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    NOUVEAUX CATALYSEURS DE RETICULATION DE COMPOSITIONS SILICONES
    1.
    发明公开
    NOUVEAUX CATALYSEURS DE RETICULATION DE COMPOSITIONS SILICONES 审中-公开
    NOUVEAUX CATALYSEURS DE RETICULATION组合物硅

    公开(公告)号：EP3215557A1

    公开(公告)日：2017-09-13

    申请号：EP15801908.3

    申请日：2015-11-06

    申请人： Bluestar Silicones France SAS ,  Université Claude Bernard Lyon 1 ,  Centre National de la Recherche Scientifique (C.N.R.S.)

    发明人： MONTEIL, Vincent ,  RAYNAUD, Jean ,  CROZET, Delphine ,  BOUSQUIÉ, Magali ,  MARROT, Sébastien

    IPC分类号： C08G77/08 ,  C08L83/04 ,  C08L83/14

    CPC分类号： C08G77/08 ,  C08G77/12 ,  C08G77/20 ,  C08G77/44 ,  C08G77/70 ,  C08K5/0091 ,  C08L83/00 ,  C08L83/04 ,  C08L2205/025

    摘要： The invention relates to a crosslinkable composition X, comprising: at least one organopolysiloxane compound A comprising, per molecule, at least two C
    2 -C
    6 alkenyl radicals bonded to silicon atoms; at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom; at least one catalyst C which is a complex corresponding to the following formula: [Fe(L
    1 )2] in which: the symbol Fe represents iron at degree of oxidation II; the symbols L
    1 , which may be identical or different, represent a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonylated compound; optionally at least one adhesion promoter D; and optionally at least one charge E. The invention also relates to the use of the previously described catalyst C as silicone composition crosslinking catalyst, to a silicone composition crosslinking method, characterized in that it consists in heating the composition X to a temperature of between 70 and 200°C, and to the resulting crosslinked silicone material Y.

    摘要翻译： 本发明涉及可交联组合物X，其包含：至少一种有机聚硅氧烷化合物A，其每分子包含至少两个与硅原子键合的C 2 -C 6烯基; 至少一种有机氢聚硅氧烷化合物B，其每分子包含至少两个与相同或不同硅原子键合的氢原子; 至少一种催化剂C，其为对应于下式的配合物：[Fe（L1）2]其中：符号Fe表示氧化度为II的铁; 符号L1可以相同或不同，表示β-二羰基阴离子或β-二羰基化合物的烯醇化物阴离子的配体; 任选地至少一种助粘剂D; 和任选地至少一种电荷E.本发明还涉及前述催化剂C作为有机硅组合物交联催化剂与有机硅组合物交联方法的用途，其特征在于其包括将组合物X加热至70℃ 和200℃，并且得到交联的硅氧烷材料Y.

    NOUVEAUX CATALYSEURS DE RÉTICULATION DE COMPOSITIONS SILICONES
    3.
    发明公开
    NOUVEAUX CATALYSEURS DE RÉTICULATION DE COMPOSITIONS SILICONES 审中-公开
    NOUVEAUX CATALYSEURS DERÉTICULATIONDE组合物硅

    公开(公告)号：EP3215556A1

    公开(公告)日：2017-09-13

    申请号：EP15801906.7

    申请日：2015-11-06

    申请人： Bluestar Silicones France SAS ,  Université Claude Bernard Lyon 1 ,  Centre National de la Recherche Scientifique (C.N.R.S.)

    发明人： MONTEIL, Vincent ,  RAYNAUD, Jean ,  CROZET, Delphine ,  BOUSQUIÉ, Magali ,  MARROT, Sébastien

    IPC分类号： C08G77/08 ,  C08L83/04 ,  C08L83/14

    CPC分类号： C08G77/08 ,  C08G77/12 ,  C08G77/20 ,  C08G77/44 ,  C08G77/70 ,  C08K5/0091 ,  C08L83/00 ,  C08L83/04 ,  C08L2205/025

    摘要： The invention relates to a crosslinkable composition X, comprising: at least one organopolysiloxane compound A comprising, per molecule, at least two C
    2 -C
    6 alkenyl radicals bonded to silicon atoms; at least one organohydrogenopolysiloxane compound B comprising, per molecule, at least two hydrogen atoms bonded to an identical or different silicon atom; at least one catalyst C which is a complex corresponding to the following formula: [Co (L
    1 )
    2 ] in which: the symbol Co represents cobalt at degree of oxidation II; the symbols L
    1 , which may be identical or different, represent a ligand which is a β-dicarbonylato anion or the enolate anion of a β-dicarbonylated compound; optionally at least one adhesion promoter D; and optionally at least one charge E. The invention also relates to the use of the previously described catalyst C as silicone composition crosslinking catalyst, to a silicone composition crosslinking method, characterized in that it consists in heating the composition X to a temperature of between 70 and 200°C, and to the resulting crosslinked silicone material Y.

    摘要翻译： 本发明涉及可交联组合物X，其包含：至少一种有机聚硅氧烷化合物A，其每分子包含至少两个与硅原子键合的C 2 -C 6烯基; 至少一种有机氢聚硅氧烷化合物B，其每分子包含至少两个与相同或不同硅原子键合的氢原子; 至少一种催化剂C，其为对应于下式的配合物：[Fe（L1）2]其中：符号Fe表示氧化度为II的铁; 符号L1可以相同或不同，表示β-二羰基阴离子或β-二羰基化合物的烯醇化物阴离子的配体; 任选地至少一种助粘剂D; 和任选地至少一种电荷E.本发明还涉及前述催化剂C作为有机硅组合物交联催化剂与有机硅组合物交联方法的用途，其特征在于其包括将组合物X加热至70℃ 和200℃，并且得到交联的硅氧烷材料Y.