公开(公告)号：EP2237878A2

公开(公告)日：2010-10-13

申请号：EP08865288.8

申请日：2008-12-16

申请人： CECA S.A. ,  Institut Français du Pétrole

发明人： BOUVIER, Ludivine ,  KIEGER, Stéphane ,  LAROCHE, Catherine ,  LEFLAIVE, Philibert ,  FRISING, Tom

IPC分类号： B01J20/18 ,  B01J20/28 ,  B01J20/32 ,  C07C7/13 ,  C07C15/08 ,  C07C37/82 ,  C07C201/16

摘要： The invention relates to agglomerated zeolitic adsorbents based on faujasite X zeolite powder having a low silica content and small crystals, said zeolite being exchanged with barium, or based on faujasite X zeolite having a low silica content and small crystals, this zeolite being exchanged both with barium and potassium. The invention also relates to the method of preparing said agglomerated zeolitic adsorbents and to the uses thereof in the separation of sugars, polyhydric alcohols, substituted-toluene isomers and cresols or in the recovery of very-pure paraxylene.

公开(公告)号：EP2237877A2

公开(公告)日：2010-10-13

申请号：EP08865186.4

申请日：2008-12-16

申请人： CECA S.A. ,  Institut Français du Pétrole

发明人： BOUVIER, Ludivine ,  KIEGER, Stéphane ,  LAROCHE, Catherine ,  LEFLAIVE, Philibert ,  FRISING, Tom

IPC分类号： B01J20/18 ,  B01J20/28 ,  B01J20/32 ,  C07C7/13 ,  C07C15/08 ,  C07C37/82 ,  C07C201/16

CPC分类号： B01J20/18 ,  B01J20/183 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/2803 ,  C07C7/13 ,  C07C17/389 ,  C07C29/76 ,  C07C37/82 ,  C07C201/16 ,  Y02P20/52 ,  C07C15/08 ,  C07C25/08 ,  C07C31/18 ,  C07C39/07 ,  C07C205/06

摘要： The present invention relates to agglomerated zeolitic adsorbents based on X zeolite and LSX zeolite powders. These adsorbents are particularly well suited for the separation of C
8 aromatic isomers and especially xylenes, for the separation of sugars, for the separation of polyhydric alcohols, for the separation of substituted-toluene isomers, such as nitrotoluene, diethyltoluene and toluenediamine, for the separation of cresols and for the separation of dichlorobenzenes.

摘要翻译： 本发明涉及基于X沸石和LSX沸石粉末的附聚沸石吸附剂。 这些吸附剂特别适用于分离C 8芳族异构体和尤其是二甲苯，用于糖的分离，用于分离多元醇，用于分离取代甲苯异构体如硝基甲苯，二乙基甲苯和甲苯二胺，用于 分离甲酚和分离二氯苯。

公开(公告)号：EP2043775A1

公开(公告)日：2009-04-08

申请号：EP07823582.7

申请日：2007-07-13

申请人： CECA S.A. ,  Institut Français du Pétrole

发明人： BOUVIER, Ludivine ,  KIEGER, Stéphane ,  LAROCHE, Catherine ,  LEFLAIVE, Philibert ,  PLEE, Dominique

IPC分类号： B01J20/18

CPC分类号： B01J20/183 ,  B01J20/186

摘要： The present invention relates to agglomerated zeolitic adsorbents based on zeolite X with an Si/Al ratio such that 1.15

摘要翻译： 包含钡X沸石粉末和惰性粘合剂的聚集的沸石吸附剂具有至少0.245cm 3> / g的Dubinin体积和至少2MPa的机械强度（Shell SMS1471-74）。 沸石粉末的晶体直径为1.6μm以下，硅/铝比为1.15-1.5，其中至少90％的阳离子交换位置被钡离子或钡和钾离子占据，条件是不再有 超过1/3的这些位点被钾离子所占据。 还包括以下独立权利要求：（1）通过将X沸石粉末与包含至少80重量％的可分解沸石的粘土和二氧化硅源的粘合剂凝聚在一起来生产吸附剂的方法（P1），干燥并煅烧附聚物， 用碱溶液粘合剂，用钡代替至少90​​％的交换位置，洗涤和干燥产物，任选地用钾取代最多33％的交换位点，并洗涤，干燥和活化产物，其中钾交换可以 在钡交换之前或之后进行; （2）通过如上所述在解吸剂的存在下通过在吸附剂上吸附来从液相或气相中的C 8芳族馏分中回收对二甲苯的方法（P2）。

公开(公告)号：EP1689695B1

公开(公告)日：2009-02-04

申请号：EP04805513.1

申请日：2004-11-23

申请人： Institut Français du Pétrole

发明人： LEFLAIVE, Philibert ,  WOLFF, Luc ,  HOTIER, Gérard

IPC分类号： C07C15/08 ,  C07C5/27 ,  C07C7/12

CPC分类号： C07C5/2775 ,  C07C5/2737 ,  C07C7/12 ,  C07C15/08

摘要： The invention concerns a method for producing paraxylene from a feedstock of hydrocarbons in an adsorption column working with a simulated moving bed at at least five areas and delivering an extract, a raffinate-2 and an intermediate raffinate. The extract is distilled, and the distillate is optionally recrystallized in order to recuperate paraxylene with a purity of at least 99.7%. The raffinate-2 is distilled and is then isomerized in a reactor preferably functioning in a liquid phase and at low temperature. The intermediate raffinate having an enriched content of ethylbenzene is distilled then isomerized in a vapor phase.

公开(公告)号：EP1689695A2

公开(公告)日：2006-08-16

申请号：EP04805513.1

申请日：2004-11-23

申请人： Institut Français du Pétrole

发明人： LEFLAIVE, Philibert ,  WOLFF, Luc ,  HOTIER, Gérard

IPC分类号： C07C15/08 ,  C07C5/27 ,  C07C7/12

CPC分类号： C07C5/2775 ,  C07C5/2737 ,  C07C7/12 ,  C07C15/08

摘要： The invention concerns a method for producing paraxylene from a feedstock of hydrocarbons in an adsorption column working with a simulated moving bed at at least five areas and delivering an extract, a raffinate-2 and an intermediate raffinate. The extract is distilled, and the distillate is optionally recrystallized in order to recuperate paraxylene with a purity of at least 99.7%. The raffinate-2 is distilled and is then isomerized in a reactor preferably functioning in a liquid phase and at low temperature. The intermediate raffinate having an enriched content of ethylbenzene is distilled then isomerized in a vapor phase.

公开(公告)号：EP2991760A1

公开(公告)日：2016-03-09

申请号：EP14719802.2

申请日：2014-04-29

申请人： IFP Énergies nouvelles ,  CECA S.A.

发明人： BATS, Nicolas ,  LAROCHE, Catherine ,  LEFLAIVE, Philibert ,  BOUVIER, Ludivine

IPC分类号： B01J20/18 ,  B01J20/28 ,  B01J20/30 ,  B01J20/32

CPC分类号： B01J20/186 ,  B01J20/28004 ,  B01J20/28007 ,  B01J20/2803 ,  B01J20/3028 ,  B01J20/3042 ,  B01J20/3071 ,  B01J20/3078 ,  B01J20/3085 ,  B01J20/3204 ,  B01J20/3236 ,  B82Y30/00 ,  C07C7/13 ,  C07C29/76 ,  C07C37/82

摘要： The present invention concerns zeolite adsorbents made from agglomerated EMT zeolite crystals comprising barium and/or potassium. These adsorbents can be applied in the separation of C8 aromatic isomer fractions and in particular xylenes, in the separation of substituted toluene isomers such as nitrotoluene, diethyltoluene and toluenediamine, and in the separation of cresols, and polyhydric alcohols, such as sugars.

摘要翻译： 本发明涉及沸石基于包括钡和/或钾沸石EMT的聚集晶体吸附剂。 这些吸附剂发现在芳族C8异构体的级分的分离应用中，爱的特别是二甲苯，二乙基甲苯和甲苯二胺在substituiertem甲苯异构体，：如硝基甲苯的分离，并在甲酚的分离，并且在多元醇，：如分离 糖。

公开(公告)号：EP2958650A1

公开(公告)日：2015-12-30

申请号：EP14705172.6

申请日：2014-02-18

申请人： IFP Énergies nouvelles ,  CECA S.A.

发明人： LAROCHE, Catherine ,  LEINEKUGEL LE COCQ, Damien ,  LEFLAIVE, Philibert ,  AUGIER, Frédéric ,  BOUVIER, Ludivine ,  LUTZ, Cécile ,  SZENDROVICS, Sylvie ,  PERSILLON, Quitterie

IPC分类号： B01D15/18 ,  B01J20/18 ,  C07C7/13 ,  C07C15/08 ,  B01J20/28

CPC分类号： C07C7/13 ,  B01D15/1828 ,  B01J20/183 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28019 ,  B01J20/28052 ,  B01J20/28071 ,  C07C15/08

摘要： The invention relates to a method for separating xylenes by means of a simulated mobile bed using an agglomerated zeolitic adsorbent solid, preferably based on faujasite zeolite with a Si/Al ratio of between 1 and 6, said solid being used in the form of particles having a diameter of between 150 μm et 500 μm.

公开(公告)号：EP3071323A1

公开(公告)日：2016-09-28

申请号：EP14800077.1

申请日：2014-11-20

申请人： CECA S.A. ,  IFP Énergies nouvelles

发明人： LAROCHE, Catherine ,  BOUVIER, Ludivine ,  LEFLAIVE, Philibert ,  LUTZ, Cécile ,  GAY, Anne-Sophie ,  MOREAU, Florent

IPC分类号： B01J20/18 ,  B01J20/28

CPC分类号： C07C7/13 ,  B01J20/12 ,  B01J20/18 ,  B01J20/183 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/28016 ,  B01J20/28069 ,  B01J20/2808 ,  B01J20/28083 ,  B01J20/28085 ,  B01J20/28088 ,  B01J20/28092 ,  B01J20/3042 ,  B01J20/3078 ,  B01J20/3085 ,  C07C15/08

摘要： The present invention relates to a zeolitic granular material having a connected zeolitic structure across the entire volume thereof, having high mechanical resistance to crushing in the bed, and optimised material transfer in the macro-mesopores. The invention also relates to the method for preparing said zeolitic granular material, as well as to the use thereof as an adsorbent material in co-current or counter-current liquid phase separation methods, typically in a simulated mobile bed.

公开(公告)号：EP2931417A1

公开(公告)日：2015-10-21

申请号：EP13802962.4

申请日：2013-12-10

申请人： CECA S.A. ,  IFP Énergies nouvelles

发明人： BOUVIER, Ludivine ,  KIEGER, Stéphane ,  LAROCHE, Catherine ,  LEFLAIVE, Philibert

IPC分类号： B01J20/18 ,  B01J20/28 ,  C07C29/76 ,  C07C37/82 ,  C07C7/13

CPC分类号： B01J20/18 ,  B01J20/183 ,  B01J20/186 ,  B01J20/28004 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/3007 ,  B01J20/3042 ,  B01J20/3071 ,  B01J20/3078 ,  C07C7/13 ,  C07C29/76 ,  C07C37/82 ,  C07C39/07 ,  C07C15/08 ,  C07C15/02

摘要： The present invention relates to zeolitic adsorbents based on small agglomerated crystals of zeolite X comprising barium, combining optimum properties in terms of selectivity and of mechanical strength. These adsorbents have applications in the separation of fractions of aromatic C
8 isomers and in particular xylenes, in the separation of substituted toluene isomers, such as nitrotoluene, diethyltoluene or toluenediamine, in the separation of cresols, and in the separation of polyhydric alcohols, such as sugars.

摘要翻译： 本发明涉及基于包含钡的沸石X的小团聚晶体的沸石吸附剂，其结合了选择性和机械强度方面的最佳性能。 这些吸附剂用于分离芳族C 8异构体，特别是二甲苯，分离取代的甲苯异构体如硝基甲苯，二乙基甲苯或甲苯二胺在分离甲酚和分离多元醇如糖 。

公开(公告)号：EP3177584A1

公开(公告)日：2017-06-14

申请号：EP15744263.3

申请日：2015-08-04

申请人： IFP Energies Nouvelles ,  CECA S.A.

发明人： LAROCHE, Catherine ,  LEFLAIVE, Philibert ,  BAUDOT, Arnaud ,  BOUVIER, Ludivine ,  LUTZ, Cécile ,  NICOLAS, Serge

IPC分类号： C07C7/13 ,  C07C15/08 ,  B01J20/18 ,  B01J20/28

CPC分类号： C07C7/13 ,  B01J20/183 ,  B01J20/186 ,  B01J20/2803 ,  B01J20/28061 ,  B01J20/28071 ,  B01J20/28083 ,  B01J20/28085 ,  C07C15/08

摘要： The invention relates to a method for separating
meta -xylene from C8 aromatic fractions, using a zeolitic adsorbent based on sodium-exchanged or sodium-and-lithium-exchanged agglomerated crystals of zeolite Y, with a large external surface area.

摘要翻译： 本发明涉及一种用于从C 8芳族馏分中分离间二甲苯，使用基于沸石吸附剂的方法钠交换或钠 - 和 - 锂交换的沸石Y的聚集晶体，具有大的外表面面积。