摘要:
A macromolecule comprises a plurality of polyhedral-modified polymers, each of said polymers comprising a polyhedral radical chemically bonded thereto at a terminus, each of said plurality of polymers being bonded to or associated with at least one other of said plurality of polymers through their respective polyhedral radicals.
摘要:
Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要:
A functionalized polymer includes a polymer chain and a terminal group linked to the chain through a functionality that contains one or more urethane groups. The functionalized polymer can be provided by reacting a nucleophile with a polymer having terminal iso(thio)cyanate functionality which, in turn, can be provided by reacting a terminally active polymer with a polyiso(thio)cyanate. Even polymers that contain substantial amounts of styrene mer can be used in the described process.
摘要:
Vulcanizates with desirable properties can be obtained from compounds incorporating polymers that include hydroxyl group-containing aryl functionalities. The functionalities can be incorporated by using any or all of appropriate initiators, monomers and optional terminating compounds. Such polymers exhibit excellent interactivity with both conventional and non-conventional fillers.
摘要:
A macromolecule comprises a plurality of polyhedral-modified polymers, each of said polymers comprising a polyhedral radical chemically bonded thereto at a terminus, each of said plurality of polymers being bonded to or associated with at least one other of said plurality of polymers through their respective polyhedral radicals.
摘要:
An initiator is presented for anionically polymerizing monomers, to provide a functional head group on the polymer. A polymer having a functional head group derived from a sulfur containing anionic initiator, and optionally as additional functional group resulting from the use of a functional terminating reagent, coupling agent or linking agent is also provided. A method is presented for anionically polymerizing monomers comprising the step of polymerizing the monomers with a sulfur containing anionic initiator to provide a functional head group on the polymer. An elastomeric compound, comprising a functional polymer and filler is also described. Also provided is a tire having decreased rolling resistance resulting from a tire component containing a vulcanizable elastomeric compound.
摘要:
A functionalized polymer includes a polymer chain and a terminal group linked to the chain through a functionality that contains one or more urethane groups. The functionalized polymer can be provided by reacting a nucleophile with a polymer having terminal iso(thio)cyanate functionality which, in turn, can be provided by reacting a terminally active polymer with a polyiso(thio)cyanate. Even polymers that contain substantial amounts of styrene mer can be used in the described process.
摘要:
A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula -NH-NR 1 R 2 where R 1 and R 2 independently are substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl groups, or together form a substituted or unsubstituted alkylene, alkenylene, cycloalkylene, cycloalkenylene, or arylene group. The functionalized polymer can be provided by reacting a living polymer with a hydrazone. Such polymers can be used in the production of compositions that include particulate fillers.
摘要翻译:一种官能化聚合物包括直接键合部分,其可以位于该聚合物的末端,由式-NH-NR 1 R 2其中R 1和R 2独立地是取代或未取代烷基,烯基,环烷基,环烯基,芳基,烯丙基,芳烷基定义 烷芳基或炔基,或者一起形成取代或未取代的亚烷基,亚烯基,亚环烷基,亚环烯基或亚芳基。 官能化聚合物可以通过使活性聚合物与腙反应来提供。 这种聚合物可以用于生产包含颗粒填料的组合物。
摘要:
A functionalized polymer includes a directly bonded moiety, which can be located at a terminus of the polymer, defined by the formula -NH-NR 1 R 2 where R 1 and R 2 independently are substituted or unsubstituted alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, allyl, aralkyl, alkaryl, or alkynyl groups, or together form a substituted or unsubstituted alkylene, alkenylene, cycloalkylene, cycloalkenylene, or arylene group. The functionalized polymer can be provided by reacting a living polymer with a hydrazone. Such polymers can be used in the production of compositions that include particulate fillers.
摘要翻译:官能化聚合物包括直接键合的部分,其可以位于由式-NH-NR 1 R 2定义的聚合物的末端,其中R 1和R 2独立地是取代或未取代的烷基,烯基,环烷基,环烯基, 芳基,烯丙基,芳烷基,烷芳基或炔基,或一起形成取代或未取代的亚烷基,亚烯基,亚环烷基,亚环烯基或亚芳基。 官能化聚合物可以通过使活性聚合物与腙反应来提供。 这种聚合物可以用于生产包括颗粒填料的组合物。