摘要:
A process for the preparation of a polypropylene in a sequential polymerization process including at least two polymerization reactors connected in series. The polymerization takes place in the presence of a Ziegler-Natta catalyst, and said Ziegler-Natta catalyst includes (a) a pro-catalyst that has a compound of a transition metal, a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, (b) a co-catalyst, and (c) an external donor. The ratio of catalyst feed rate to propylene feed rate in the first polymerization reactor is 1.0 to 4.5 g/t.
摘要:
The present invention relates to a process for the preparation of a polypropylene in a sequential polymerization process comprising a pre-polymerization reactor and at least two polymerization reactors connected in series, wherein the polymerization in the at least two polymerization reactors takes place in the presence of a Ziegler-Natta catalyst, and said Ziegler-Natta catalyst comprises (a) a pro-catalyst comprising (a1) a compound of a transition metal, (a2) a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), (a3) an internal electron donor,
(b) a co-catalyst, and (c) an external donor, wherein said Ziegler-Natta catalyst is present in the pre-polymerization reactor and ethylene (C2) in addition to propylene (C3) is fed to said pre-polymerization reactor in a C2/C3 feed ratio of 0.5 to 10.0 g/kg.
摘要:
The present invention relates to a new biaxially oriented polypropylene (BOPP) film, a process for the preparation of such film as well as the use of a polypropylene for the preparation of such film and an article comprising such film.
摘要:
The present invention relates to a new biaxially oriented polypropylene (BOPP) film, a process for the preparation of such film as well as the use of a polypropylene for the preparation of such film and an article comprising such film.
摘要:
Polypropylene composition having a MFR2 in the range of equal or more than 0.5 to 6.0 g/10min, said composition comprises, a propylene homopolymer, a random propylene copolymer, an elastomeric propylene copolymer, a polyethylene, and an a-nucleating agent, wherein the polypropylene composition is a heterophasic system in which the propylene homopolymer and the random propylene copolymer form the matrix of said system and the elastomeric propylene copolymer and the polyethylene are dispersed in said matrix.
摘要:
Process for the preparation of a polypropylene in a sequential polymerization process comprising at least three reactors connected in series, wherein the polymerization takes place in the presence of a Ziegler-Natta catalyst, said Ziegler-Natta catalyst comprises ▪ a pro-catalyst comprising a compound of a transition metal (TM), a compound of a metal which metal is selected from one of the groups 1 to 3 of the periodic table (IUPAC), and an internal electron donor, ▪ a co-catalyst (Co), and ▪ an external donor (ED), wherein further the mol-ratio of co-catalyst (Co) to external donor (ED) [Co/ED] is in the range of above 12 to below 25, and the mol-ratio of co-catalyst (Co) to transition metal (TM) [Co/TM] is in the range of above 100 to below 200.