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    ELECTROCOAT RESIN COMPOSITIONS CONTAINING CARBAMATE FUNCTIONAL RESINS HAVING ONE OR MORE QUATERNARY AMMONIUM GROUPS AND AT LEAST ONE CARBAMATE FUNCTIONAL REACTIVE ADDITIVE
    1.
    发明公开
    ELECTROCOAT RESIN COMPOSITIONS CONTAINING CARBAMATE FUNCTIONAL RESINS HAVING ONE OR MORE QUATERNARY AMMONIUM GROUPS AND AT LEAST ONE CARBAMATE FUNCTIONAL REACTIVE ADDITIVE 有权
    电沉积的涂料组合物含有CARBAMATHALTIGES树脂至少一个季铵基团和至少一个氨基甲酸酯

    公开(公告)号：EP1242543A1

    公开(公告)日：2002-09-25

    申请号：EP00970754.8

    申请日：2000-10-11

    Applicant: BASF CORPORATION

    Inventor： DECEMBER, Timothy

    IPC: C09D5/44 ,  C08K5/205

    CPC classification number: C09D5/4465 ,  C08K5/205 ,  C09D5/4488

    Abstract: The invention provides a resin composition comprising (A) a polymer comprising at least one primary carbamate functional group and one or more 10 quaternary ammonium groups, and (B) a carbarnate functional reactive additive that is generated in situ during the production of polymer (A). The invention also provides a method of making a electrocoat resin composition comprising (A) a polymer having at least one primary carbonate group and one or more quaternary ammoniwn groups and (B) a carbarnate functional 1 5 reactive additive, the method comprising reacting a monomeric polyisocyanate, and a compound comprising at least one group that is reactive with isocyanate and at least one carbamate group, so as to produce both (1) an intermediate product having at least one carbamate functional group and at least one isocyanate functional group, as well as (2) a carbamate functional reactive additive having no isocyanate 20 functionality, reacting said intermediate product with a compound having at least one epoxy group and at least one isocyanate reactive group, said reaction occuring in the presence of the reactive additive so as to produce a carbamate functional resin having at least one epoxy group, reacting said at least one epoxy group with a tertiary amine compound in the presence of an acid to provide a carbamate functional resin having 25 one or more quaternary ammonium groups, said reaction occurring in the presence of the reactive additive to provide a resin composition comprising (A) a carbamate functional resin having one or more quaternary ammonium groups and (B) a carbarnate functional reactive additive. Finally, the invention provides electrocoat coating compositions comprising 30 the resin composition of the invention and a method of using said electrocoat coating compositions.

    A CARBAMATE FUNCTIONAL RESIN FOR PROVIDING AN ANODIC ELECTROCOAT BINDER
    7.
    发明授权
    A CARBAMATE FUNCTIONAL RESIN FOR PROVIDING AN ANODIC ELECTROCOAT BINDER 有权
    CARBAMATHALTIGES树脂对ANAPHORESEANWENDUNG

    公开(公告)号：EP1153082B1

    公开(公告)日：2004-08-04

    申请号：EP99959101.9

    申请日：1999-11-29

    Applicant: BASF Corporation

    Inventor： DECEMBER, Timothy

    IPC: C08L57/12 ,  C09D5/44

    CPC classification number: C25D13/22 ,  C08F212/14 ,  C08F220/36 ,  C08L61/32 ,  C09D5/4407 ,  C09D133/064 ,  C08L2666/02

    Abstract: The invention provides a polymer (a) having a polymer backbone having appended thereto at least one carbamate functional group, the polymer represented by randomly repeating units according to formula (I), wherein R1 represents H or CH3, R2 represents H, alkyl, or cycloalkyl, L represents a divalent linking group, A represents repeat units comprising at least one repeat unit having a pendant carboxylic acid group, x represents 10 to 90 weight %, and y represents 90 to 10 weight %. The invention further provides an anodic electrocoat coating composition comprising an aqueous dispersion of a polymer (a) and (b) a compound having a plurality of functional groups that are reactive with said carbamate groups, wherein the repeat units A of polymer (a) having a pendant carboxylic acid group are base-salted. Finally, the invention provides an anodic electrodeposition method requiring 1) immersing a conductive substrate in a coating composition comprising, in an aqueous medium, polymer (a) and (b) a compound having a plurality of functional groups that are reactive with said carbamate groups, 2) applying a voltage between a cathode and the conductive substrate, and 3) removing the substrate from the coating composition.

    CARBAMATE FUNCTIONAL RESIN HAVING A CATIONIC SALTING SITE
    10.
    发明公开
    CARBAMATE FUNCTIONAL RESIN HAVING A CATIONIC SALTING SITE 有权
    与阳离子盐官氨基甲酸酯官能树脂

    公开(公告)号：EP1144521A1

    公开(公告)日：2001-10-17

    申请号：EP99961866.3

    申请日：1999-11-30

    Applicant: Basf Corporation

    Inventor： DECEMBER, Timothy ,  OHRBOM, Walter ,  MENOVCIK, Gregory

    IPC: C09D5/44 ,  C08L57/12

    CPC classification number: C25D13/22 ,  C08F212/14 ,  C08F220/36 ,  C08L61/32 ,  C09D5/4407 ,  C09D133/062 ,  C08L2666/14

    Abstract: The invention provides a polymer (a) having a polymer backbone having appended thereto at least one carbamate functional group, the polymer represented by randomly repeating units according to the formula: (I) R1 represents H or CH3, R2 represents H, alkyl, or cycloalkyl, L represents a divalent linking group, A represents repeat units comprising at least one repeat unit having a pendant cationic salting group, x represents 10 to 90 weight %, and y represents 90 to 10 weight %. The invention further provides a cathodic electrocoat coating composition comprising an aqueous dispersion of a polymer (a) and (b) a compound having a plurality of functional groups that are reactive with said carbamate groups, wherein the repeat units A of polymer (a) having a pendant cationic salting group are salted with an acid. Finally, the invention provides a cathodic electrodeposition method requiring 1) immersing a conductive substrate in a coating composition comprising, in an aqueous medium, a polymer (a) and (b) a compound having a plurality of functional groups that are reactive with said carbamate groups, 2) applying a voltage between an anode and the conductive substrate, and 3) removing the substrate from the coating composition.

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