摘要:
Method of making an oxide of M, wherein M is at least one transition metal, preferably selected from Ni, Mn, or Co, or a mixture of two or more thereof, comprising at least steps (S1) and (S2): (S1) mixing a composition comprising water and at least one cation of at least one M with a composition comprising water and at least one anion selected from the group consisting of hydroxide, hydrogen carbonate, and carbonate, or a mixture of two or more thereof, in a colloid mill; (S2) precipitating an oxide or hydroxide or hydrogen carbonate or carbonate or a mixture of two or more thereof of M from the milled mixture obtained in step (S1).
摘要:
Method of making lithium difluoro (oxalato) borate Li [BF2C2O4], optionally in mixture with lithium tetrafluoroborate, comprising at least steps (S) and (T1) or (T2): (S) mixing lithium oxalate and boron trifluoride in the form of a complex with an ether in an organic solvent; (T1) heating the mixture obtained in step (S); or (T2) heating the mixture obtained in step (S) under a pressure above atmos-pheric pressure; wherein the reaction is carried out in the absence of a chloride-containing compound.
摘要:
Method of making a mixed oxide comprising at least Li and M, and optionally one or more of Al, Si, Mg, and B, wherein M is selected from at least one transition metal, comprising at least steps (S1) to (S3), and optionally step (S4), and steps (T1) to (T2): (S1) mixing a composition comprising water and at least one cation of at least one M with a composition comprising water and at least one anion selected from the group consisting of hydroxide, hydrogen carbonate, and carbonate, or a mixture of two or more thereof; (S2) precipitating an oxide or hydroxide or hydrogen carbonate or carbonate, or a mixture of two or more thereof, of M from the mixture obtained in step (S1); (S3) isolating said oxide or hydroxide or hydrogen carbonate or carbonate, or a mixture of two or more thereof, of M precipitated in step (S2); (S4) optionally, sintering the compound isolated in step (S3); (T1) mixing a lithium oxide, lithium hydroxide, lithium carbonate or lithium hydrogen carbonate, or a mixture of two or more thereof, with a product obtained in step (S3) or (S4); (T2) sintering the mixture obtained in step (T1); with the proviso that any one of steps (S1) to (S4) is carried out in the absence of a compound containing a NH-moiety.