物聚合的催化剂组分，其中R为具有1-12个碳原子的烷基，环烷基或芳基，包含Ti，Mg，卤素和电子给体 到1,2-二醚作为内部电子给体化合物。 本发明的催化剂适合用于乙烯的（共）聚合过程以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS
    5.
    发明公开
    CATALYST COMPONENT FOR THE POLYMERIZATION OF OLEFINS 有权
    用于烯烃聚合的催化剂组分

    公开(公告)号：EP2029277A1

    公开(公告)日：2009-03-04

    申请号：EP07729982.4

    申请日：2007-06-07

    申请人： Basell Poliolefine Italia S.r.l.

    发明人： COLLINA, Gianni ,  DI DIEGO, Maria ,  FUSCO, Ofelia ,  MORINI, Giampiero ,  VINCENZI, Paolo

    IPC分类号： B01J27/135 ,  B01J27/138 ,  C08F4/642 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C08F210/06 ,  C08F4/6545 ,  C08F4/651 ,  C08F2/001 ,  C08F210/16 ,  C08F2500/12 ,  C08F2500/18 ,  C08F2500/24

    摘要： Catalyst component for the polymerization of olefins comprising Mg, Ti, halogen and an electron donor is obtained by a batch process comprising: (A) A first step comprising reacting an adduct of formula MgCl2(ROH)n, where R is a C1-C10 alkyl group, and n is from 0.5 to 6, in a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature ranging from 0°C to 80°C and then removing the liquid medium; (B) A subsequent step comprising reacting the solid product obtained in (A) in a liquid medium comprising an electron donor ED selected from ethers, esters, ketones, silanes, amines, nitriles and amides, and a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C and then, after removing the liquid medium; (C) A subsequent step comprising reacting the solid product coming from (B) with a liquid medium comprising a titanium compound having at least a Ti-Cl bond at a temperature higher than 80°C.

    摘要翻译： 包括Mg，Ti，卤素和电子给体的烯烃聚合的催化剂组分通过间歇方法获得，该方法包括：（A）第一步，该方法包括使式MgCl 2（ROH）n的加合物（其中R为C 1 -C 10 烷基，并且n为0.5-6，在包含至少具有Ti-Cl键的钛化合物的液体介质中，在0℃至80℃的温度范围内，然后除去液体介质; （B）随后的步骤包括使在（A）中获得的固体产物在包含选自醚，酯，酮，硅烷，胺，腈和酰胺的电子给体ED的液体介质中与具有至少一个Ti -Cl键的温度高于80℃，然后除去液体介质后， （C）随后的步骤包括使来自（B）的固体产物与包含至少具有Ti-Cl键的钛化合物的液体介质在高于80℃的温度下反应。